Abstract: The present invention relates to a method for the synthesis of certain perfluoropolyether polymers having well-defined recurring units structure, and whereas the fraction of reactive end groups can be easily tuned.

Abstract: The present invention relates to a method for exchanging heat with an object said method comprising using a heat transfer fluid wherein said heat transfer fluid comprises one or more chemical compounds having the general formula: Rf—O—CF2—O—CX?CYZ (I) wherein Rf can be any C2-C6 linear, branched or C5C6 cyclic saturated carbon chain which can be partially or fully fluorinated, and can comprise 0-5 Oxygen atoms which, when present, are all engaged in ether bonds, and wherein X, Y and Z can be independently selected from halogens or hydrogen, with the proviso that at least one of X, Y or Z is a halogen.

Abstract: The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).

Abstract: The invention relates to a method for manufacturing low-molecular-weight polytetrafluoroethylene, comprising: a) a first step of mixing high-molecular-weight polytetrafluoroethylene with at least one additive selected from the group consisting of ethers having formula R1—O—R2, wherein R1 and R2 are independently selected among C1-C10 straight or branched aliphatic group, C4-C10 alicyclic or heterocyclic groups, C5-C10 aromatic or heteroaromatic groups; (per)fluorinated vinyl ethers; (per)fluorinated olefins; and optionally substituted aromatic hydrocarbons, and b) a second step of irradiating the so obtained mixture with ionizing radiation, said second step b) being carried out substantially in the absence of oxygen.

Abstract: The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).

Abstract: The present invention relates to a method for exchanging heat with an object said method comprising using a heat transfer fluid wherein said heat transfer fluid comprises one or more chemical compounds having the general formula: (I) wherein: R1, R2, R3, R4 can be the same or different, linear or branched, partially fluorinated alkyl groups having a C1-C6 carbon chain.

Abstract: The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).

Abstract: The present invention relates to a method for the synthesis of certain perfluoropolyether polymers having well-defined recurring units structure, and whereas the fraction of reactive end groups can be easily tuned.

Abstract: A process for the preparation of fluorinated compounds having at least one —OSF5 group, said method comprising the step of reacting SOF4 with a fluorinated 3- or 4-membered cyclic ether in the presence of a fluoride catalyst.

Abstract: The invention pertains to a fluoroelastomer composition [composition (C)] comprising: —at least one fluoroelastomer [fluoroelastomer (A)]; —at least one basic compound [base (B)]; —at least one pyridinium-type salt [salt (P)] having at least two groups in ortho or para position to the quaternized nitrogen bearing a reactive hydrogen atom.

Abstract: The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).

Abstract: A process for the preparation of fluorinated compounds having at least one —OSF5 group, said method comprising the step of reacting SOF4 with a fluorinated 3- or 4-membered cyclic ether in the presence of a fluoride catalyst.

Abstract: A process for the preparation of fluorinated compounds having at least one —OSF5 group, said method comprising the step of reacting SOF4 with a fluorinated 3- or 4-membered cyclic ether in the presence of a fluoride catalyst.

Abstract: The invention pertains to a fluoroelastomer composition [composition (C)] comprising:—at least one fluoroelastomer [fluoroelastomer (A)];—at least one basic compound [base (B)];—at least one pyridinium-type salt [salt (P)] having at least two groups in ortho or para position to the quaternized nitrogen bearing a reactive hydrogen atom.

Abstract: A process for the preparation of the fluoroalkyl sulfonate salt of a nitrogen-based organic base said process comprising the step of reacting a fluoroalkyl sulfonyl halide with an organic base selected from the group consisting of tertiary amines, pyridines, amidines and guanidines.

Abstract: The present invention pertains to a composition comprising: (I) at least one ionic liquid of formula (1-a) or of formula (1-b): [RF-CFR?F-SO3]? A+ (1-a) [(RF-CFR?F—SO2)2N]? (1-b) wherein: -RF is a C1-C25 fluoroalkyi group, optionally comprising one or more than one catenary ethereal oxygen atoms, -R?F is —F or a —CF3 group, and -A+ is an organic cation selected from the group consisting of tetraalkylammonium, pyridinium, imidazolium, piperidinium, pyrrolidinium, amidinium and guanidinium groups, and (II) at least one metal salt of formula (II): MeB, (H) wherein: -Mem+ is a metal cation deriving from a metal (Me) selected from the group consisting of groups IB, MB, IVB, VB, VIB, MIA, IVA and VIII (8, 9, 10) of the Periodic Table, preferably from the group consisting of groups IVB, VB, VIB and IMA of the Periodic Table, wherein m is the valence of said metal cation, and —Bn? is an inorganic anion, wherein n is the valence of said inorganic anion.

Abstract: The present invention pertains a fluoropolymer [polymer (F)] comprising: —recurring units derived from at least one ethylenically unsaturated fluorinated monomer [monomer (FM)]; —from 5% to 60% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived at least one ethylenically unsaturated fluorinated monomer containing at least one —SO2F functional group [monomer (IO)]; and —from 0.01% to 10% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from at least one monomer comprising an azide group [monomer (Az)], to a process for its manufacture, to a cross-linkable composition comprising the same, to a process for cross-linking the same and to articles comprising the cross-linked polymer.

Abstract: A compound of formula CF2?CFCF2OSF5 and polymers comprising recurring units deriving from CF2?CFCF2OSF5 are disclosed as well as processes for their preparation.

Abstract: A process for fluorinating hydrocarbon compounds, which comprises: A. providing a compound selected from the group consisting of straight-chain, branched-chain and cyclic alkanes, straight-chain, branched-chain and cyclic ethers, said compound comprising at least one carbon-hydrogen bond and being free from —C(O)— functional groups; B. reacting said compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a compound wherein at least one carbon-hydrogen bond has been replaced by a carbon-fluorine bond. Compositions of partially fluorinated compounds obtained with the process are also disclosed.

Abstract: A process for the preparation of the fluoroalkyl sulfonate salt of a nitrogen-based organic base said process comprising the step of reacting a fluoroalkyl sulfonyl halide with an organic base selected from the group consisting of tertiary amines, pyridines, amidines and guanidines.