Abstract: Disclosed herein are methods of synthesizing a hybrid nanomaterial comprising 3D out-of-plane single- to few-layer fuzzy graphene on a scaffold, such as a Si nanowire mesh through a plasma-enhanced chemical vapor deposition process. By varying graphene growth conditions (CH4 partial pressure and process time), the size, density, and electrical properties of the hybrid nanomaterial can be controlled. Porous nanowire-templated 3D graphene hybrid nanomaterials exhibit high electrical conductivity and also demonstrate exceptional electrochemical functionality.