Abstract: A method of forming a solid, dense, hermetic lithium-ion electrolyte membrane comprises combing an amorphous, glassy, or low melting temperature solid reactant with a refractory oxide reactant to form a mixture, casting the mixture to form a green body, and sintering the green body to form a solid membrane. The resulting electrolyte membranes can be incorporated into lithium-ion batteries.

Abstract: A gallium doped garnet composition of the formula: Li7?3yLa3Zr2GayO12 where y is from 0.4 to 2.0, and as defined herein. Also disclosed is a method for making a dense Li-ion conductive cubic garnet membrane, comprising one of two alternative lower temperature routes, as defined herein.

Abstract: A method of making a ceramic honeycomb article which includes: applying at least one green membrane coating layer on a green substrate, the green substrate comprising a plurality of cells comprised of a plurality of interior channels and a plurality of porous interior walls between the channels; drying the at least one green membrane coating layer on the green substrate to produce a green coated substrate; and firing the green coated substrate into a porous substrate, wherein applying the at least one green membrane coating layer and the drying the at least one green membrane coating layer are repeated from 2 to 10 times prior to firing to form multiple green membrane coating layers on the green substrate and wherein the firing the green coated substrate forms a ceramic honeycomb article comprised of the porous substrate and multiple fired coating layers on the porous substrate.

Abstract: Disclosed herein are filtration articles comprising a porous ceramic structure comprising a plurality of channels separated by a plurality of porous interior walls, and a nanomembrane disposed on at least a portion of a surface of the porous ceramic structure, wherein the nanomembrane comprises nanoparticles of at least one inorganic oxide, and wherein the nanoparticles are present in a concentration ranging from about 0.001 g/L to about 1 g/L based on the total volume of the porous ceramic structure. Methods for making such filtration articles and methods for filtering a particulate from a fluid using such filtration articles are also disclosed herein.

Abstract: An inorganic membrane filtration article and methods for making the same. The membrane filtration article includes a sintered flow-through ceramic honeycomb with a plurality of partition walls defining a plurality of open channels from an inlet end of the honeycomb to an outlet end of the honeycomb. The honeycomb is formed from a cordierite composition with low-sodium and/or low-potassium content for enhanced filtration performance.

Abstract: A gallium doped garnet composition of the formula: Li7-3yLa3Zr2GayO12 where y is from 0.4 to 2.0, and as defined herein. Also disclosed is a method for making a dense Li-ion conductive cubic garnet membrane, comprising one of two alternative lower temperature routes, as defined herein.

Abstract: A gallium doped garnet composition of the formula: Li7-3yLa3Zr2GayO12 where y is from 0.4 to 2.0, and as defined herein. Also disclosed is a method for making a dense Li-ion conductive cubic garnet membrane, comprising one of two alternative lower temperature routes, as defined herein.

Abstract: A method of producing bi-modal particles includes the steps of igniting a first precursor gas using a primary burner thereby producing a first plurality of particles of a first size, fluidly transporting the first plurality of particles down a particle tube, igniting a second precursor gas using a secondary burner thereby producing a second plurality of particles of a second size, flowing the second plurality of particles into the first plurality of particles, and capturing the first and second plurality of particles.

Abstract: A membrane filter article including: a porous substrate, as defined herein; and a porous first layer, as defined herein, on the porous interior walls of the substrate, wherein the porous first layer has a pore size property as defined herein. Also disclosed is a method of making and using the membrane filter article.

Abstract: A gallium doped garnet composition of the formula: Li7-3yLa3Zr2GayO12 where y is from 0.4 to 2.0, and as defined herein. Also disclosed is a method for making a dense Li-ion conductive cubic garnet membrane, comprising one of two alternative lower temperature routes, as defined herein.

Abstract: A process and system for applying coating materials to glass edges of various profiles. The glass edge is coated by picking up the coating material from an applicator such as, for example, a roller, through precise independent or relative control of the spatial relationship between the edge of the glass article and the applicator to achieve desirable product attributes such as coating thickness, profile, coverage areas and consistency. Such spatial relationships include the gap distance between the roller and applicator, coating thickness on the applicator, applicator and/or glass speed, and the like.

Abstract: An insulating glass-ceramic substrate for synthesizing graphene includes discrete, crystalline, nanophase metallic regions capable of catalyzing graphene growth. The nanophase regions may be formed by thermal treatment of a glass-ceramic substrate containing the corresponding metal oxide. Single layer and double layer graphene are prepared on the modified glass-ceramic substrate in a vacuum chemical vapor deposition (CVD) process from hydrocarbon precursors. The graphene-coated glass-ceramic substrate is electrically conductive.

Abstract: A coating apparatus includes modular interfaces and substrate receptors for accommodating various shapes and sizes of monolith substrates when coating layers are applied onto the monolith substrates. The monolith substrates are laterally surrounded by an elastically deformable sleeve that prevents lateral leakage of a vacuum out of the monolith substrate when a vacuum is applied to opposing ends of the monolith substrate, thereby eliminating needs for bulky vacuum chambers. The coating apparatus also includes valves and control apparatus that enable excess precursor liquid to be drained from monolith channels in-situ, without the use of additional spin-drying steps. Coating methods for using the coating apparatus are provided.

Abstract: An insulating glass-ceramic substrate for synthesizing graphene includes discrete, crystalline, nanophase metallic regions capable of catalyzing graphene growth. The nanophase regions may be formed by thermal treatment of a glass-ceramic substrate containing the corresponding metal oxide. Single layer and double layer graphene are prepared on the modified glass-ceramic substrate in a vacuum chemical vapor deposition (CVD) process from hydrocarbon precursors. The graphene-coated glass-ceramic substrate is electrically conductive.

Abstract: Wall flow membrane filters, fabricated by masking a first subset of the channels at one or both ends of a honeycomb body comprising an array of open-ended through-channels separated by porous channel walls, applying a membrane-forming composition to the porous channel walls of a second subset of the channels, curing the membrane-forming composition to provide a wall-adhering fluid-permeable membrane; and then plugging the first subset of channels at a first end of the body and the second subset of channels at a second end of the body, are useful in exhaust systems of improved particulate filtration efficiency for gasoline direct injection or diesel engines.

Abstract: A flame spray pyrolysis method for making nanoscale, lithium ion-conductive ceramic powders comprises providing a precursor solution comprising chemical precursors dissolved in an organic solvent, and spraying the precursor solution into an oxidizing flame to form a nanoscale, lithium ion-conductive ceramic powder, wherein a concentration of the chemical precursors in the solvent ranges from 1 to 20 M. The precursor solution can comprise 1-20% excess lithium with respect to a stoichiometric composition of the ceramic powder. Nominal compositions of the nanoscale, ceramic powders are Li1.4Al0.4M1.6(PO4)3 where M is Ti or Ge.

Abstract: A flame spray pyrolysis method for making nanoscale, lithium ion-conductive ceramic powders comprises providing a precursor solution comprising chemical precursors dissolved in an organic solvent, and spraying the precursor solution into an oxidizing flame to form a nanoscale, lithium ion-conductive ceramic powder, wherein a concentration of the chemical precursors in the solvent ranges from 1 to 20 M. The precursor solution can comprise 1-20% excess lithium with respect to a stoichiometric composition of the ceramic powder. Nominal compositions of the nanoscale, ceramic powders are Li1.4Al0.4M1.6(PO4)3 where M is Ti or Ge.

Abstract: A method and apparatus for applying a uniform membrane coating to a substrate, such as a honeycomb structure, having a plurality of through-channels, wherein the through-channels have an average diameter of less than or equal to 3 mm. The method includes providing a liquid precursor comprising membrane-forming materials to the substrate and applying a pressure differential across the substrate. The pressure differential causes the liquid precursor to travel uniformly through the through-channels, depositing the membrane-forming materials on the walls of the through-channels and forming the membrane on the walls of the through-channels. The apparatus includes a chamber capable of holding the substrate and of maintaining a pressure differential across the plurality of through-channels.

Abstract: A method of forming a solid, dense, hermetic lithium-ion electrolyte membrane comprises combing an amorphous, glassy, or low melting temperature solid reactant with a refractory oxide reactant to form a mixture, casting the mixture to form a green body, and sintering the green body to form a solid membrane. The resulting electrolyte membranes can be incorporated into lithium-ion batteries.

Abstract: A coating apparatus includes modular interfaces and substrate receptors for accommodating various shapes and sizes of monolith substrates when coating layers are applied onto the monolith substrates. The monolith substrates are laterally surrounded by an elastically deformable sleeve that prevents lateral leakage of a vacuum out of the monolith substrate when a vacuum is applied to opposing ends of the monolith substrate, thereby eliminating needs for bulky vacuum chambers. The coating apparatus also includes valves and control apparatus that enable excess precursor liquid to be drained from monolith channels in-situ, without the use of additional spin-drying steps. Coating methods for using the coating apparatus are provided.