Patents by Inventor Cornelia Adriana De Wolf

Cornelia Adriana De Wolf has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10995257
    Abstract: A two-step process to produce oil or gas from a subterranean formation wherein in a first step the subterranean formation is treated with an aqueous composition containing a chelating agent selected from the group of glutamic acid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), and N-hydroxyethyl ethylenediamine N,N?,N?-triacetic acid or a salt thereof (HEDTA) and wherein, in a next step, in the outlet streams from the subterranean formation the aqueous phase is separated from the non-aqueous phase.
    Type: Grant
    Filed: June 14, 2013
    Date of Patent: May 4, 2021
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana De Wolf, Hisham Nasr-El-Din, Estevao De Oliveira Barra, Edwin Rudolf Antony Bang, Theodor Johannes Stanitzek
  • Patent number: 10301534
    Abstract: The present invention relates to a process for treating a sandstone formation comprising introducing a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) and having a pH of between 1 and 14 into the formation. The invention in addition relates to a fluid suitable for use in the above process containing 5-30 wt % of glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA), a corrosion inhibitor, a surfactant, and a mutual solvent.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: May 28, 2019
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana de Wolf, Mohamed Ahmed Nasr-El-Din Mahmoud, Hisham Nasr-El-Din
  • Patent number: 10294412
    Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.
    Type: Grant
    Filed: August 21, 2015
    Date of Patent: May 21, 2019
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana de Wolf, Hisham Nasr-El-Din, James N. LePage, Mohamed Ahmed Nasr-El-Din Mahmoud, Johanna Hendrika Bemelaar
  • Patent number: 9803134
    Abstract: An acidic aqueous solution containing a chelating agent and an acid, wherein the chelating agent is glutamic acid N,N-diacetic acid (GLDA) or a salt thereof, and wherein the amount of GLDA or the salt thereof is at least 10 wt %, based on the weight of the aqueous solution, and to the use thereof as an oilfield chemical, in descaling processes, or in processes in which highly concentrated aqueous acids are used, such as cleaning processes or plating processes.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: October 31, 2017
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana De Wolf, James N. Lepage, Johanna Hendrika Bemelaar
  • Patent number: 9745509
    Abstract: The present invention relates to a process to treat a subterranean formation by introducing a composition containing between 1 and 40 wt % on total weight of the composition of a chelating agent selected from the group of glutamic acid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), and methylglycine N,N-diacetic acid or a salt thereof (MGDA) into the formation, wherein the process comprises a soaking step.
    Type: Grant
    Filed: June 3, 2014
    Date of Patent: August 29, 2017
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hisham Nasr-El-Din, Cornelia Adriana De Wolf, Mohammed Ali Ibrahim Sayed, Estevao De Oliveira Barra
  • Patent number: 9725643
    Abstract: The present invention relates to a foam containing water, between 5 and 30 wt % on total weight of the foam of a chelating agent selected from the group of glutamic aid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), N-hydroxyethyl ethylenediamine-N,N?,N?-triacetic acid or a salt thereof (HEDTA), a foaming agent, and at least 25 vol % on total volume of the foam of a gas, and having a pH of between 2 and 5, to a viscosified composition containing water, between 5 and 30 wt % on total volume of the composition of a chelating agent selected from the group of glutamic aid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), N-hydroxyethyl ethylenediamine-N,N?,N?-triacetic acid or a salt thereof (HEDTA), and at least 0.
    Type: Grant
    Filed: April 24, 2013
    Date of Patent: August 8, 2017
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL, B.V.
    Inventors: Cornelia Adriana De Wolf, Hisham Nasr-El-Din, Edwin Rudolf Antony Bang, Guanqun Wang, Josef Johannes Maria Baltussen, Conrardus Hubertus Joseph Theeuwen, Boen Ho O, Marcel Cornelis Paulus Van Eijk
  • Patent number: 9587171
    Abstract: The present invention relates to a process for treating a subterranean formation wherein a fluid containing an ammonium salt of glutamic acid N,N-diacetic acid (GLDA) or methylglycine N,N-diacetic acid (MGDA) is introduced into the formation.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: March 7, 2017
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana De Wolf, James N. Lepage, Hisham Nasr-El-Din, Mohamed Ahmed Nasr-El-Din Mahmoud, Edwin Rudolf Antony Bang, Noble Thekkemelathethil George
  • Patent number: 9556378
    Abstract: The present invention relates to a chelating agent precursor that contains glutamic acid N,N-diacetic acid (GLDA) and/or methylglycine N,N-diacetic acid (MGDA) wherein at least one of the carboxylic acid groups is present as a carboxylic acid derivative selected from the group of amides, anhydrides, and esters, combinations thereof, and salts thereof, provided that it is not the triethyl ester of GLDA, the triethyl mono-t-butyl ester of GLDA, the tri-t-butyl ester of GLDA, the monobenzyl tri-t-butyl ester of GLDA, any ester or amide that contains azacycloalkane groups, any amide that contains biotin groups, any amide that contains minoethylcarbamoyl based amide groups, (S)-diethyl 2,2?-(1-benzyloxy)-1,5-dioxo-5-(prop-2-ynylamino)pentan-2-ylazanediyl-diacetate, diethyl 2,2?-(5-(3-azidopropylamino)-1-(benzyloxy)-1,5-dioxo-pentan-2-ylazanediyl-diacetate, the trimethyl ester of MGDA, the monomethyl ester dimethylamide of MGDA, the dibenzyl ester of MGDA, the dibenzyl mono t-butyl ester of MGDA, the di t-butyl est
    Type: Grant
    Filed: February 20, 2012
    Date of Patent: January 31, 2017
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: James N. Lepage, Cornelia Adriana De Wolf, Johanna Hendrika Bemelaar, Adrianus Maria Reichwein, Axel Carstens, Edwin Rudolf Antony Bang
  • Publication number: 20160115376
    Abstract: The present invention relatestoa process to treat a subterranean formation by introducing a composition containing between 1 and 40 wt % on total weight of the composition of a chelating agent selected from the group of glutamic acid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), and methylglycine N,N-diacetic acid or a salt thereof (MGDA) into the formation, wherein the process comprises a soaking step.
    Type: Application
    Filed: June 3, 2014
    Publication date: April 28, 2016
    Inventors: Hisham Nasr-El-Din, Cornelia Adriana De Wolf, Mohammed Ali Ibrahim Sayed, Estevao De Oliveira Barra
  • Publication number: 20150361330
    Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.
    Type: Application
    Filed: August 21, 2015
    Publication date: December 17, 2015
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana de Wolf, Hisham Nasr-El-Din, James N. LePage, Mohamed Ahmed Nasr-El-Din Mahmoud, Johanna Hendrika Bemelaar
  • Patent number: 9150780
    Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: October 6, 2015
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana de Wolf, Hisham Nasr-El-Din, James N. LePage, Mohamed Ahmed Nasr-El-Din Mahmoud, Johanna Hendrika Bemelaar
  • Publication number: 20150080271
    Abstract: The present invention relates to a foam containing water, between 5 and 30 wt % on total weight of the foam of a chelating agent selected from the group of glutamic aid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), N-hydroxyethyl ethylenediamine-N,N?,N?-triacetic acid or a salt thereof (HEDTA), a foaming agent, and at least 25 vol % on total volume of the foam of a gas, and having a pH of between 2 and 5, to a viscosified composition containing water, between 5 and 30 wt % on total volume of the composition of a chelating agent selected from the group of glutamic aid N,N-diacetic acid or a salt thereof (GLDA), aspartic acid N,N-diacetic acid or a salt thereof (ASDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA), N-hydroxyethyl ethylenediamine-N,N?,N?-triacetic acid or a salt thereof (HEDTA), and at least 0.
    Type: Application
    Filed: April 24, 2014
    Publication date: March 19, 2015
    Inventors: Cornelia Adriana De Wolf, Hisham Nasr-El-Din, Edwin Rudolf Antony Bang, Guanqun Wang, Josef Johannes Maria Baltussen, Conrardus Hubertus Joseph Theeuwen, Boen Ho O, Marcel Cornelis Paulus Van Eijk
  • Publication number: 20150005216
    Abstract: The present invention relates to the use of solutions containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) in treating subterranean formations, wherein the solutions contact carbon steel-containing equipment, and to a system containing a carbon steel-containing material in contact with a solution containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA), at elevated temperatures and/or employing carbon steel types as usually found in subterranean formations.
    Type: Application
    Filed: February 11, 2013
    Publication date: January 1, 2015
    Applicant: Akzo Nobel Chemicals International B.V.
    Inventors: Cornelia Adriana De Wolf, Albertus Jacobus Maria Bouwman, Hisham Nasr-El-Din
  • Publication number: 20140124205
    Abstract: The present invention relates to a process for fracturing a subterranean formation comprising a step of fracturing the formation and a step of introducing a treatment fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA) and/or N-hydroxyethyl ethylenediamine N,N?,N?-triacetic acid or a salt thereof (HEDTA) into the formation, wherein the fracturing step can take place before introducing the treatment fluid into the formation, while introducing the treatment fluid into the formation or subsequent to introducing the treatment fluid into the formation.
    Type: Application
    Filed: June 11, 2012
    Publication date: May 8, 2014
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hisham Nasr-El-Din, Mohamed Ahmed Nasr-El-Din Mahmoud, Cornelia Adriana De Wolf, Jia He
  • Publication number: 20140116710
    Abstract: The present invention relates to a process for treating a shale formation comprising introducing a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA),and/or N- hydroxyethyl ethylenediamine N,N?,N?-triacetic acid or a salt thereof (HEDTA) into the formation which process may optionally contain an additional fracturing step.
    Type: Application
    Filed: June 11, 2012
    Publication date: May 1, 2014
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hisham Naser-El-Din, Cornelia Adriana De Wolf, Mohamed Ahmed Nasr-El-Din Mahmoud
  • Publication number: 20140120276
    Abstract: The present invention relates to process to reduce the corrosion of equipment containing a chromium-containing alloy in the oil and/or gas industry, comprising a step of contacting the equipment based on a chromium-containing alloy with a solution containing at least 1 wt % on total weight of the solution of glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) having an acidic pH, the use of the above solutions in equipment containing a chromium-containing alloy to reduce corrosion, and to a system containing a piece of equipment used in the oil and/or gas industry made at least partly from chromium-containing alloy in contact with an acidic solution containing at least 1 wt % of glutamic acid N,N-di acetic acid or a salt thereof (GLDA) and/or methylglycine N,N-di acetic acid or a salt thereof (MGDA).
    Type: Application
    Filed: June 11, 2012
    Publication date: May 1, 2014
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana De Wolf, Albertus Jacobus Maria Bouwman, Hisham Nasr-El-Din
  • Publication number: 20130331304
    Abstract: The present invention relates to a chelating agent precursor that contains glutamic acid N,N-diacetic acid (GLDA) and/or methylglycine N,N-diacetic acid (MGDA) wherein at least one of the carboxylic acid groups is present as a carboxylic acid derivative selected from the group of amides, anhydrides, and esters, combinations thereof, and salts thereof, provided that it is not the triethyl ester of GLDA, the triethyl mono-t-butyl ester of GLDA, the tri-t-butyl ester of GLDA, the monobenzyl tri-t-butyl ester of GLDA, any ester or amide that contains azacycloalkane groups, any amide that contains biotin groups, any amide that contains minoethylcarbamoyl based amide groups, (S)-diethyl 2,2?-(1-benzyloxy)-1,5-dioxo-5-(prop-2-ynylamino)pentan-2-ylazanediyl-diacetate, diethyl 2,2?-(5-(3-azidopropylamino)-1-(benzyloxy)-1,5-dioxo-pentan-2-ylazanediyl-diacetate, the trimethyl ester of MGDA, the monomethyl ester dimethylamide of MGDA, the dibenzyl ester of MGDA, the dibenzyl mono t-butyl ester of MGDA, the di t-butyl est
    Type: Application
    Filed: February 20, 2012
    Publication date: December 12, 2013
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: James N. Lepage, Cornelia Adriana De Wolf, Johanna Hendrika Bemelaar, Adrianus Maria Reichwein, Axel Carstens, Edwin Rudolf Antony Bang
  • Publication number: 20130281329
    Abstract: The present invention relates to a process for treating a subterranean formation wherein a fluid containing an ammonium salt of glutamic acid N, N-diacetic acid (GLDA) or methylglycine N, N-diacetic acid (MGDA) is introduced into the formation.
    Type: Application
    Filed: December 14, 2011
    Publication date: October 24, 2013
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana De Wolf, James N. Lepage, Hisham Nasr-El-Din, Mohamed Ahmed Nasr-El-Din Mahmoud, Edwin Rudolf Antony Bang, Noble Thekkemelathethil George
  • Publication number: 20130274154
    Abstract: The present invention relates to a process for treating a sandstone formation comprising introducing a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and having a pH of between 1 and 14 into the formation. The invention in addition relates to a fluid and a kit of parts suitable for use in the above process containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA), a corrosion inhibitor, a surfactant, and optionally a mutual solvent.
    Type: Application
    Filed: December 14, 2011
    Publication date: October 17, 2013
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hisham Nasr-El-Din, Cornelia Adriana De Wolf, Mohamed Ahmed Nasr-El-Din Mahmoud, Albertus Jacobus Maria Bouwman, Noble Thekkemelathethil George
  • Publication number: 20130274155
    Abstract: The present invention relates to a process to control iron in a subterranean formation wherein a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) is introduced into the formation at a temperature between 77 and 400° F. (about 2 and 204° C.). The invention also covers a process of treating a subterranean formation wherein simultaneously iron control takes place.
    Type: Application
    Filed: December 14, 2011
    Publication date: October 17, 2013
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hisham Nasr-El-Din, James N. Lepage, Cornelia Adriana De Wolf, Mohamed Ahmed Nasr-El-Din Mahmoud, Ahmed Issam Elsayed Salama Assem