Patents by Inventor Daniel A. De Schryver

Daniel A. De Schryver has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11891754
    Abstract: This invention provides aqueous flame retardant dispersions comprising water, a brominated flame retardant containing aromatically-bound bromine, at least one dispersant, at least one wetting agent, and at least one thickener. The brominated flame retardant has an average particle size of about 20 ?m or less. The flame retardant dispersion contains about 50 wt % or more of brominated polymeric flame retardant, based on the total weight of the dispersion. Also provided are coating compositions, processes for forming flame retardant dispersions, processes for forming coating compositions, and processes for applying the coating compositions to textile substrates.
    Type: Grant
    Filed: March 12, 2019
    Date of Patent: February 6, 2024
    Assignee: Albemarle Corporation
    Inventors: Rajeev S. Mathur, Jon Shannon Reed, Daniel A. De Schryver, John Randall Chaya
  • Publication number: 20230272185
    Abstract: This invention provides a flame retardant additive composition which comprises at least one glow suppressant and at least one brominated flame retardant. The glow suppressant is about 0.5 wt % or more of the flame retardant additive composition, based on the total weight of the flame retardant additive composition. The brominated flame retardant contains aromatically-bound bromine and is selected from a) a brominated anionic styrenic polymer having a number average molecular weight of about 750 to about 7500, and/or a bromine content of about 60 wt % to about 77 wt %, b) a brominated anionic chain transfer vinyl aromatic polymer which contains about 70 wt % or more bromine, or a mixture of any two or more of these. Also provided are flame retarded polyolefin compositions that contain at least one glow suppressant and a brominated flame retardant.
    Type: Application
    Filed: August 5, 2021
    Publication date: August 31, 2023
    Inventors: Jonathan P. McCarney, Daniel A. De Schryver, Rajeev S. Mathur
  • Publication number: 20210131027
    Abstract: This invention provides aqueous flame retardant dispersions comprising water, a brominated flame retardant containing aromatically-bound bromine, at least one dispersant, at least one wetting agent, and at least one thickener. The brominated flame retardant has an average particle size of about 20 ?m or less. The flame retardant dispersion contains about 50 wt % or more of brominated polymeric flame retardant, based on the total weight of the dispersion. Also provided are coating compositions, processes for forming flame retardant dispersions, processes for forming coating compositions, and processes for applying the coating compositions to textile substrates.
    Type: Application
    Filed: March 12, 2019
    Publication date: May 6, 2021
    Inventors: Rajeev S. Mathur, Jon Shannon Reed, Daniel A. De Schryver, John Randall Chaya
  • Publication number: 20150337125
    Abstract: This invention relates to useful brominated flame retardants and the use of the brominated materials as flame retardants in flammable thermoplastic and thermosetting materials.
    Type: Application
    Filed: May 23, 2014
    Publication date: November 26, 2015
    Applicant: Albemarle Corporation
    Inventors: Jonathan McCarney, Jon Shannon Reed, Daniel De Schryver, Govindarajulu Kumar
  • Patent number: 7666943
    Abstract: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer, and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
    Type: Grant
    Filed: July 20, 2006
    Date of Patent: February 23, 2010
    Assignee: Albemarle Corporation
    Inventors: Jon Shannon Reed, Daniel A. De Schryver
  • Patent number: 7666944
    Abstract: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: February 23, 2010
    Assignee: Albemarle Corporation
    Inventors: Daniel A. De Schryver, Jon Shannon Reed, Douglas W. Luther, Samuel G. Thomas, Jr., Arthur G. Mack
  • Publication number: 20080139752
    Abstract: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %, and a GPC weight average molecular weight in the range of about 5000 to about 40,000, or a GPC weight average molecular weight of at least about 600,000. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
    Type: Application
    Filed: October 30, 2007
    Publication date: June 12, 2008
    Applicant: Albemarle Corporation
    Inventors: Daniel A. De Schryver, Jon Shannon Reed, Douglas W. Luther, Samuel G. Thomas, Arthur G. Mack
  • Publication number: 20070021562
    Abstract: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer, and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %. When the fiber-forming thermoplastic polymer is a polyester, the polybrominated anionic styrenic polymer is present in a flame resistant or flame retardant amount. When the fiber-forming thermoplastic polymer is a polyamide, the polybrominated anionic styrenic polymer is at least about 2 wt % of the fiber or filament. When the fiber-forming thermoplastic polymer is a polyolefin, at least one synergist is present and the polybrominated anionic styrenic polymer is no more than about 15 wt % of the fiber or filament.
    Type: Application
    Filed: July 20, 2006
    Publication date: January 25, 2007
    Inventors: Jon Reed, Daniel De Schryver
  • Publication number: 20050159552
    Abstract: A fiber or filament which is formed from ingredients comprising (a) at least one fiber-forming thermoplastic polymer, and (b) at least one polybrominated anionic styrenic polymer is provided. The polybrominated anionic styrenic polymer has a bromine content of at least about 50 wt %. Processes for producing such fibers or filaments are also provided.
    Type: Application
    Filed: January 21, 2004
    Publication date: July 21, 2005
    Inventors: Jon Reed, Daniel De Schryver
  • Publication number: 20040072929
    Abstract: A flame retardant molding composition formed from components comprising
    Type: Application
    Filed: June 27, 2002
    Publication date: April 15, 2004
    Inventor: Daniel A. De Schryver
  • Publication number: 20030195286
    Abstract: Flame retardant additive compositions having enhanced thermal stability are described. They comprise a blend formed from (A) at least one organic bromine flame retardant selected from (i) a flame retardant compound having a plurality of bromine atoms directly bonded to a cycloaliphatic ring, (ii) the bis(2,3-dibromopropyl ether) of tetrabromobisphenol-A, and (iii) the bis(2,3-dibromopropyl ether) of tetrabromobisphenol-S, (B) an alkyltin mercaptoalkanoate, and (C) a zeolite adjuvant. The proportions are 0.01-0.08 part by weight of (B) per part by weight of (A), and 0.01-0.35 part by weight of (C) per part by weight of (A). Thermoplastic polymer compositions in which these additive compositions are employed possess enhanced properties.
    Type: Application
    Filed: April 15, 2002
    Publication date: October 16, 2003
    Inventor: Daniel A. De Schryver
  • Patent number: 6617379
    Abstract: N,N′-piperazinebis(neopentylglycol)phosphoramidate is used in combination with at least one co-additive which is (i) melamine, (ii) one or more melamine compounds or derivatives, or (iii) both of (i) and (ii) to provide effective flame retardancy in thermoplastic polymers. With polymers that tend to release trace amounts of acid under thermal processing conditions, a hydrotalcite is preferably included in the composition. In acid-sensitive polymers such as polyesters, the N,N′-piperazinebis(neopentylglycol)phosphoramidate should be free or essentially free of acid species as determinable by use of nmr, mass spec, and/or HPLC.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: September 9, 2003
    Assignee: Albemarle Corporation
    Inventors: Anteneh Z. Worku, Daniel A. De Schryver, Susan D. Landry, Arthur G. Mack
  • Publication number: 20030109608
    Abstract: N,N′-piperazinebis(neopentylglycol)phosphoramidate is used in combination with at least one co-additive which is (i) melamine, (ii) one or more melamine compounds or derivatives, or (iii) both of (i) and (ii) to provide effective flame retardancy in thermoplastic polymers. With polymers that tend to release trace amounts of acid under thermal processing conditions, a hydrotalcite is preferably included in the composition. In acid-sensitive polymers such as polyesters, the N,N′-piperazinebis(neopentylglycol)phosphoramidate should be free or essentially free of acid species as determinable by use of nmr, mass spec, and/or HPLC.
    Type: Application
    Filed: December 4, 2001
    Publication date: June 12, 2003
    Inventors: Anteneh Z. Worku, Daniel A. De Schryver, Susan D. Landry, Arthur G. Mack
  • Publication number: 20020086927
    Abstract: A flame retardant molding composition which comprises a blend formed from at least the following components: (A) a thermoplastic polyamide or thermoplastic polyester polymer (B) at least one organic halogen-containing flame retardant, (C) a zinc borate, a mixed oxide of zinc and boron, or zinc sulfide, or a mixture of any two or more of the foregoing; and (D) an olefin-based polymer. The composition produces molded articles which exhibit increased comparative tracking index ratings.
    Type: Application
    Filed: January 23, 2002
    Publication date: July 4, 2002
    Inventors: Daniel A. De Schryver, Dominique Fasbinder
  • Patent number: 6235831
    Abstract: A polyalkylene terephthalate polymer, such as polyethylene terephthalate, polybutylene terephthalate, blends or copolymers thereof, and analogous polyester-type engineering thermoplastics, with which has been blended a flame retardant amount of brominated styrenic polymer, such as brominated polystyrene, that, prior to blending, is characterized by (a) containing less than 700 ppm Cl and having a TGA temperature for 1% weight loss of 340° C. or higher; and/or (b) having an actual Mw which is within about 20%, and preferably within about 10%, of its calculated theoretical Mw, the theoretical Mw being based upon the actual bromine content of the brominated styrenic polymer and the Mw of the styrenic polymer reactant used to produce the brominated styrenic polymer; and/or (c) being essentially free of each of the following impurities: (1) ethylene dichloride, (2) bromodichloroethane, (3) dibromochloroethane, (4) dibromodichloroethane, and (5) tribrormochloroethane.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: May 22, 2001
    Assignee: Albemarle Corporation
    Inventors: Jon S. Reed, Susan D. Landry, Daniel A. De Schryver, Billie B. Dadgar, Donald E. Balhoff, Charles H. Kolich, Meng-Sheng Ao, Homer C. Lin
  • Patent number: 5674972
    Abstract: This invention relates to polyamide-based formulations flame retarded with synergized brominated flame retardants and having good thermal stability.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: October 7, 1997
    Assignee: Albemarle Corporation
    Inventors: Luc Van Wabeeke, Daniel De Schryver