Abstract: This disclosure relates to catalysts and processes designed to convert DME and/or methanol and hydrogen (H2) to desirable liquid fuels. These catalysts produce the fuels efficiently and with a high selectivity and yield, and reduce the formation of aromatic hydrocarbons by incorporating H2 into the products. This disclosure also describes process methods to further upgrade these fuels to higher molecular weight liquid fuel mixtures, which have physical properties comparable with current commercially used liquid fuels.

Abstract: The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.

Abstract: This disclosure relates to catalysts and processes designed to convert DME and/or methanol and hydrogen (H2) to desirable liquid fuels. These catalysts produce the fuels efficiently and with a high selectivity and yield, and reduce the formation of aromatic hydrocarbons by incorporating H2 into the products. This disclosure also describes process methods to further upgrade these fuels to higher molecular weight liquid fuel mixtures, which have physical properties comparable with current commercially used liquid fuels.