Abstract: A process for producing multicoat paint systems by (I) applying a dual-cure primer (A) curable thermally and with actinic radiation to a substrate to give a primer film (A), (II) exposing the primer film (A) to actinic radiation to give a partially cured primer film (A), (III) applying a pigmented coating material (B) curable thermally and/or a pigmented dual-cure coating material (B) to the partially cured primer film (A) to give at least one pigmented film (B), (IV) exposing the dual-cure film (B) to actinic radiation to give a partially cured film (B), (V) applying a clearcoat material (C) curable with actinic radiation and/or a dual-cure clearcoat material (C) to the film (B) to give a clearcoat and/or a dual-cure clearcoat film (C), (VI) exposing the clearcoat film(s) (C) to actinic radiation to give a dual-cure clearcoat (C) and/or a partially cured clearcoat film (C), and (VII) subjecting the films (A), (B), and (C) to joint thermal curing when still only partially cured.

Abstract: Coating materials curable thermally, or thermally and with actinic radiation, comprising (A) binder selected from the group consisting of random, alternating and block, linear, branched and comb polyaddition resins, polycondensation resins, and addition (co)polymers of olefinically unsaturated monomers, curable physically, thermally, with actinic radiation, and thermally and with actinic radiation; and (B) nanoparticles selected from the group consisting of nanoparticles modified with at least one compound of the general formula I: [(S—)o-L-]n-M-(—X—R)m?n , ??(I) ?where the indices and the variables have the following meanings: S is a reactive functional group having at least one bond which can be activated with actinic radiation; L is at least one divalent organic linking group; X independently at each occurrence is an oxygen atom, sulfur atom or>NR1, where R1=hydrogen atom or alkyl group having from 1 to 4 carbon atoms; M is a metal atom; R is a monovalent organic radical; o is an integer from 1 to

Abstract: A process for producing multicoat paint systems by (I) applying a dual-cure primer (A) curable thermally and with actinic radiation to a substrate to give a primer film (A), (II) exposing the primer film (A) to actinic radiation to give a partially cured primer film (A), (III) applying a pigmented coating material (B) curable thermally and/or a pigmented dual-cure coating material (B) to the partially cured primer film (A) to give at least one pigmented film (B), (IV) exposing the dual-cure film (B) to actinic radiation to give a partially cured film (B), (V) applying a clearcoat material (C) curable with actinic radiation and/or a dual-cure clearcoat material (C) to the film (B) to give a clearcoat and/or a dual-cure clearcoat film (C), (VI) exposing the clearcoat film(s) (C) to actinic radiation to give a dual-cure clearcoat (C) and/or a partially cured clearcoat film (C), and (VII) subjecting the films (A), (B), and (C) to joint thermal curing when still only partially cured.

Abstract: Coating materials curable thermally, or thermally and with actinic radiation, comprising