Abstract: A roll for use in a continuous casting machine includes a roll body that is constructed and arranged to be mounted for rotation in a guide segment area of a continuous casting machine, and a generally cylindrical outer surface on the roll body. Preferably, the outer surface is fabricated at least in part from an age-hardenable nickel-based alloy that includes, in weight percent, up to 0.3% carbon, about 5% to about 12% chromium, and about 10% to about 30% molybdenum. The roll exhibits superior high temperature strength and stability, low thermal expansion, and superior oxidation resistance at temperatures that are typical during operation in a continuous casting machine. A process of making a metal casting using such a roll is also disclosed.