Abstract: A method is disclosed for recovering germanium from a gaseous mixture which includes a germanium-containing compound in vapor or particulate form, acid in vapor form, and water vapor. The gaseous mixture is contacted with a liquid containing water under conditions effective to dissolve the germanium-containing compound in the liquid. The acidity of the resulting liquid mixture is increased under conditions effective to vaporize the germanium-containing compound. The vaporized germanium-containing compound is contacted with one or more aqueous solutions under conditions effective to dissolve and precipitate the germanium-containing compound in at least one of the one or more aqueous solutions, and the resulting precipitate is separated from the at least one of the one or more aqueous solutions. The methods described herein are particularly well suited for recovering germanium from the waste gases produced during optical waveguide manufacturing processes.

Abstract: Improved single-mode optical waveguide fibers having a central core region, surrounded by an inner cladding region through which light at a chosen signal wavelength will propagate to an appreciable degree along with propagation of same in the central core region, the inner core region further surrounded by an outer cladding region, the improvement comprising germanium dioxide in the inner cladding region at a concentration within the range of about 0.005 percent by weight to about 1 percent by weight of said inner cladding region, effective to significantly reduce the concentration of oxygen atoms in the inner cladding region which are available to form defects that cause hydrogen-induced attenuation. Also provided are core preforms, overclad preforms, and processes for making the fibers, core preforms and overclad preforms.

Abstract: A precision burner for oxidizing halide-free, silicon-containing compounds, such as, octamethylcyclotetrasiloxane (OMCTS), is provided. The burner includes a subassembly (13) which can be precisely mounted on a burner mounting block (107) through the use of an alignment stub (158), a raised face (162) on the burner mounting block (107), and a recess (160) in the back of the subassembly (13). The burner's face includes four concentric gas-emitting regions: a first central region (36, 90) from which exits a mixture of OMCTS and O.sub.2, a second innershield region (38, 92) from which exits N.sub.2, a third outershield region (40, 42, 94, 96) from which exits O.sub.2, and a fourth premix region (44, 98) from which exits a mixture of CH.sub.4 and O.sub.2. The burner provides more efficient utilization of halide-free, silicon-containing raw materials than prior burners.

Abstract: The present invention is directed to a purified polyalkylsiloxane composition having a boiling point, under atmospheric conditions, of less than about 250.degree. C. and containing high boiling impurities, including siloxanes and silanol-terminated siloxanes, that have boiling points, under atmospheric conditions, of greater than about 250.degree. C. in a total concentration of less than 14 ppm. The present invention is further directed to a method of producing a purified polyalkylsiloxane composition, having a boiling point, under atmospheric conditions, of less than about 250.degree. C., by distilling a polyalkylsiloxane starting material containing high boiling impurities having boiling points, under atmospheric conditions, of greater than about 250.degree. C. in a total concentration of at least 14 ppm, under conditions effective to produce a purified polyalkylsiloxane composition having a boiling point under atmospheric conditions of less than about 250.degree. C.

Abstract: Improved single-mode optical waveguide fibers comprising a central core region, surrounded by an inner cladding region through which light at a chosen signal wavelength will propagate to an appreciable degree along with propagation of same in the central core region, the inner core region further surrounded by an outer cladding region, the improvement comprising germanium dioxide in the inner cladding region at a concentration within the range of about 0.005 percent by weight to about 1 percent by weight of said inner cladding region, effective to significantly reduce the concentration of oxygen atoms in the inner cladding region which are available to form defects that cause hydrogen-induced attenuation. Also provided are core preforms, overclad preforms, and processes for making the fibers, core preforms and overclad preforms.

Abstract: The present invention is directed to a purified polyalkylsiloxane composition having a boiling point, under atmospheric conditions, of less than about 250.degree. C. and containing high boiling impurities, including siloxanes and silanol-terminated siloxanes, that have boiling points, under atmospheric conditions, of greater than about 250.degree. C. in a total concentration of less than 14 ppm. The present invention is further directed to a method of producing a purified polyalkylsiloxane composition, having a boiling point, under atmospheric conditions, of less than about 250.degree. C., by distilling a polyalkylsiloxane starting material containing high boiling impurities having boiling points, under atmospheric conditions, of greater than about 250.degree. C. in a total concentration of at least 14 ppm, under conditions effective to produce a purified polyalkylsiloxane composition having a boiling point under atmospheric conditions of less than about 250.degree. C.

Abstract: A precision burner for oxidizing halide-free, silicon-containing compounds, such as, octamethyl-cyclotetrasiloxane (OMCTS), is provided. The burner includes a subassembly (13) which can be precisely mounted on a burner mounting block (107) through the use of an alignment stub (158), a raised face (162) on the burner mounting block (107), and a recess (160) in the back of the subassembly (13). The burner's face includes four concentric gas-emitting regions: a first central region (36, 90) from which exits a mixture of OMCTS and O.sub.2, a second innershield region (38, 92) from which exits N.sub.2, a third outershield region (40, 42, 94, 96) from which exits O.sub.2, and a fourth premix region (44, 98) from which exits a mixture of CH.sub.4 and O.sub.2. The burner provides more efficient utilization of halide-free, silicon-containing raw materials than prior burners.

Abstract: The invention concerns a method and apparatus for producing a carbon coated optical fiber. An optical fiber is drawn through a reactor tube. Reactant gas is flowed into the tube and onto the fiber where it reacts to form a carbon coating on the fiber. The reactant gas and reaction products are flowed in the direction of movement of the fiber and out of an end of the tube and into a receiving chamber having a diameter larger than that of the reaction tube. The reactant gas continues to react as it flows through the tube and after it exits the tube. At least some of the reaction product deposit on the surface of the receiving chamber where it has no adverse effect on the draw process.

Abstract: An improved method for making preforms by vapor deposition soot laydown processes is provided wherein an oxidizing atmosphere is used during at least part of the laydown process, e.g., during the laydown of the center portion of the preform. The use of such an atmosphere has been found to result in enhanced dopant capture, reduced axial trends, and an overall stabilization of the laydown process. A method for selecting burner flows which optimize the laydown process is also provided.

Abstract: The invention concerns a method and apparatus for producing a carbon coated optical fiber. An optical fiber is drawn through a reactor tube. Reactant gas is flowed into the tube and onto the fiber where it reacts to form a carbon coating on the fiber. The reactant gas and reaction products are flowed in the direction of movement of the fiber and out of an end of the tube and into a receiving chamber having a diameter larger than that of the reaction tube. The reactant gas continues to react as it flows through the tube and after it exits the tube. At least some of the reaction product deposit on the surface of the receiving chamber where it has no adverse effect on the draw process.

Abstract: A system for delivering a liquid reactant at high flow rates to an oxidation/flame hydrolysis glass soot deposition site. A first liquid only reactant is delivered to a flash vaporization chamber to form a thin film and mixed with oxygen after vaporization. Additional vaporized reactants are thereafter mixed with the vaporized first liquid prior to delivery to an oxidation/flame hydrolysis burner to form a glass soot outer cladding layer on a soot preform. The soot preform is subsequently fused to form a high quality glass blank for drawing into optical fiber.

Abstract: Method and apparatus wherein continuous indexed lengths of optical fiber are automatically measured for load at failure for each failure below a predetermined maximum stress. A predetermined length of optical fiber is indexed. The optical fiber is clamped at one or more clamp points along its length. Increasing tension is applied to a first indexed length of optical fiber between at least one clamp point and a tension application means. Increasing tension is applied between an initial value and the predetermined maximum load. The increasing tension is measured during its application. If failure occurs, the actual load at failure is detected while the increasing tension is being applied. When failure does not occur, the first length of optical fiber is released and a second length of optical fiber is indexed to the position where increasing tension is applied to the second length between at least one clamp point and the tension application means.

Abstract: A porous glass optical waveguide preform is formed by depositing a coating of glass particulate material on the lateral surface of a core which may be a porous glass body continuously produced by the axial deposition of glass particles. The core rotates and moves longitudinally in one direction with respect to two flame hydrolysis burners which emit streams of glass particles having different compositions. In addition, the two burners reciprocatingly move with respect to a portion of the length of the core. The speed of each burner varies as it traverses along its path of reciprocating motion. The thickness of the layer produced by a burner at a given point is inversely related to the speed of the burner as it passes that point. The layers formed by the completion of a single traverse by both burners combine to form a conically-shaped layer, the composition of which varies from the base toward the apex thereof.

Abstract: A porous glass optical waveguide preform is formed by depositing a coating of glass particulate material on the lateral surface of a core which may be a porous glass body continuously produced by the axial deposition of glass particles. The core rotates and moves longitudinally in one direction with respect to two flame hydrolysis burners which emit streams of glass particles having different compositions. In addition, the two burners reciprocatingly move with respect to a portion of the length of the core. The speed of each burner varies as it traverses along its path of reciprocating motion. The thickness of the layer produced by a burner at a given point is inversely related to the speed of the burner as it passes that point. The layers formed by the completion of a single traverse by both burners combine to form a conically-shaped layer, the composition of which varies from the base toward the apex thereof.

Abstract: A non-contact system for monitoring the tension in an optical waveguide fiber during drawing is provided. The system comprises: (a) means for sensing the motion of the fiber in a direction transverse to the direction in which the fiber is moving; (b) means for analyzing the sensed motion to determine at least one frequency component thereof; and (c) means for monitoring the frequency component so determined so as to monitor the tension in the fiber.

Abstract: Methods are provided for reducing the water content of optical waveguide fibers produced from blanks having a centerline aperture and having compositions which prevent cooling of the blank to room temperature between consolidation and drawing. In accordance with certain aspects of the invention, the water content is reduced by storing the blanks at as low a temperature as possible, preferably below about 550.degree. C. In accordance with other aspects, the water content is reduced by filling the apertures of the blanks with an inert atmosphere during storage.

Abstract: A porous glass optical waveguide preform is formed by depositing a coating of glass particulate material on the lateral surface of a core which may be a porous glass body continuously produced by the axial deposition of glass particles. The core rotates and moves longitudinally in one direction with respect to two flame hydrolysis burners which emit streams of glass particles having different compositions. In addition, the two burners reciprocatingly move with respect to a portion of the length of the core. The speed of each burner varies as it traverses along its path of reciprocating motion. The thickness of the layer produced by a burner at a given point is inversely related to the speed of the burner as it passes that point. The layers formed by the completion of a single traverse by both burners combine to form a conically-shaped layer, the composition of which varies from the base toward the apex thereof.

Abstract: An apparatus is provided for curing a coating applied to an optical fiber. An elongated ultraviolet lamp and the optical fiber emerging from the coater are located at focii of an elliptical mirror which focuses the ultraviolet energy onto the coated fiber. The fiber is surrounded by a cylindrical chamber that is transparent to ultraviolet light. The chamber includes a jacket through which there flows a fluid which absorbs infrared energy. A cooling gas flows from a annular slot located at the bottom end of the chamber. The slot is so angled that gas flowing therefrom is directed upwardly and inwardly toward the coated fiber so that there exists within the chamber a recirculating flow of cooling gas. This enables the cooling gas to repeatedly absorb heat from the coated fiber and give up that heat to the chamber wall which is cooled by the fluid.

Abstract: A porous glass optical waveguide preform is formed by depositing a coating of glass particulate material on the lateral surface of a core which may be a porous glass body continuously produced by the axial deposition of glass particles. The core rotates and moves longitudinally in one direction with respect to two flame hydrolysis burners which emit streams of glass particles having different compositions. In addition, the two burners reciprocatingly move with respect to a portion of the length of the core. The speed of each burner varies as it traverses along its path of reciprocating motion. The thickness of the layer produced by a burner at a given point is inversely related to the speed of the burner as it passes that point. The layers formed by the completion of a single traverse by both burners combine to form a conically-shaped layer, the composition of which varies from the base toward the apex thereof.

Abstract: A porous glass optical waveguide preform is formed by depositing a coating of glass particulate material on the lateral surface of a core which may be a porous glass body produced by the axial deposition of glass particulate material. The core rotates and moves longitudinally in one direction with respect to a flame hydrolysis burner. In addition, the burner oscillates longitudinally with respect to a portion of the length of the core.