Abstract: An alloy according to example embodiments of the present invention may include zirconium, tin, iron, chromium, and nickel, with a majority of the alloy being zirconium. The composition of the alloy may be about 0.85-2.00% tin by weight, about 0.15-0.30% iron by weight, about 0.40-0.75% chromium by weight, and less than 0.01% nickel by weight. The alloy may further include 0.004-0.020% silicon by weight, 0.004-0.020% carbon by weight, and/or 0.05-0.20% oxygen by weight. Accordingly, the alloy exhibits reduced hydrogen absorption and improved corrosion resistance and may be used to form a fuel assembly component.

Abstract: Disclosed herein are zirconium-based alloys and methods of fabricating nuclear reactor components, particularly fuel cladding tubes, from such alloys that exhibit improved corrosion resistance in aggressive coolant compositions. The fabrication steps include a late-stage ?-treatment on the outer region of the tubes. The zirconium-based alloys will include between about 1.30 and 1.60 wt % tin; between about 0.06 and 0.15 wt % chromium; between about 0.16 and 0.24 wt % iron, and between 0.05 and 0.08 wt % nickel, with the total content of the iron, chromium and nickel comprising above about 0.31 wt % of the alloy and will be characterized by second phase precipitates having an average size typically less than about 40 nm. The final finished cladding will have a surface roughness of less than about 0.50 ?m Ra and preferably less then about 0.10 ?m Ra.

Abstract: Disclosed herein are zirconium-based alloys that may be fabricated to form nuclear reactor components, particularly fuel cladding tubes, that exhibit sufficient corrosion resistance and hydrogen absorption characteristics, without requiring a late stage ?+? or ?-quenching processes. The zirconium-base alloys will include between about 1.30-1.60 wt % tin; 0.0975-0.15 wt % chromium; 0.16-0.24 wt % iron; and up to about 0.08 wt % nickel, with the total content of the iron, chromium and nickel comprising at least about 0.3175 wt % of the alloy. The resulting components will exhibit a surface region having a mean precipitate sizing of between about 50 and 100 nm and a Sigma A of less than about 2×10?19 hour with the workpiece processing generally being limited to temperatures below 680° C. for extrusion and below 625° C. for all other operations, thereby simplifying the fabrication of the nuclear reactor components while providing corrosion resistance comparable with conventional alloys.

Abstract: An alloy according to example embodiments of the present invention may include zirconium, tin, iron, chromium, and nickel, with a majority of the alloy being zirconium. The composition of the alloy may be about 0.85-2.00% tin by weight, about 0.15-0.30% iron by weight, about 0.40-0.75% chromium by weight, and less than 0.01% nickel by weight. The alloy may further include 0.004-0.020% silicon by weight, 0.004-0.020% carbon by weight, and/or 0.05-0.20% oxygen by weight. Accordingly, the alloy exhibits reduced hydrogen absorption and improved corrosion resistance and may be used to farm a fuel assembly component.

Abstract: Example embodiments are directed to providing a thin, adherent coating on the surfaces of nuclear reactor components, which are known to cause increased corrosion on adjacent zirconium alloy structures, and methods of reducing the increased corrosion. Example embodiments include coatings being structurally bonded to components such that the difference in the corrosion potential between a coated component and a zirconium alloy component is less than that between a component without the coating and the zirconium alloy component.

Abstract: A method for fabricating a composite cladding comprised of a moderate-purity metal barrier of zirconium metallurgically bonded on the inside surface of a zirconium alloy tube which improves corrosion resistance. The improved corrosion resistance of the liner is accomplished by suitable heat treatment of the Zircaloy-zirconium composite cladding to allow diffusion of alloying elements, notably Fe and Ni, from the Zircaloy into the zirconium, in particular, to the inner surface of the zirconium liner. This diffusion anneal reduces the undesirable tendency of zirconium liner to oxidize rapidly.

Abstract: A cladding tube having a cross-section and including (1) a zirconium alloy outer circumferential substrate having an inner surface and having one or more alloying elements, (2) a zirconium barrier layer bonded to the inner surface of the outer circumferential substrate and being alloyed with the one or more alloying elements, and (3) a zirconium alloy inner circumferential liner bonded to the inner surface of the zirconium barrier layer. The barrier layer will have a concentration profile including a diffusion layer extending from the barrier layer's inner surface (facing nuclear fuel) to the barrier layer's interior (between the barrier layer's inner and outer surfaces). At the interior edge of the diffusion layer, there will be substantially no alloying elements. At the outer edge of the diffusion layer (the barrier layer's inner surface), the maximum concentration of alloying elements will occur.

Abstract: A method is provided for forming a three-layer cladding tube having an outer substrate, a zirconium barrier layer, and an inner liner having alloying elements, in which the zirconium barrier layer (located between an outer substrate and inner liner) is at least partially alloyed with alloying elements that impart resistance to corrosion. The barrier layer has a diffusion layer extending from its inner surface (facing the fuel) to the barrier layer's interior (the interior being defined between the barrier layer's inner and outer surfaces). At the interior edge of the diffusion layer, there will be substantially no alloying elements beyond those normally present in zirconium. The methods of forming such structure include a diffusion anneal of a three-layer cladding in the range of 650.degree.-1000.degree. C. for times between about 1 minute and 20 hours. This anneal drives some of the alloying elements from the inner liner into the zirconium barrier layer to form the diffusion layer.

Abstract: A method for fabricating a composite cladding comprised of a moderate-purity metal barrier of zirconium metallurgically bonded on the inside surface of a zirconium alloy tube which improves corrosion resistance. The improved corrosion resistance of the liner is accomplished by suitable heat treatment of the Zircaloy-zirconium composite cladding to allow diffusion of alloying elements, notably Fe and Ni, from the Zircaloy into the zirconium, in particular, to the inner surface of the zirconium liner. This diffusion anneal reduces the undesirable tendency of zirconium liner to oxidize rapidly.