Patents by Inventor Daisuke Asahina
Daisuke Asahina has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10676628Abstract: A surface treatment liquid composition for a substrate is provided. The surface treatment liquid composition includes a water-soluble salt, water, and a resin particle including a resin having a structural unit represented by the following formula (1): where R1 represents —COO—; each of R2 and R3 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and n represents an integer of from 5 to 100.Type: GrantFiled: May 15, 2017Date of Patent: June 9, 2020Assignee: Ricoh Company, Ltd.Inventors: Takuya Saiga, Satoyuki Sekiguchi, Ryo Miyakoshi, Daisuke Asahina
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Patent number: 10564557Abstract: A toner including polyester, wherein an amount of heat of a peak derived from the polyester in a range of from 40° C. through 70° C. during a cooling process is from 1.0 J/g through 15 J/g in differential scanning calorimetry performed under conditions below, <measuring conditions> after maintaining the toner at ?20° C., heating the toner to 130° C. at 10° C./min (a first heating process), after maintaining the toner at 130° C. for 1 minute, cooling the toner to ?50° C. at cooling speed of 10° C./min (the cooling process), and after maintaining the toner at ?50° C. for 5 minutes, heating the toner to 130° C. at 10° C./min (a second heating process).Type: GrantFiled: April 17, 2018Date of Patent: February 18, 2020Assignee: Ricoh Company, Ltd.Inventors: Ryo Miyakoshi, Daisuke Asahina, Yoshihiro Moriya, Satoshi Kojima, Satoshi Takahashi
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Publication number: 20200048482Abstract: An ink includes a solvent and a resin, wherein the storage elastic modulus G1 of an ink film obtained by drying the ink is 2.0×108-5.0×108 Pa at 20 degrees C. as measured by a dynamic viscoelasticity measuring method and the ratio (G2/G1) of the storage elastic modulus G1 to the storage elastic modulus G2 of the ink film measured at 80 degrees C. by the dynamic viscoelasticity measuring method is 0.30-0.85.Type: ApplicationFiled: October 18, 2019Publication date: February 13, 2020Inventors: Satoyuki Sekiguchi, Daisuke Asahina, Yuusuke Fujita
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Patent number: 10513619Abstract: An ink includes a solvent and a resin, wherein the storage elastic modulus G1 of an ink film obtained by drying the ink is 2.0×108-5.0×108 Pa at 20 degrees C. as measured by a dynamic viscoelasticity measuring method and the ratio (G2/G1) of the storage elastic modulus G1 to the storage elastic modulus G2 of the ink film measured at 80 degrees C. by the dynamic viscoelasticity measuring method is 0.30-0.85.Type: GrantFiled: October 19, 2016Date of Patent: December 24, 2019Assignee: Ricoh Company, Ltd.Inventors: Satoyuki Sekiguchi, Daisuke Asahina, Yuusuke Fujita
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Patent number: 10156801Abstract: A toner, including: a colorant; a binder resin; and a releasing agent, wherein the binder resin includes a polyester resin, and the toner satisfies requirements (1) and (2) below: (1): G?(50)?3.0×107 Pa and 1.0×105 Pa?G?(60)?1.0×107 Pa, where G?(50) is a storage modulus at 50° C. of the toner and G?(60) is a storage modulus at 60° C. of the toner; and (2): a spin-spin relaxation time of the toner at 50° C. measured by solid echo method of pulse NMR is 1.0 ms or shorter.Type: GrantFiled: August 13, 2014Date of Patent: December 18, 2018Assignee: Ricoh Company, Ltd.Inventors: Kohsuke Nagata, Shinya Nakayama, Tsuyoshi Sugimoto, Daisuke Asahina, Susumu Chiba
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Patent number: 10078296Abstract: A member for an image forming apparatus includes a surface layer including a block copolymer, wherein the block copolymer includes a polyamide block and a polyether block and the composition ratio of the polyether block to the polyamide block is from 0.2 to 1.5.Type: GrantFiled: May 31, 2017Date of Patent: September 18, 2018Assignee: RICOH COMPANY, LTD.Inventors: Ryo Miyakoshi, Hidetoshi Fujii, Akira Izutani, Daisuke Asahina
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Publication number: 20180231902Abstract: A toner including polyester, wherein an amount of heat of a peak derived from the polyester in a range of from 40° C. through 70° C. during a cooling process is from 1.0 J/g through 15 J/g in differential scanning calorimetry performed under conditions below, <measuring conditions> after maintaining the toner at ?20° C., heating the toner to 130° C. at 10° C./min (a first heating process), after maintaining the toner at 130° C. for 1 minute, cooling the toner to ?50° C. at cooling speed of 10° C./min (the cooling process), and after maintaining the toner at ?50° C. for 5 minutes, heating the toner to 130° C. at 10° C./min (a second heating process).Type: ApplicationFiled: April 17, 2018Publication date: August 16, 2018Inventors: Ryo Miyakoshi, Daisuke Asahina, Yoshihiro Moriya, Satoshi Kojima, Satoshi Takahashi
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Patent number: 9885967Abstract: Provided is a resin for a toner, which is a copolymer including a crystalline segment, and having a maximum elastic stress value at 100° C. (ES100) of 1,000 Pa or less, and a maximum elastic stress value at 70° C. (ES70) of 1,000 Pa or greater when the temperature is lowered from 100° C. to 70° C., where the maximum elastic stress values are measured according to a large amplitude oscillatory shear procedure.Type: GrantFiled: August 13, 2014Date of Patent: February 6, 2018Assignee: Ricoh Company, Ltd.Inventors: Azumi Miyaake, Daisuke Asahina, Toyoshi Sawada, Hiroshi Yamashita, Tsuyoshi Sugimoto, Shinya Nakayama, Susumu Chiba, Satoyuki Sekiguchi
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Patent number: 9851649Abstract: A toner includes a binder resin including a copolymer resin containing structural units derived from crystalline and non-crystalline resins, respectively. Spin-spin relaxation time (t50) of the toner at 50° C. measured by pulse NMR is ?0.05 msec., spin-spin relaxation time (t130) at 130° C. when warmed from 50° C. to 130° C. is >15 msec., and spin-spin relaxation time (t?70) at 70° C. when cooled from 130° C. to 70° C. is ?1.00 msec. A binarized image obtained by binarizing a phase image of the toner observed by a tapping mode AFM based on intermediate value between maximum and minimum phase difference values in the phase image includes first phase difference images constituted by large phase-difference portions and a second phase difference image constituted by a small phase-difference portion. The first phase difference images are dispersed in the second phase difference image. The dispersion diameter of the first phase difference images is 150 nm or less.Type: GrantFiled: November 27, 2013Date of Patent: December 26, 2017Assignee: Ricoh Company, Ltd.Inventors: Keiji Makabe, Tsuyoshi Sugimoto, Akinori Saito, Suzuka Amemori, Toyoshi Sawada, Hiroshi Yamashita, Shinya Nakayama, Atsushi Yamamoto, Daisuke Asahina, Satoyuki Sekiguchi
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Publication number: 20170355868Abstract: A surface treatment liquid composition for a substrate is provided. The surface treatment liquid composition includes a water-soluble salt, water, and a resin particle including a resin having a structural unit represented by the following formula (1): where R1 represents —COO—; each of R2 and R3 independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and n represents an integer of from 5 to 100.Type: ApplicationFiled: May 15, 2017Publication date: December 14, 2017Inventors: Takuya SAIGA, Satoyuki Sekiguchi, Ryo Miyakoshi, Daisuke Asahina
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Publication number: 20170351198Abstract: A member for an image forming apparatus includes a surface layer including a block copolymer, wherein the block copolymer includes a polyamide block and a polyether block and the composition ratio of the polyether block to the polyamide block is from 0.2 to 1.5.Type: ApplicationFiled: May 31, 2017Publication date: December 7, 2017Applicant: RICOH COMPANY, LTD.Inventors: Ryo MIYAKOSHI, Hidetoshi FUJII, Akira IZUTANI, Daisuke ASAHINA
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Publication number: 20170130082Abstract: An ink includes a solvent and a resin, wherein the storage elastic modulus G1 of an ink film obtained by drying the ink is 2.0×108-5.0×108 Pa at 20 degrees C. as measured by a dynamic viscoelasticity measuring method and the ratio (G2/G1) of the storage elastic modulus G1 to the storage elastic modulus G2 of the ink film measured at 80 degrees C. by the dynamic viscoelasticity measuring method is 0.30-0.85.Type: ApplicationFiled: October 19, 2016Publication date: May 11, 2017Inventors: Satoyuki SEKIGUCHI, Daisuke ASAHINA, Yuusuke FUJITA
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Patent number: 9606464Abstract: A resin composition for a toner including a polyester resin and a colorant, wherein the polyester resin has A(10)-A(180) of 70 or greater, where A(10) (%) is a transmittance of light having a wavelength of 500 nm through a mixture of 20 parts by mass of the polyester resin added to 80 parts by mass of ethyl acetate and stirred at 25° C. for 10 minutes, and A(180) (%) is the transmittance after the mixture is left to stand for 3 hours.Type: GrantFiled: June 13, 2013Date of Patent: March 28, 2017Assignee: Ricoh Company, Ltd.Inventors: Yoshitaka Yamauchi, Kazumi Suzuki, Tatsuya Morita, Hiroshi Yamashita, Tsuyoshi Sugimoto, Daisuke Asahina
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Patent number: 9593213Abstract: A polylactic resin composition, including: polylactic resin as main component, wherein in a binary image of the polylactic resin composition obtained by binarizing a phase image of a cross-section of the polylactic resin composition observed with an AFM in tapping mode based on intermediate value between maximum and minimum values of phase differences of the polylactic resin composition in free vibration, phases equal to or greater than intermediate value are dispersed in a phase less than intermediate value, and average equivalent circle diameter of the phases equal to or greater than intermediate value is from 0.2 ?m to 1 ?m, and wherein polylactic resin composition is detected to have at least one glass transition temperature (Tg) in a range of ?20° C. or lower, and at least one glass transition temperature (Tg) in a range of 40° C. to 70° C. in a temperature elevating process of differential scanning calorimeter (DSC) measurement thereof.Type: GrantFiled: October 28, 2015Date of Patent: March 14, 2017Assignee: Ricoh Company, Ltd.Inventors: Satoyuki Sekiguchi, Daisuke Asahina
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Patent number: 9563141Abstract: A toner, including: a copolymerization resin, wherein the copolymerization resin includes: a unit derived from a polyester resin including a polycarboxylic acid having a valence of 2 or more and a polyol having a valence of 2 or more; and a unit derived from a resin having a polyhydroxycarboxylic acid skeleton, where the unit derived from the resin having a polyhydroxycarboxylic acid skeleton is bonded to the unit derived from the polyester resin via at least one of a urethane group and a urea group, and wherein the toner has a relative degree of crystallization of 10% or more and less than 50%.Type: GrantFiled: January 20, 2014Date of Patent: February 7, 2017Assignee: Ricoh Company, Ltd.Inventors: Tsuyoshi Sugimoto, Hiroshi Yamashita, Daisuke Asahina, Susumu Chiba, Satoyuki Sekiguchi
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Patent number: 9557670Abstract: A toner, including: a binder resin; and a colorant, wherein the toner has a storage modulus of 1.0×107 Pa or more at 50° C., a loss modulus of 8.0×104 Pa to 2.0×105 Pa at 80° C., and a loss modulus of 2.0×102 Pa to 1.0×103 Pa at 160° C.Type: GrantFiled: February 28, 2013Date of Patent: January 31, 2017Assignee: Ricoh Company, Ltd.Inventors: Masana Shiba, Hiroshi Yamashita, Tsuyoshi Sugimoto, Daisuke Asahina, Yukari Fukuda, Rintaro Takahashi, Satoyuki Sekiguchi
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Patent number: 9557669Abstract: A toner, wherein the toner has glass transition temperature [Tg1st (toner)] of 20° C. to 50° C., where the glass transition temperature [Tg1st (toner)] is measured in a first heating in differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has glass transition temperature [Tg2nd (THF insoluble matter)] of ?40° C. to 30° C., where the glass transition temperature [Tg2nd (THF insoluble matter)] is measured in a second heating in differential scanning calorimetry (DSC) of the tetrahydrofuran (THF) insoluble matter, wherein the THF insoluble matter has a storage modulus at 100° C. [G?(100) (THF insoluble matter)] of 1.0×105 Pa to 1.0×107 Pa, and wherein a ratio of a storage modulus of the THF insoluble matter at 40° C. [G?(40) (THF insoluble matter)] to the storage modulus of the THF insoluble matter at 100° C. [G?(100) (THF insoluble matter)] is 3.5×10 or less.Type: GrantFiled: August 29, 2014Date of Patent: January 31, 2017Assignee: Ricoh Company, Ltd.Inventors: Shinsuke Nagai, Shinya Nakayama, Tsuyoshi Sugimoto, Susumu Chiba, Kohsuke Nagata, Daisuke Asahina
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Patent number: 9557672Abstract: A toner, including: a polyester resin, wherein the polyester resin includes a diol component and a crosslink component as constituent components thereof, wherein the diol component contains an aliphatic diol having 3 to 10 carbon atoms in an amount of 50 mol % or more, wherein the crosslink component contains a trihydric or higher aliphatic alcohol, and wherein the toner has a glass transition temperature (Tg1st) of 20° C. to 50° C., where the glass transition temperature (Tg1st) is measured in first heating in differential scanning calorimetry (DSC) of the toner.Type: GrantFiled: August 13, 2014Date of Patent: January 31, 2017Assignee: Ricoh Company, Ltd.Inventors: Susumu Chiba, Tsuyoshi Sugimoto, Shinya Nakayama, Kohsuke Nagata, Shinsuke Nagai, Daisuke Asahina
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Patent number: 9477165Abstract: A toner including a polyester resin having an amorphous polyester segment is provided. The amorphous polyester segment includes a condensation polymerization product between a carboxylic acid and an alcohol. The carboxylic acid includes both aliphatic and aromatic dicarboxylic acids. The toner deforms with a deformation rate of from 1.0% to 5.0% under a pressure of 100 gf at 40° C. and 80% RH. In a binarized image of an AFM phase image of the toner, first phase-contrast images serving as large-phase-difference portions are dispersed in second phase-contrast images serving as small-phase-difference portions, and the first phase-contrast images have a dispersion diameter of 100 nm or less. An endothermic quantity Q1 obtained in a first heating of DSC is from 10 to 50 J/g, and a ratio of an endothermic quantity obtained in the second heating Q2 to that in first heating Q1 is 0.65 or less.Type: GrantFiled: March 16, 2015Date of Patent: October 25, 2016Assignee: Ricoh Company, Ltd.Inventors: Azumi Miyaake, Hiroshi Yamashita, Daisuke Asahina, Ryo Miyakoshi, Satoyuki Sekiguchi
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Publication number: 20160231661Abstract: A toner, wherein the toner has glass transition temperature [Tg1st (toner)] of 20° C. to 50° C., where the glass transition temperature [Tg1st (toner)] is measured in a first heating in differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has glass transition temperature [Tg2nd (THF insoluble matter)] of ?40° C. to 30° C., where the glass transition temperature [Tg2nd (THF insoluble matter)] is measured in a second heating in differential scanning calorimetry (DSC) of the tetrahydrofuran (THF) insoluble matter, wherein the THF insoluble matter has a storage modulus at 100° C. [G?(100) (THF insoluble matter)] of 1.0×105 Pa to 1.0×107 Pa, and wherein a ratio of a storage modulus of the THF insoluble matter at 40° C. [G?(40) (THF insoluble matter)] to the storage modulus of the THF insoluble matter at 100° C. [G?(100) (THF insoluble matter)] is 3.5×10 or less.Type: ApplicationFiled: August 29, 2014Publication date: August 11, 2016Inventors: Shinsuke NAGAI, Shinya NAKAYAMA, Tsuyoshi SUGIMOTO, Susumu CHIBA, Kohsuke NAGATA, Daisuke ASAHINA