Abstract: A transfer method and system (8) to discharge overflow slurry from a polymerization reactor (10) to a tank (14). The method includes thermally isolating a conduit extension (28) at a distal end of a transfer line (20) from a quench fluid inlet (42) to a quench chamber (12). The transfer system (8) is characterized by an annular thermal barrier around the conduit extension (28) that can include insulation (34) and/or thermally resistant support ring (36), and a trap-free conduit (20) in fluid communication between the reactor (10) and the conduit extension (28). The transfer method and system can reduce or eliminate incidents of transfer line (20) plugging in the manufacture of isoolefin polymers and copolymers.

Abstract: Provided for herein is a process for separating a hydrocarbon-rubber from a hydrofluorocarbon diluent comprising contacting a polymer slurry comprising the hydrocarbon-rubber dispersed within the hydrofluorocarbon diluent with a hydrocarbon solvent capable of dissolving the hydrocarbon-rubber, to produce a first liquid phase and a second liquid phase, and separating the first liquid phase from the second liquid phase.

Abstract: A transfer method and system (8) to discharge overflow slurry from a polymerization reactor (10) to a tank (14). The method includes thermally isolating a conduit extension (28) at a distal end of a transfer line (20) from a quench fluid inlet (42) to a quench chamber (12). The transfer system (8) is characterized by an annular thermal barrier around the conduit extension (28) that can include insulation (34) and/or thermally resistant support ring (36), and a trap-free conduit (20) in fluid communication between the reactor (10) and the conduit extension (28). The transfer method and system can reduce or eliminate incidents of transfer line (20) plugging in the manufacture of isoolefin polymers and copolymers.

Abstract: Provided for herein is a process to produce an essentially homogeneous single liquid phase hydrocarbon-rubber cement from a polymer slurry comprising a hydrocarbon-rubber, a diluent, and unreacted monomer(s), the process comprising: (a) contacting the polymer slurry with a hydrocarbon solvent; and (b) removing the diluent in amounts not sufficiently more than is necessary to produce the essentially homogeneous single liquid phase hydrocarbon-rubber cement wherein the mass fraction of monomer(s) in the hydrocarbon-rubber cement, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber cement, is less than the mass fraction of monomer(s) in the hydrocarbon-rubber slurry, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber slurry, wherein the diluent comprises a hydrofluorocarbon.

Abstract: Provided for herein is a process for separating a hydrocarbon-rubber from a hydrofluorocarbon diluent comprising contacting a polymer slurry comprising the hydrocarbon-rubber dispersed within the hydrofluorocarbon diluent with a hydrocarbon solvent capable of dissolving the hydrocarbon-rubber, to produce a first liquid phase and a second liquid phase, and separating the first liquid phase from the second liquid phase.