Abstract: The present invention lies in the fields of chemistry and materials engineering. More specifically, the present invention describes a process of heat treatment of polymeric precursors including as active phases particle charge or a mixture of active phases with inert phases called “fillers”. It is also described a surface including ceramic polymer obtained by said process. The volumetric positive variation resulting from the formation of new phases, which for their formation, incorporate atoms from the gaseous phase, contributes to a minor shrinkage of the composition during the heat treatment process. The process of the present invention allows obtaining the desired phases in smaller treatment times and lower temperatures, when compared to a thermal treatment process as conventional pyrolysis (PC) due to the presence of highly reactive species, as for example atomic nitrogen produced by the dissociation of nitrogen molecules in the plasma environment.

Abstract: The present invention describes a process for coating conductive component in a plasma reactor and a conductive component coating, wherein the process comprises the steps of cleaning, mechanical support deposition, topographic modification by plasma bombardment, chemical support layer deposition and amorphous carbon layer deposition (Diamond-Like Carbon). In one embodiment, the process is in single cycle. The present invention pertains to the fields of Materials Engineering, Physics and Chemistry.

Abstract: The present invention describes a process for coating conductive component in a plasma reactor and a conductive component coating, wherein the process includes the steps of cleaning, mechanical support deposition, topographic modification by plasma bombardment, chemical support layer deposition and amorphous carbon layer deposition (Diamond-Like Carbon). In one embodiment, the process is in single cycle. The present invention pertains to the fields of Materials Engineering, Physics and Chemistry.

Abstract: The metallurgical composition comprises a main particulate metallic material, for example iron or nickel, and at least one alloy element for hardening the main metallic material, which form a structural matrix; a particulate solid lubricant, such as graphite, hexagonal boron nitride or mixture thereof; and a particulate alloy element which is capable of forming, during the sintering of the composition conformed by compaction or by injection molding, a liquid phase, agglomerating the solid lubricant in discrete particles. The composition may comprise an alloy component to stabilize the alpha-iron matrix phase, during the sintering, in order to prevent the graphite solid lubricant from being solubilized in the iron. The invention further refers to the process for obtaining a self-lubricating sintered product.

Abstract: The reactor (R) has a reaction chamber (RC) provided with a support (S) for metallic pieces and with a system of an anode, connected to a ground, and of a cathode system connected to the support (S) and to a pulsating DC power supply. In the reaction chamber (RC), heated and supplied with a gas load, is formed, by means of an electric discharge in the cathode, a gas plasma. A liquid or gas precursor is admitted in at least one tubular cracking chamber associated with a high voltage energy source. It may be provided at least one tubular sputtering chamber associated with an electric power supply receiving a solid precursor. A potential difference is applied between the anode and one and/or other of said tubular chambers, to release the alloy elements to be ionically bombarded against the metallic pieces, either simultaneously or individually and in any order.

Abstract: The present invention describes the process for enriching the surface of ferromagnetic particles and coating ferromagnetic particles. More specifically the present invention describes the obtainment of materials developed by processes of: surface enrichment, surface oxidation, particle coating via dry powder mixing by tumbling, via reactions with boron compounds, via liquid glassy suspension and non-metallic compounds, and the possibility of using one or more of the techniques described concomitantly. The present invention is in the field of Mechanical Engineering, Electrical Engineering, Chemical Engineering and Materials Engineering.

Abstract: A process for the synthesis of nanostructured metallic hollow spherical particles, in which the metal is deposited onto sacrificial masks formed in a polymeric colloidal solution by the electroless autocatalytic deposition method. Deposition releases only gaseous products (N2 and H2) during the oxidation thereof, which evolve without leaving contaminants in the deposit. The particulate material includes nanostructured metallic hollow spherical particles with average diameter ranging from 100 nm to 5 ?m and low density with respect to the massic metal. A process for compacting and sintering a green test specimen are also described.

Abstract: The metallurgical composition comprises a main particulate metallic material, for example iron or nickel, and at least one alloy element for hardening the main metallic material, which form a structural matrix; a particulate solid lubricant, such as graphite, hexagonal boron nitride or mixture thereof; and a particulate alloy element which is capable of forming, during the sintering of the composition conformed by compaction or by injection molding, a liquid phase, agglomerating the solid lubricant in discrete particles. The composition may comprise an alloy component to stabilize the alpha-iron matrix phase, during the sintering, in order to prevent the graphite solid lubricant from being solubilized in the iron. The invention further refers to the process for obtaining a self-lubricating sintered product.

Abstract: The metallurgical composition comprises a main particulate metallic material, for example iron or nickel, and at least one alloy element for hardening the main metallic material, which form a structural matrix; a particulate solid lubricant, such as graphite, hexagonal boron nitride or mixture thereof; and a particulate alloy element which is capable of forming, during the sintering of the composition conformed by compaction or by injection molding, a liquid phase, agglomerating the solid lubricant in discrete particles. The composition may comprise an alloy component to stabilize the alpha-iron matrix phase, during the sintering, in order to prevent the graphite solid lubricant from being solubilized in the iron. The invention further refers to the process for obtaining a self-lubricating sintered product.

Abstract: The present invention lies in the fields of chemistry and materials engineering. More specifically, the present invention describes a process of heat treatment of polymeric precursors including as active phases particle charge or a mixture of active phases with inert phases called “fillers”. It is also described a surface including ceramic polymer obtained by said process. The volumetric positive variation resulting from the formation of new phases, which for their formation, incorporate atoms from the gaseous phase, contributes to a minor shrinkage of the composition during the heat treatment process. The process of the present invention allows obtaining the desired phases in smaller treatment times and lower temperatures, when compared to a thermal treatment process as conventional pyrolysis (PC) due to the presence of highly reactive species, as for example atomic nitrogen produced by the dissociation of nitrogen molecules in the plasma environment.

Abstract: The process comprises the steps of: mixing a load of oxide ceramic material particles (10) with a load of space holder particles (20), defined by graphite and/or amorphous carbon; compacting the mixture formed by ceramic material particles (10) and space holder particles (20), to form a compact body (E); and sintering said compact body (E), so that the ceramic material particles (10) form sintering contacts with each other, whereas the carbon of the space holder particles (20) is removed by the reaction with the oxygen in the sintering medium, to form open secondary pores (II), by eliminating the space holder particles (20). The metallurgic composition comprises the mixture of the ceramic material particles (10) with the space holder particles (20).

Abstract: The present invention describes a process for coating conductive component in a plasma reactor and a conductive component coating, wherein the process includes the steps of cleaning, mechanical support deposition, topographic modification by plasma bombardment, chemical support layer deposition and amorphous carbon layer deposition (Diamond-Like Carbon). In one embodiment, the process is in single cycle. The present invention pertains to the fields of Materials Engineering, Physics and Chemistry.

Abstract: The reactor (R) has a reaction chamber (RC) provided with a support (S) for metallic pieces and with a system of an anode, connected to a ground, and of a cathode system connected to the support (S) and to a pulsating DC power supply. In the reaction chamber (RC), heated and supplied with a gas load, is formed, by means of an electric discharge in the cathode, a gas plasma. A liquid or gas precursor is admitted in at least one tubular cracking chamber associated with a high voltage energy source. It may be provided at least one tubular sputtering chamber associated with an electric power supply receiving a solid precursor. A potential difference is applied between the anode and one and/or other of said tubular chambers, to release the alloy elements to be ionically bombarded against the metallic pieces, either simultaneously or individually and in any order.

Abstract: The plasma reactor comprises a reaction chamber (23) connectable to a source of ionizable gases (25) and to a heating device (80), said reactor (10) being subjected to the phases of heating (A), cleaning (L) and/or surface treatment (S), cooling (R), unloading (D) and loading (C) of metallic pieces (1). The installation comprises: at least two reactors (10), each being selectively and alternately connected to: the same source of ionizable gases (25); the same vacuum source (60); the same electrical energy source (50); and to the same heating device (80), the latter being displaceable between operative positions, in each of which surrounding laterally and superiorly a respective reactor (10), while the latter is in its heating phase (A) and cleaning phase (L) and/or in the surface treatment phase (S) of the metallic pieces (1).

Abstract: A process for the synthesis of nanostructured metallic hollow spherical particles, in which the metal is deposited onto sacrificial masks formed in a polymeric colloidal solution by the electroless autocatalytic deposition method. Deposition releases only gaseous products (N2 and H2) during the oxidation thereof, which evolve without leaving contaminants in the deposit. The particulate material includes nanostructured metallic hollow spherical particles with average diameter ranging from 100 nm to 5 ?m and low density with respect to the massic metal. A process for compacting and sintering a green test specimen are also described.

Abstract: The process basically comprises: dissolving a lamellar disulphide, as a source of the solid lubricant, in an aqueous solvent, forming a first aqueous solution; dissolving a reducing agent, as hydroxylamine, sodium hypophosphite or sodium borohydride, in an aqueous solvent, forming a second aqueous solution; mixing the first and second aqueous solutions, forming a third aqueous solution; neutralizing the pH of the third aqueous solution; dissolving a sulphur source, in an aqueous solvent, forming a fourth aqueous solution; mixing the third and fourth aqueous solutions, forming a fifth aqueous solution, which is contained and heated in an autoclave; cooling the fifth aqueous solution to the room temperature; and removing, from the autoclave, the nanoparticles in powder form.

Abstract: The process: includes mixing a metallic powder including iron or nickel or copper or mixtures of two or three elements thereof where the sum thereof defines at least 55% in mass of the metal matrix of the component to be produced, and a molybdenum disulfide powder as a densification agent and as a solid lubricant with a content from 3 to 30% in volume; filling a mold with the mixture and obtaining a compact presenting from 5 to 25% in volume of primary pores; and subjecting the compact to a temperature and time sufficient to allow the reaction of the molybdenum disulfide with the matrix, forming iron sulfide, nickel sulfide or copper sulfide, and the diffusion of the molybdenum in the matrix; and subjecting the compact to temperature sufficient to transform the sulfide into a liquid phase, filling the primary pores before finishing the sintering step of the compact.

Abstract: The metallurgical composition comprises a main particulate metallic material, for example iron or nickel, and at least one alloy element for hardening the main metallic material, which form a structural matrix; a particulate solid lubricant, such as graphite, hexagonal boron nitride or mixture thereof; and a particulate alloy element which is capable of forming, during the sintering of the composition conformed by compaction or by injection molding, a liquid phase, agglomerating the solid lubricant in discrete particles. The composition may comprise an alloy component to stabilize the alpha-iron matrix phase, during the sintering, in order to prevent the graphite solid lubricant from being solubilized in the iron. The invention further refers to the process for obtaining a self-lubricating sintered product.

Abstract: The plasma reactor comprises a reaction chamber (23) connectable to a source of ionizable gases (25) and to a heating device (80), said reactor (10) being subjected to the phases of heating (A), cleaning (L) and/or surface treatment (S), cooling (R), unloading (D) and loading (C) of metallic pieces (1). The installation comprises: at least two reactors (10), each being selectively and alternately connected to: the same source of ionizable gases (25); the same vacuum source (60); the same electrical energy source (50); and to the same heating device (80), the latter being displaceable between operative positions, in each of which surrounding laterally and superiorly a respective reactor (10), while the latter is in its heating phase (A) and cleaning phase (L) and/or in the surface treatment phase (S) of the metallic pieces (1).

Abstract: The metallurgical composition includes a main particulate metallic material, for example iron or nickel, and at least one alloy element for hardening the main metallic material, which form a structural matrix; a particulate solid lubricant, such as graphite, hexagonal boron nitride or mixture thereof; and a particulate alloy element which is capable of forming, during the sintering of the composition conformed by compaction or by injection molding, a liquid phase, agglomerating the solid lubricant in discrete particles. The composition may include an alloy component to stabilize the alpha-iron matrix phase, during the sintering, in order to prevent the graphite solid lubricant from being solubilized in the iron. The invention further refers to a self-lubricating sintered product, obtained from the composition, and to the process for obtaining said product.