Abstract: A reactive material for use as a reactive liner in penetrating (shape-charge) warheads and for use in reactive fragments in fragmenting warheads is disclosed. The reactive material comprises an oxidizing agent and a metal filler or metal/metal oxide filler. The oxidizing agent comprises a fluoropolymer having high fluorine content, a low melt temperature, and a high mechanical strength. Preferably, the fluoropolymer is a thermoplastic fluoropolymer, such as a polymer of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride. The metal filler comprises a high density, reactive metal. Preferably, the metal filler is hafnium or tantalum. The reactive material is safely processed at temperatures significantly below the thermal autoignition point of the reactive material.

Abstract: In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped pre-form, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a non-oxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Abstract: In this method for making a sintered reactive material, fuel particles are blended with a polymer matrix comprising at least one fluoropolymer in an inert organic media to disperse the fuel particles in the polymer matrix and form a reactive material. The reactive material is dried and pressed to obtain a shaped pre-form, which is sintered in an inert atmosphere to form the sintered reactive material. By sintering in an inert atmosphere, the sintered reactive material may include reactive metals and/or metalloids in a non-oxidized state. The resulting sintered reactive material preferably has a tensile strength in excess of 1800 psi and an elongation at break in excess of 30%.

Abstract: An extrudable black body decoy flare composition which, when combusted, provided black body radiation is disclosed. The compositions generally include from about 40% to about 70% metal such as magnesium or aluminum, from about 10% to about 40% polytetrafluoroethylene, and from about 8% to about 30% binder. Important to the operation of the invention is the production of carbon upon combustion of the composition. Accordingly, polyaromatic thermoplastics, such as polystyrene and dimethyl phthalate, serve as the binder.

Abstract: An extrudable black body decoy flare composition which, when combusted, provided black body radiation is disclosed. The compositions generally include from about 40% to about 70% metal such as magnesium or aluminum, from about 10% to about 40% polytetrafluoroethylene, and from about 8% to about 30% binder. Important to the operation of the invention is the production of carbon upon combustion of the composition. Accordingly, polyaromatic thermoplastics, such as polystyrene and dimethyl phthalate, serve as the binder.

Abstract: In this process for producing a black body decoy flare, a composition which, when combusted, provides black body radiation is extruded. The compositions generally include from about 40% to about 70% metal such as magnesium or aluminum, from about 10% to about 40% polytetrafluoroethylene, and from about 8% to about 30% binder. Important to the operation of the invention is the production of carbon upon combustion of the composition. Accordingly, polyaromatic thermoplastics, such as polystyrene and dimethyl phthalate, serve as the binder.

Abstract: The present invention relates to an igniter composition which is capable of being extruded to yield a robust igniter extrudate. The composition is particularly useful in the form of an igniter stick or other selected geometry for use in supplemental safety restraint systems designed for use such as in vehicles, ground or airborne, having such systems.

Abstract: Compositions are provided which, when burned, produce significant levels of infrared radiation, but only limited levels of visible radiation. The basic components of the compositions include a binder, an oxidizer, and a fuel, where the binder also acts the fuel. Preferred oxidizers include those compounds which produce large quantities of infrared radiation when the flare composition is burned. Such oxidizers include potassium nitrate, cesium nitrate, rubidium nitrate, and combinations of these compounds. Selection of the binder is important in order to provide the composition with the desirable characteristics identified above. The binder of the present invention does not produce significant soot. At the same time, the binder serves to form a composition which is processible, avoids chunking, and is compatible with the oxidizers used. It has been found that polymer binders which include relatively short carbon chains (1-6 continuous carbon atoms) are preferred.

Abstract: The present invention relates to flares and other solid propellant devices, rockets or the like, equipped with an igniter or igniter system which is based in whole in part on an extruded igniter stick.

Abstract: Compositions are provided which, when burned, produce significant levels of infrared radiation, but only limited levels of visible radiation. The basic components of the compositions include a binder, an oxidizer, and a fuel, where the binder also acts the fuel. Preferred oxidizers include those compounds which produce large quantities of infrared radiation when the flare composition is burned. Such oxidizers include potassium nitrate, cesium nitrate, rubidium nitrate, and combinations of these compounds. Selection of the binder is important in order to provide the composition with the desirable characteristics identified above. The binder of the present invention does not produce significant soot. At the same time, the binder serves to form a composition which is processible, avoids chunking, and is compatible with the oxidizers used. It has been found that polymer binders which include relatively short carbon chains (1-6 continuous carbon atoms) are preferred.

Abstract: Compositions are provided which, when burned, produce significant levels of infrared radiation, but only limited levels of visible radiation. The basic components of the compositions include a binder, an oxidizer, and an organic fuel. Preferred oxidizers include those compounds which produce large quantities of infrared radiation when the flare composition is burned. Such oxidizers include potassium nitrate, cesium nitrate, rubidium nitrate, and combinations of these compounds. The composition preferably includes significant quantities of cesium nitrate as an oxidizer. Selection of the binder is important in order to provide the composition with the desirable characteristics identified above. The binder of the present invention does not produce significant soot when burned. At the same time, the binder serves to form a composition which is processible, avoids chunking, and is compatible with the oxidizers used.

Abstract: This invention relates to the production of black body-generating decoy flares for thrusted applications. Compositions are provided which, when combusted, provide black body radiation. The compositions generally include from about 20% to about 60% metal, such as magnesium or aluminum, from about 5% to about 50% ammonium perchlorate, and from about 8% to about 30% binder. Important to operation of the present invention is the production of graphitized carbon upon combustion of the composition. Accordingly, high carbon content materials are added to the compositions. These materials may include from about 5% to about 30% polyaromatic compounds, such as decacyclene, anthracene, and naphthalene. Other suitable high carbon materials include polyolefins. This invention also discloses methods of using these compositions in thrusted decoy flare applications.

Abstract: A covert, i.e., no visible light emitted, multispectral day/night target marker is disclosed. The marker emits a signature detectable in the electromagnetic spectrum including visible, near infrared, middle and longwave infrared, and radar regions. The marker is particularly useful for marking of target areas so that they can be easily detected from the ground or the air. The visible spectrum is marked by a white or colored pyrotechnic smoke generant. The near infrared region is marked by near infrared emitting photodiodes encased in a hardened polymeric molding compound. These diodes are only visible through night vision devices (image intensifiers). The middle through the far infrared regions are marked by the heat generated from the combustion of the pyrotechnic smoke generant. The smoke generant is housed in a canister having a highly emissive surface. The radar region is marked using radar chaff. The target marker is configured for use with conventional mortar or rocket delivered flare systems.

Abstract: Convert infrared tracer compositions are provided. The compositions are formed using peroxide such as strontium peroxide and barium peroxide. Added to these materials is a burn rate catalyst such as boron, iron oxide, cupric oxide, manganese dioxide, carbon, silicon, graphite fibrils, amorphous silica, copper oxide, potassium dodecaborate, the dipotassium salt of bitetrazole amine, and the potassium salt of dilituric acid. The composition also includes alkali metal compounds in order to enhance the infrared emissions. The compositions are bound together using a binder such that the composition results in a granular material having a mean particle size in the range of from about 500.mu. to about 800.mu..

Abstract: Conductive carbon fibrils are incorporated into energetic compositions to enhance the burn rate. The carbon fibrils are grown catalytically from carbon precursors and are substantially free of pyrolytically deposited thermal carbon. The fibrils generally have a length in the range from about 1.mu. to about 10.mu. and a diameter in the range from about 3.5 nanometers to about 75 nanometers. Length to diameter aspect ratios are greater than 5, and typically in the range from about 100:1 to about 1000:1. A 100% improvement in burn rate was observed in compositions containing as little as 0.1 weight percent carbon fibrils. Greater amounts of carbon fibrils (2 weight percent) have increased the burn rate 500%. In most cases, fibril concentration will be in the range from about 0.1 to about 2 weight percent, although greater amounts are possible. The burn rate may be effectively tailored by varying the amount of fibrils added to the composition.

Abstract: A composition which is capable of producing an obscuring white smoke is disclosed which employs a dicarboxylic acid as the primary smoke producing agent. It is found that by using a dicarboxylic acid smoke producing agent, a generally non-toxic and non-corrosive smoke is achieved. Also included within the composition are a binder, a fuel or coolant, and an oxidizer. The binder may be any one of a number of binders such as nitrocellulose or a polymer binder. A low energy fuel is preferred in order to minimize heat and flame produced. Such fuels may include, for example, starch, dextrose, lactose, sucrose, or sulphur. The presently preferred oxidizer is KCLO.sub.3. Other substances may also be added to the composition. For example, sodium bicarbonate may be added to act as a buffer for the KCLO.sub.3 and as a further coolant. In some cases it may also be desirable to add aluminum for purposes of producing more uniform burning and increased thermal conductivity through out the composition.

Abstract: An infrared illuminant composition and flares produced therefrom having increased burn rate and increased infrared intensity while maintaining low visible light intensity. The composition comprises potassium nitrate, cesium nitrate, hexamine, boron, silicon, ferric oxide and a binder. A process to produce infrared illuminant flares prevents or substantially eliminates chunking out of burning pieces of the illuminant at pressing increments in the flares.