Abstract: One embodiment of the present specification provides a siloxane compound represented by Chemical Formula 1 below: In Chemical Formula 1, R1a and R1b are each independently a substituted or unsubstituted straight or branched-chain alkyl group having 1 to 16 carbon atoms, R2a and R2b are each independently a substituted or unsubstituted straight or branched-chain alkyl group having 1 to 16 carbon atoms, R3a and R3b are each independently a substituted or unsubstituted straight or branched-chain alkylene group having 1 to 16 carbon atoms, R4a, R4b, R5a, and R5b are each independently hydrogen, a substituted or unsubstituted straight or branched alkyl group having 1 to 16 carbon atoms, or a substituted or unsubstituted straight or branched-chain heteroalkyl group having 1 to 16 carbon atoms, m1 and m2 are each an integer from 0 to 2, and when m1 and m2 are each 0, a plurality of OR2a and OR2b are the same or different, and when m1 and m2 are each 2, a plurality of R1a and R1b are the same or different, and x

Abstract: Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido or alcoxy group is introduced is coordinated, a method of synthesizing the same, and olefin polymerization using the transition metal complex. Compared to a conventional transition metal complex having a silicon bridge and an oxido ligand, the transition metal complex has a phenylene bridge, so that a monomer easily approaches the transition metal complex in terms of structure and a pentagon ring structure of the transition metal complex is stably maintained. The catalyst composition including the transition metal complex is used to synthesize a polyolefin copolymer having a very low density less than 0.910 g/cc.

Abstract: Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amine-based group is introduced is coordinated, a method of synthesizing the same, and olefin polymerization using the transition metal complex In the novel transition metal complex, an imino phenyl group is not cross-linked to a metal atom and directly introduced to a cyclopentadiene (Cp) ring. The catalyst composition including the transition metal compound is used to obtain a polyolefin copolymer having a very low density less than 0.910 g/cc.