Abstract: A new class of phase change materials has been discovered based on compounds of: Ga; lanthanide; and chalcogenide. This includes compounds of Ga, La, and S (GLS) as well as related compounds in which there is substitution of S with O, Se and/or Te. Moreover, La can be substituted with other lanthanide series elements. It has been demonstrated that this class of materials exhibit low energy switching. For example, the GLS material can provide an optical recording medium with erasability 3-5 dB greater than the erasability of GeSbTe (GST) material which is the standard material for phase change memories.

Abstract: The invention relates to synthesis of germanium sulphide glasses and optical devices formed therefrom. In a chemical vapour deposition process, germanium tetrachloride is reacted with hydrogen sulphide at temperatures in the range 450-700° C. to form germanium sulphide. Lower temperatures within this range of 450-550° C. directly produce a glass, whereas higher temperatures within the range of 600-700° C. produce a crystalline powder which can then be reduced to a glass by subsequent melting and annealing. The reaction is preferably carried out at atmospheric pressure or slightly higher. Thin films and bulk glasses suitable for optical waveguides can be formed directly in one processing step as can powders and microspheres. The materials synthesised are of a high purity with low oxide impurities and only trace levels of transition metal ions.

Abstract: Microstructured optical fibre is fabricated using extrusion. The main design of optical fibre has a core suspended in an outer wall by a plurality of struts. A specially designed extruder die is used which comprises a central feed channel, flow diversion channels arranged to divert material radially outwards into a welding chamber formed within the die, a core forming conduit arranged to receive material by direct onward passage from the central feed channel, and a nozzle having an outer part in flow communication with the welding chamber and an inner part in flow communication with the core forming conduit, to respectively define an outer wall and core of the preform. With this design a relatively thick outer wall can be combined with thin struts (to ensure extinction of the optical mode field) and a core of any desired diameter or other thickness dimension in the case of non-circular cores. As well as glass, the extrusion process is suitable for use with polymers.

Abstract: An optical waveguide includes a clad of clad glass and a core of core glass. The clad glass includes gallium, lanthanum, and sulfur. The clad glass may include gallium sulfide and lanthanum oxide. The clad glass may also include lanthanum fluoride. The core glass includes gallium, lanthanum, sulfur, oxygen, and fluorine. The core glass may include gallium sulfide, lanthanum oxide, and lanthanum fluoride. An optical fiber perform is also disclosed.