Patents by Inventor Coralie Graire

Coralie Graire has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10752573
    Abstract: This invention relates to a process for the continuous production of a (meth)acrylic ester by transesterification reaction between a C1-C4 light alkyl (meth)acrylate, with a heavy alcohol in the presence of a catalyst, characterised in that the flows feeding the reactor are introduced through a static mixer placed on a recirculation loop of the reactor. The use of a static mixer improves the selectivity of the reaction and consequently the overall productivity of (meth)acrylic ester synthesis process.
    Type: Grant
    Filed: December 7, 2017
    Date of Patent: August 25, 2020
    Assignee: Arkema France
    Inventors: Fanny Dubut, Marc Esch, Coralie Graire, Benoit Riflade
  • Publication number: 20200079722
    Abstract: This invention relates to a process for the continuous production of a (meth)acrylic ester by transesterification reaction between a C1-C4 light alkyl (meth)acrylate, with a heavy alcohol in the presence of a catalyst, characterised in that the flows feeding the reactor are introduced through a static mixer placed on a recirculation loop of the reactor. The use of a static mixer improves the selectivity of the reaction and consequently the overall productivity of (meth)acrylic ester synthesis process.
    Type: Application
    Filed: December 7, 2017
    Publication date: March 12, 2020
    Inventors: Fanny DUBUT, Marc ESCH, Coralie GRAIRE, Benoit RIFLADE
  • Patent number: 10000439
    Abstract: The invention relates to the production of alkyl acrylate according to a continuous transesterification process. In one embodiment the process of the invention uses a simple column to purify a reaction mixture of acryl acrylate in one step yielding alkyl acrylate with a purity of greater than 99.8%.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: June 19, 2018
    Assignee: Arkema France
    Inventors: Alain F. Riondel, Coralie Graire, Marc Esch, Andre Levray
  • Patent number: 9776946
    Abstract: The invention relates to the industrial production of highly pure 2-propylheptyl acrylate with a high yield according to a process by transesterification, preferably in semi-continuous mode. The process according to the invention uses ethyl titanate in solution in 2-propylheptanol or 2-propylheptyl titanate as transesterification catalyst, and implements a purification sequence comprising a single distillation column and a film evaporator.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: October 3, 2017
    Assignee: Arkema France
    Inventors: Alain F. Riondel, Coralie Graire
  • Patent number: 9403750
    Abstract: The invention relates to a process for continuously producing 2-octyl acrylate by reacting acrylic acid and 2-octanol in the presence of a sulfonic acid esterification catalyst and at least one polymerization inhibitor. The water formed by the esterification reaction is entrained by distillation in a column surmounting the reactor in the form of a heteroazeotropic mixture with the 2-octanol which is then subjected, after condensation, to separation in a decanter so as to give an upper organic phase and a lower aqueous phase. The reaction mixture containing the reaction product and residual by-products are purified by separation means in order to obtain: (1) pure 2-octyl acrylate and (2) unreacted 2-octanol and acrylic acid compounds that will be recycled along with the catalyst.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: August 2, 2016
    Assignee: Arkema France
    Inventors: Alain Riondel, Coralie Graire, Andre Levray, Reinhard Linemann
  • Patent number: 9296679
    Abstract: The invention relates to the production of 2-octyl acrylate of high purity and in good yield, that includes the recycling of economically upgradable products, such as un-reacted reactants and catalyst. The process uses ethyl titanate in solution in 2-octanol or 2-octyl titanate as a tranesterification catalyst and employs a purification train comprising only two distillation columns.
    Type: Grant
    Filed: January 14, 2013
    Date of Patent: March 29, 2016
    Assignee: Arkema France
    Inventors: Alain Riondel, Coralie Graire, Marc Esch
  • Publication number: 20160023985
    Abstract: The invention relates to the industrial production of highly pure 2-propylheptyl acrylate with a high yield according to a process by transesterification, preferably in semi-continuous mode. The process according to the invention uses ethyl titanate in solution in 2-propylheptanol or 2-propylheptyl titanate as tranesterification catalyst, and implements a purification sequence comprising a single distillation column and a film evaporator.
    Type: Application
    Filed: February 24, 2014
    Publication date: January 28, 2016
    Inventors: Alain F. RIONDEL, Coralie GRAIRE
  • Publication number: 20150315120
    Abstract: The invention relates to the production of alkyl acrylate according to a continuous transesterification process. In one embodiment the process of the invention uses a simple column to purify a reaction mixture of acryl acrylate in one step yielding alkyl acrylate with a purity of greater than 99.8%.
    Type: Application
    Filed: December 16, 2013
    Publication date: November 5, 2015
    Applicant: Arkema France
    Inventors: Alain F. RIONDEL, Coralie GRAIRE, Marc ESCH, Andre LEVRAY
  • Publication number: 20150299093
    Abstract: The invention relates to a process for continuously producing 2-octyl acrylate by reacting acrylic acid and 2-octanol in the presence of a sulfonic acid esterification catalyst and at least one polymerization inhibitor. The water formed by the esterification reaction is entrained by distillation in a column surmounting the reactor in the form of a heteroazeotropic mixture with the 2-octanol which is then subjected, after condensation, to separation in a decanter so as to give an upper organic phase and a lower aqueous phase. The reaction mixture containing the reaction product and residual by-products are purified by separation means in order to obtain: (1) pure 2-octyl acrylate and (2) unreacted 2-octanol and acrylic acid compounds that will be recycled along with the catalyst.
    Type: Application
    Filed: October 30, 2012
    Publication date: October 22, 2015
    Inventors: Alain Riondel, Coralie GRAIRE, Andre LEVRAY, Reinhard LINEMANN
  • Publication number: 20150203436
    Abstract: The invention relates to the industrial production of 2-octyl acrylate of very high purity and with a high yield, using a continuous transesterification process. The method of the invention uses ethyl titanate in solution in 2-octanol or 2-octyl titanate as a transesterification catalyst, and employs a purification train comprising two distillation columns.
    Type: Application
    Filed: January 14, 2013
    Publication date: July 23, 2015
    Inventors: Alain Riondel, Coralie Graire, Marc Esch
  • Patent number: 9018410
    Abstract: The invention relates to the production of 2-octylacrylate of high purity and in good yield using ethyl titanate in solution in 2-octanol or 2-octyl titanate as a transesterification catalyst.
    Type: Grant
    Filed: January 14, 2013
    Date of Patent: April 28, 2015
    Assignee: Arkema France
    Inventors: Alain Riondel, Coralie Graire, Marc Esch, Reinhard Linemann
  • Patent number: 8940925
    Abstract: The invention relates to a method for producing N,N-dimethylaminoethyl acrylate by the transesterification reaction of an alykl acrylate by N1N-dimethylaminoethanol, and more particularly relates to a method for purifying the azeotropic fraction generated during said reaction, thereby enabling the recycling thereof on the alkyl acrylate production unit. The aim of the method of the invention is in particular to remove the acetaldehyde and the dialkoxyethane contained in the azeotropic fraction, either by the direct distillation of the azeotropic fraction or by the distillation of the aqueous phase resulting from the water scrubbing of the azeotropic fraction.
    Type: Grant
    Filed: January 27, 2010
    Date of Patent: January 27, 2015
    Assignee: Arkema France
    Inventors: Jean-Michel Paul, Coralie Graire, Audrey Riehl
  • Publication number: 20120035389
    Abstract: The invention relates to a method for producing N,N-dimethylaminoethyl acrylate by the transesterification reaction of an alykl acrylate by N1N-dimethylaminoethanol, and more particularly relates to a method for purifying the azeotropic fraction generated during said reaction, thereby enabling the recycling thereof on the alkyl acrylate production unit. The aim of the method of the invention is in particular to remove the acetaldehyde and the dialkoxyethane contained in the azeotropic fraction, either by the direct distillation of the azeotropic fraction or by the distillation of the aqueous phase resulting from the water scrubbing of the azeotropic fraction.
    Type: Application
    Filed: January 27, 2010
    Publication date: February 9, 2012
    Applicant: Arkema France
    Inventors: Jean-Michel Paul, Coralie Graire, Audrey Riehl