Abstract: Methanol steam reforming catalysts, and steam reformers and fuel cell systems incorporating the same. In some embodiments, the methanol steam reforming catalyst includes zinc oxide as an active component. In some embodiments, the methanol steam reforming catalyst further includes at least one of chromium oxide and calcium aluminate. In some embodiments, the methanol steam reforming catalyst is not pyrophoric. Similarly, in some embodiments, steam reformers including a reforming catalyst according to the present disclosure may include an air-permeable or air-accessible reforming catalyst bed. In some embodiments, the methanol steam reforming catalyst is not reduced during use. In some embodiments, the methanol reforming catalysts are not active at temperatures below 275° C. In some embodiments, the methanol steam reforming catalyst includes a sulfur-absorbent material. Steam reformers, reforming systems, fuel cell systems and methods of using the reforming catalysts are also disclosed.

Abstract: Fuel cell systems that include at least one fuel cell stack adapted to receive a fuel stream containing hydrogen gas or other proton source, and an oxidant stream containing oxygen gas. The systems include an oxidant supply system adapted to deliver an enriched, or concentrated, oxidant stream to the fuel cell stack. In some embodiments, the oxidant supply system is adapted to receive an air stream and produce an oxygen-enriched stream therefrom. In some embodiments, the fuel cell system includes a water-recovery system adapted to recover water produced in the fuel cell stack, such as may be recovered from the cathode exhaust stream from the fuel cell stack. In some embodiments, the recovered water is utilized as at least a portion of a feed stream for the fuel cell system, such as for a reformer or electrolyzer that produces hydrogen used as fuel for the fuel cell stack.

Abstract: Methanol steam reforming catalysts, and steam reformers and fuel cell systems incorporating the same. In some embodiments, the methanol steam reforming catalyst includes zinc oxide as an active component. In some embodiments, the methanol steam reforming catalyst further includes at least one of chromium oxide and calcium aluminate. In some embodiments, the methanol steam reforming catalyst is not pyrophoric. Similarly, in some embodiments, steam reformers including a reforming catalyst according to the present disclosure may include an air-permeable or air-accessible reforming catalyst bed. In some embodiments, the methanol steam reforming catalyst is not reduced during use. In some embodiments, the methanol reforming catalysts are not active at temperatures below 275° C. In some embodiments, the methanol steam reforming catalyst includes a sulfur-absorbent material. Steam reformers, reforming systems, fuel cell systems and methods of using the reforming catalysts are also disclosed.

Abstract: Diffusion and atomizing burner assemblies and fuel processing and fuel cell systems containing the same. The burner assembly receives at least one liquid and/or gaseous fuel stream, mixes the stream with air, and combusts the mixed stream to provide heat for a fuel processor. In some embodiments, the burner assembly receives at least one combustible fuel stream produced by the fuel processing and/or fuel cell system. In some embodiments, the burner assembly receives a fuel stream having the same composition as a stream that is delivered for non-combustion purposes to another portion of the fuel processing and/or fuel cell system. In some embodiments, the burner assembly receives and vaporizes a fuel stream that includes the same carbon-containing feedstock and/or has the same overall composition as the feed stream from which the steam reformer or other fuel processor produces hydrogen gas. Methods of use are also disclosed.

Abstract: Feedstock delivery systems for fuel processors, and fuel processing systems incorporating the same. In some embodiments, the feedstock delivery system includes at least one pressurized tank or other reservoir that is adapted to store in liquid form a feedstock for a fuel processor. The delivery system further includes a pressurization assembly that is adapted to pressurize the reservoir by delivering a stream of pressurized gas thereto. In some embodiments, the gas is at least substantially comprised of nitrogen or other inert gases. In some embodiments, the gas is a nitrogen-enriched or a reduced-oxygen air stream. In some embodiments, the delivery system includes a sensor assembly that is adapted to monitor the concentration of oxygen in, and/or being delivered to, the reservoir(s). In some embodiments, the delivery system includes a pumpless delivery system that regulates the delivery under pressure of the feedstock from the tank to the fuel processor.