Abstract: A refrigeration cycle is a refrigeration cycle using a mixed refrigerant which is a flammable refrigerant and which contains at least 1,2-difluoroethylene (HFO-1132(E)), and includes a compressor (1), a heat-source-side heat exchanger (3), an expansion mechanism (4), a use-side heat exchanger (2), and a decompression mechanism (7). The decompression mechanism (7) decompresses, between an inlet and an outlet of the heat-source-side heat exchanger (3), the mixed refrigerant flowing through the heat-source-side heat exchanger (3) that functions as an evaporator.

Abstract: A refrigeration cycle apparatus that is able to reduce the amount of refrigerant used while reducing a pressure loss in the case where a refrigerant containing at least 1,2-difluoroethylene is used is provided. In an air conditioner (1) including a refrigerant circuit (10), including a compressor (21), an outdoor heat exchanger (23), an outdoor expansion valve (24), and an indoor heat exchanger (31), and a refrigerant containing at least 1,2-difluoroethylene and sealed in the refrigerant circuit (10), the outdoor heat exchanger (23) has a heat transfer tube (23b) of which a pipe diameter is greater than or equal to 6.35 mm and less than 10.0 mm.

Abstract: An object is to provide a mixed refrigerant having three types of performance, i.e., a refrigerating capacity that is equivalent to that of R410A, a sufficiently low GWP, and a lower flammability (Class 2L) according to the ASHRAE standard. Provided is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf), wherein when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x, y, z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AC, CF, FD, and DA that connect the following 4 points: point A (71.1, 0.0, 28.9), point C (36.5, 18.2, 45.3), point F (47.6, 18.3, 34.1), and point D (72.0, 0.0, 28.0), or on these line segments; the line segment AC is represented by coordinates (0.0181y2?2.2288y+71.

Abstract: A refrigeration cycle apparatus capable of keeping a LCCP low when a heat cycle is performed using a sufficiently small-GWP refrigerant, and a method of determining a refrigerant enclosure amount in the refrigeration cycle apparatus are provided. An outdoor unit (20) including a compressor (21) and an outdoor heat exchanger (23), an indoor unit (30) including an indoor heat exchanger (31), and a refrigerant pipe (5, 6) that connects the outdoor unit (20) and the indoor unit (30) to each other are provided. A refrigerant containing at least 1,2-difluoroethylene is enclosed in a refrigerant circuit (10) that is constituted by connecting the compressor (21), the outdoor heat exchanger (23), and the indoor heat exchanger (31) to one another. An enclosure amount of the refrigerant in the refrigerant circuit (10) per 1 kW of refrigeration capacity satisfies a condition of 160 g or more and 560 g or less.

Abstract: A warm-water generating apparatus (1) uses, as a refrigerant, a mixed refrigerant containing at least 1,2-difluoroethylene (HFO-1132(E)). The warm-water generating apparatus (1) includes a compressor (21), a heat-source-side air heat exchanger (24), an expansion valve (23), and a use-side water heat exchanger (22). The water heat exchanger (22) causes the mixed refrigerant flowing therein and first water to exchange heat with each other to heat the first water.

Abstract: A refrigeration cycle apparatus that is able to reduce the amount of refrigerant used while reducing a pressure loss in the case where a refrigerant containing at least 1,2-difluoroethylene is used is provided. In an air conditioner (1) including a refrigerant circuit (10), including a compressor (21), an outdoor heat exchanger (23), an outdoor expansion valve (24), and an indoor heat exchanger (31), and a refrigerant containing at least 1,2-difluoroethylene and sealed in the refrigerant circuit (10), the outdoor heat exchanger (23) has a heat transfer tube (23b) of which a pipe diameter is greater than or equal to 6.35 mm and less than 10.0 mm.

Abstract: The present invention provides a method for efficiently producing 1-chloro-1,2-difluoroethylene at low cost. Specifically, the present invention provides a method for producing 1-chloro-1,2-difluoroethylene, including the step of dehydrohalogenating chlorofluoroethane represented by formula (1) CFClX1—CHFX2 wherein X1 and X2 are different from each other and represent H, F, or Cl; and either X1 or X2 is H.

Abstract: The present invention provides a method for producing tetrafluoropropene represented by formula (1) by bringing monochlorotrifluoropropene represented by formula (2) into contact with anhydrous hydrogen fluoride in the presence of a catalyst, the method being capable of maintaining the conversion of the starting material and the selectivity for the target product within an excellent range, while reducing degradation of the catalyst to maintain the reaction for a long time.

Abstract: The present invention provides a method for producing a target fluorine-containing olefin with high conversion and selectivity using a process comprising a dehydrofluorination reaction of a hydrofluorocarbon. The method comprises a first reaction step comprising subjecting a hydrofluorocarbon to dehydrofluorination in the presence of a catalyst. The hydrofluorocarbon is a compound represented by Formula (1): RfCFYCHZ2, wherein Rf represents a straight or branched C1-3 perfluoroalkyl group, and Y and Z each independently represent H or F wherein when all Zs are H, Y represents F. The catalyst comprises chromium oxide represented by the chemical formula: CrOm (1.5<m<3).

Abstract: The present invention provides a composition comprising an HFO compound, the composition having excellent stability with decomposition and oxidation of the HFO compound being inhibited, the composition having improved refrigerating capacity when used as a heat transfer medium, compared with the case in which an HFO compound is used alone. More specifically, the present invention provides a composition comprising at least one HFO compound selected from the group consisting of HFO-1234yf, (E-/Z-)HFO-1234ze, and (E-/Z-)HFO-1225ye; and a chlorine-containing compound, wherein (1) the chlorine-containing compound is at least one member selected from the group consisting of CH2?CHCl, CHF?CHCl, CH2?CFCl, CF3Cl, CH3Cl, CF3CH2Cl, CClF?CHCl, and CHF?CCl2, and (2) the chlorine-containing compound is contained in an amount ranging from 1 to 500000 mass ppm.

Abstract: An object of the present invention is to provide a solvent and a detergent that have excellent basic properties as solvents or detergents, such as solubility, and that have a boiling point, flammability, toxicity, GWP, and ODP that are all within preferable ranges. To achieve the above object, the present invention provides a solvent composition or detergent composition comprising a hydrochlorofluoropropene represented by the formula: CX3CX?CX2, wherein each X is the same or different and is F or Cl, at least one X is F, and at least three X are Cl; the hydrochlorofluoropropene having an atmospheric pressure boiling point of 50° C. or higher.

Abstract: The present invention provides a composition comprising an HFO compound, the composition having excellent stability with decomposition and oxidation of the HFO compound being inhibited, the composition having improved refrigerating capacity when used as a heat transfer medium, compared with the case in which an HFO compound is used alone. More specifically, the present invention provides a composition comprising at least one HFO compound selected from the group consisting of HFO-1234yf, (E-/Z-)HFO-1234ze, and (E-/Z-)HFO-1225ye; and a chlorine-containing compound, wherein (1) the chlorine-containing compound is at least one member selected from the group consisting of CH2?CHCl, CHF?CHCl, CH2?CFCl, CF3Cl, CH3Cl, CF3CH2Cl, CClF?CHCl, and CHF?CCl2, and (2) the chlorine-containing compound is contained in an amount ranging from 1 to 500000 mass ppm.

Abstract: The present invention provides a method for producing a fluorine-containing haloolefin compound, the method easily inhibiting catalyst deactivation, and the method being capable of inhibiting a decrease in conversion and selectivity in the reaction, even when the reaction is continued for a long period of time. The present invention is a method for producing a fluorine-containing haloolefin compound via a step of fluorinating a C3 halogenated hydrocarbon. The method comprises a step of removing a stabilizer contained in the C3 halogenated hydrocarbon before the fluorination step.

Abstract: The present invention provides an economically advantageous method for efficiently producing a fluorine-containing compound while ensuring high conversion of the starting compound, reducing production of 245cb, and reducing equipment costs and energy costs.

Abstract: The present invention provides a method for efficiently producing 1-chloro-1,2-difluoroethylene at low cost. Specifically, the present invention provides a method for producing 1-chloro-1,2-difluoroethylene, including the step of dehydrohalogenating chlorofluoroethane represented by formula (1) CFClX1—CHFX2 wherein X1 and X2 are different from each other and represent H, F, or Cl; and either X1 or X2 is H.

Abstract: The present invention provides a method for producing tetrafluoropropene represented by formula (1) by bringing monochlorotrifluoropropene represented by formula (2) into contact with anhydrous hydrogen fluoride in the presence of a catalyst, the method being capable of maintaining the conversion of the starting material and the selectivity for the target product within an excellent range, while reducing degradation of the catalyst to maintain the reaction for a long time.

Abstract: This invention provides a method for stably producing 2,3,3,3-tetrafluoropropene for a long period of time wherein unreacted materials are reused after distillation without liquid-liquid separation to suppress catalyst deactivation.

Abstract: This invention provides a method for stably producing 2,3,3,3-tetrafluoropropene for a long period of time while suppressing catalyst deactivation. This invention provides a method for producing 2,3,3,3-tetrafluoropropene, the method comprising: (d) reacting 2-chloro-3,3,3-trifluoropropene with hydrogen fluoride in the presence of a catalyst; (e) subjecting the reaction mixture obtained in step (d) to distillation to separate the mixture into a first stream comprising 2,3,3,3-tetrafluoropropene as a main component and a second stream comprising unreacted hydrogen fluoride and organic matter containing unreacted 2-chloro-3,3,3-trifluoropropene as main components; and (f) recycling the second stream separated in step (e) above to the reaction of step (d), wherein the distillation of step (e) is performed under conditions that satisfy the relationship of a specific equation.

Abstract: The present invention provides an economically advantageous method for efficiently producing a fluorine-containing compound while ensuring high conversion of the starting compound, reducing production of 245cb, and reducing equipment costs and energy costs.

Abstract: The present invention provides a method for producing a fluorine-containing haloolefin compound, the method easily inhibiting catalyst deactivation, and the method being capable of inhibiting a decrease in conversion and selectivity in the reaction, even when the reaction is continued for a long period of time. The present invention is a method for producing a fluorine-containing haloolefin compound via a step of fluorinating a C3 halogenated hydrocarbon. The method comprises a step of removing a stabilizer contained in the C3 halogenated hydrocarbon before the fluorination step.