Abstract: The present invention relates to a process and apparatus for quantifying solid residue on a sample. The process includes using a solid substrate and an aerosolizing device, adding a solid material to the aerosolizing device, forming a particle cloud of solid particles, wherein at least 1% of the mass concentration of solid particles have a mass median aerodynamic particle diameter up to about 10 ?m, thus applying the solid particles to the solid substrate(s) to form treated substrate(s), maintaining at a temperature of from about 30 to about 120° C. for at least a portion of the process, and removing a portion of solid particles from the treated substrate(s), and analyzing said at least one sample. The present invention further comprises an apparatus for applying solid particles to a substrate. The process can be used, for example, to analyze the dirt pickup resistance of a solid sample.

Abstract: The disclosure provides a coating composition comprising a treated inorganic core particle, having improved dispersability, prepared by a process comprising: heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C., more typically about 93 to about 97° C., still more typically about 95 to about 97° C.; and adding a soluble alumina source to the slurry while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of about 7% to about 14% and alumina present in the amount of about 4.0% to about 8.0%; and wherein the particle to particle surface treatments are substantially homogeneous.

Abstract: Inkjet inks are provided, relating in particular to smear resistant inkjet inks, and even more particularly to smear resistant pigmented aqueous inkjet inks comprising polyurethane dispersions and self-dispersing pigments. The polyurethane dispersions have a glass transition temperature Tg greater than ?30 ° C. to less than about 35 ° C. and have at least one of the following thermal properties: loss modulus E? of 1.7 to 5×108 pascals, and/or a peak tan delta is 0.23 to 0.65, where the glass transition temperature, peak tan delta and the loss modulus are measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

Abstract: The disclosure provides a coating composition comprising a treated inorganic core particle, having improved dispersability, prepared by a process comprising: heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C., more typically about 93 to about 97° C., still more typically about 95 to about 97° C.; and adding a soluble alumina source to the slurry while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of about 7% to about 14% and alumina present in the amount of about 4.0% to about 8.0%; and wherein the particle to particle surface treatments are substantially homogeneous.

Abstract: The disclosure provides a paper slurry comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.

Abstract: The disclosure provides a polymer composition comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.

Abstract: The disclosure provides a treated inorganic pigment, typically a titanium dioxide pigment, comprising an inorganic pigment having a surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, based on the total weight of the treated pigment; wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11. The treated inorganic pigments have better flow characteristics, and generally fewer lumps.

Abstract: The disclosure provides a coating composition comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.

Abstract: The disclosure provides a paper slurry comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.

Abstract: This disclosure relates to ink composition, having a viscosity of 0.02-13 Poise, comprising an inorganic pigment surface treated with alumina and at least one silicon based surface treatment selected from the group consisting of polysiloxane and polysiloxane block polymer to form a treated inorganic pigment, wherein the silicon based surface treatment is present in the amount of about 0.3 to about 1%, based on the total weight of the treated inorganic pigment; a binder resin having a glass transition temperature of less than 50° C., and comprising at least one adhesion promoting group; and a solvent based ink vehicle having the following solubility parameters using the MPa1/2 units: ?d of greater than about 15.9, a ?p of less than about 9.1 and a ?h of less than about 12.1. These inks have enhanced gloss and lower viscosity characteristics.

Abstract: Inkjet inks are provided, in particular to smear resistant inkjet inks, and even more particularly to smear resistant pigmented aqueous inkjet inks comprising polyurethane dispersions and self-dispersing pigments. The polyurethane dispersions have a glass transition temperature Tg greater than ?30° C. to less than about 35° C. and has at least one of the following thermal properties loss modulus E? of 1.7 to 5×108 pascals, and/or a peak tan delta is 0.23 to 0.65, where the glass transition temperature, peak tan delta and the loss modulus are measured by dynamic mechanical analysis on a film prepared from the polyurethane dispersion.

Abstract: A pigment dispersion useful for forming coating compositions containing dispersed pigment, a non-aqueous carrier liquid and an ABC-block polymer dispersant (binder); wherein the ABC block polymer has a number average molecular weight of about 5,000-20,000 and contains a polymeric A segment, a polymeric B segment and a polymeric C segment; wherein the polymeric A segment of the block polymer is of polymerized monomers selected from the following group: alkyl (meth)acrylate monomers having 1-12 carbon atoms in the alkyl group, aryl (meth)acrylate monomers, cyclo alkyl (meth)acrylate monomers or mixtures of any of the above; the polymeric B segment of the block polymer is of polymerized alkyl amino alkyl (meth)acrylate monomers having 1-4 carbon atoms in the alkyl group quaternized with an alkylating agent; and the polymeric C segment of the block polymer is of polymerized monomers of hydroxy alkyl (meth)acrylate having 1-4 carbon atoms in the alkyl group and monomers selected from the following group: alkyl

Abstract: Acrylic AB block copolymers prepared by group transfer polymerization that are useful as pigment dispersants, characterized by mononuclear or dinuclear heterocyclic groups bonded to the highly polar anchoring A segment of the block copolymer backbone to facilitate attachment on a pigment surface and improve dispersant efficiency in solvent-borne paint systems.