Patents by Inventor Cornel Hagiopol

Cornel Hagiopol has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230086996
    Abstract: Binder compositions and processes for making and using same. In some embodiments, the binder composition can include a urea-based compound, a bifunctional quaternary ammonium salt, and an aldehyde-based resin. In some embodiments, a resinated substrate can include a plurality of substrates and the binder composition. In some embodiments, a process for making a composite product can include contacting a plurality of substrates with the binder composition. The process can also include heating the resinated substrate to at least partially cure the aldehyde-based resin to produce the composite product. In some embodiments, a composite product can include the plurality of substrates and the aldehyde-based resin at least partially cured. In some embodiments, the plurality of substrates can include lignocellulosic substrates. In other embodiments, the plurality of substrates can include glass fibers.
    Type: Application
    Filed: January 20, 2021
    Publication date: March 23, 2023
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Sudhir Mulik, Robert Breyer, Cornel Hagiopol, Robert Miller
  • Patent number: 10738025
    Abstract: Modified polyphenol binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated monomer and at least one polyphenolic compound. The polyphenolic compound can include a lignin, a tannin, a novolac resin, a modified phenol formaldehyde resin, bis-phenol A, humic acid, or any mixture thereof.
    Type: Grant
    Filed: October 10, 2016
    Date of Patent: August 11, 2020
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, Derek L. Atkinson
  • Patent number: 10711401
    Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
    Type: Grant
    Filed: October 2, 2017
    Date of Patent: July 14, 2020
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
  • Patent number: 10633798
    Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
    Type: Grant
    Filed: December 4, 2017
    Date of Patent: April 28, 2020
    Assignee: ECOLAB USA INC.
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
  • Patent number: 10472549
    Abstract: Creping adhesives can include one or more crosslinked resins having the chemical formula (O), (P), or (Q), where RX can be a crosslinking moiety, each RY can independently be a substituted or unsubstituted organic diyl moiety, and each A? can independently be an anion. The creping adhesive can have a cylinder probe adhesion of about 100 gram-force to about 300 gram-force. The creping adhesive can have a peel adhesion of about 20 g/cm to about 110 g/cm.
    Type: Grant
    Filed: June 23, 2016
    Date of Patent: November 12, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol
  • Patent number: 10421212
    Abstract: Methods for making composite products are provided. In at least one specific embodiment, the method can include combining a plurality of lignocellulose substrates and one or more free radical precursors to produce a mixture of the lignocellulose substrates and the one or more free radical precursors. The method can also include maintaining the mixture at a temperature less than 60° C. for at least 10 minutes while retaining at least 11 wt % of the one or more free radical precursors charged to the mixture. The method can then include heating the mixture comprising at least 11 wt % of the one or more free radical precursors charged to the mixture to a temperature of at least 60° C. to about 300° C. to produce a composite product. The composite product can have a density less than 1 g/cm3 and an internal bond strength of at least 0.35 MPa.
    Type: Grant
    Filed: October 3, 2016
    Date of Patent: September 24, 2019
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Adam K. Sniady, Cornel Hagiopol, Derek L. Atkinson, Bobby L. Williamson, John B. Hines
  • Publication number: 20190169341
    Abstract: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
    Type: Application
    Filed: February 12, 2019
    Publication date: June 6, 2019
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Bobby L. Williamson, Adam K. Sniady, Brian L. Swift, Ramji Srinivasan, Feng Jing, Cornel Hagiopol
  • Patent number: 10301777
    Abstract: Wet strengthened fiber products, wet strengthening resins, and methods for making such wet strengthened fiber products and wet strengthening resins. The wet strengthened fiber product can include a fiber web and an at least partially cured wet strengthening resin, which prior to at least partially curing, the wet strengthening resin can include a polyamide-epihalohydrin (PAE) resin and a cationic styrene maleimide (SMI) resin. The PAE resin can include a reaction product of a polyamidoamine and an epihalohydrin and the cationic SMI resin can include a reaction product of a styrene maleic anhydride (SMA) copolymer and an amine. The wet strengthened fiber product can include the wet strengthening resin in an amount of about 0.05 wt % to about 5 wt %, based on a dried weight of the wet strengthened fiber product.
    Type: Grant
    Filed: June 27, 2017
    Date of Patent: May 28, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston
  • Patent number: 10227431
    Abstract: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
    Type: Grant
    Filed: September 14, 2018
    Date of Patent: March 12, 2019
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Bobby L. Williamson, Adam K. Sniady, Brian L. Swift, Ramji Srinivasan, Feng Jing, Cornel Hagiopol
  • Patent number: 10190261
    Abstract: Resin compositions, products made therewith, and methods for making such resin compositions and products. The resin composition can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound. The product can include a fiber web and an at least partially cured resin composition. The resin composition, prior to curing, can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound.
    Type: Grant
    Filed: June 26, 2017
    Date of Patent: January 29, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol, James W. Johnston, Frederick S. Potter
  • Publication number: 20190010269
    Abstract: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
    Type: Application
    Filed: September 14, 2018
    Publication date: January 10, 2019
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Bobby L. Williamson, Adam K. Sniady, Brian L. Swift, Ramji Srinivasan, Feng Jing, Cornel Hagiopol
  • Patent number: 10144818
    Abstract: Resins compositions and methods for making and using same. The resin composition can include a glyoxalated polyacrylamide resin and a polyamide-epihalohydrin resin. The polyamide-epihalohydrin resin can include a polyamine partially crosslinked with a bridging moiety and having azetidinium ions. The bridging moiety can be derived from a functionally symmetric crosslinker. A fiber product can include a plurality of fibers and the resin composition, where the resin composition can be at least partially cured.
    Type: Grant
    Filed: October 15, 2015
    Date of Patent: December 4, 2018
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, David F. Townsend, Cornel Hagiopol, James W. Johnston
  • Patent number: 10077328
    Abstract: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
    Type: Grant
    Filed: November 12, 2017
    Date of Patent: September 18, 2018
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Bobby L. Williamson, Adam K. Sniady, Brian L. Swift, Ramji Srinivasan, Feng Jing, Cornel Hagiopol
  • Publication number: 20180179427
    Abstract: Creping adhesives can include one or more crosslinked resins having the chemical formula (O), (P), or (Q), where RX can be a crosslinking moiety, each RY can independently be a substituted or unsubstituted organic diyl moiety, and each A? can independently be an anion. The creping adhesive can have a cylinder probe adhesion of about 100 gram-force to about 300 gram-force. The creping adhesive can have a peel adhesion of about 20 g/cm to about 110 g/cm.
    Type: Application
    Filed: June 23, 2016
    Publication date: June 28, 2018
    Applicant: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol
  • Patent number: 9982395
    Abstract: Strengthening resins and methods for making and using same. The strengthening resin can include a polyamine partially cross-linked with a bridging moiety and having azetidinium ions. The bridging moiety can be derived from a functionally symmetric cross-linker. The functionally symmetric cross-linker can include a diisocyanate, a 1,3-dialkyldiazetidine-2,4-dione, a dianhydride, a diacyl halide, a dienone, a dialkyl halide, or any mixture thereof.
    Type: Grant
    Filed: May 29, 2015
    Date of Patent: May 29, 2018
    Assignee: ECOLAB USA INC.
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson, Brian L. Swift, David R. Snead
  • Publication number: 20180112359
    Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
    Type: Application
    Filed: December 4, 2017
    Publication date: April 26, 2018
    Applicant: ECOLAB USA INC.
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
  • Publication number: 20180066092
    Abstract: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
    Type: Application
    Filed: November 12, 2017
    Publication date: March 8, 2018
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Bobby L. Williamson, Adam K. Sniady, Brian L. Swift, Ramji Srinivasan, Feng Jing, Cornel Hagiopol
  • Publication number: 20180023254
    Abstract: Compositions and methods related to new wet strength resins are provided. By using functionally-symmetrical cross-linkers and mono-functional modifiers, and separating the steps of reacting a prepolymer with the cross-linkers from the reaction of intermediate cross-linked prepolymer with epichlorohydrin, new wet strength resin products are provided having improved properties.
    Type: Application
    Filed: October 2, 2017
    Publication date: January 25, 2018
    Applicant: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, Cornel Hagiopol, Dexter C. Johnson
  • Patent number: 9834890
    Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.
    Type: Grant
    Filed: May 23, 2016
    Date of Patent: December 5, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
  • Patent number: 9815928
    Abstract: Binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated compound having two or more unsaturated carbon-carbon bonds and at least one free radical precursor. At least one of the unsaturated carbon-carbon bonds can be a pi-bond that is not conjugated with an aromatic moiety and can be capable of free radical addition. The free radical precursor can be present in an amount of about 7 wt % to about 99 wt %, based on the weight of the one or more unsaturated compounds.
    Type: Grant
    Filed: February 29, 2016
    Date of Patent: November 14, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Bobby L. Williamson, Adam K. Sniady, Brian L. Swift, Ramji Srinivasan, Feng Jing, Cornel Hagiopol