Abstract: A catalyst for storing nitrogen oxides (NOx) in an exhaust gas from a lean burn engine comprising a NOx storage material and a substrate, wherein the NOx storage material comprises a NOx storage component and an NO oxidation promoter on a support material, wherein the NO oxidation promoter is manganese or an oxide, hydroxide or carbonate thereof.

Abstract: An exhaust system (10) for a lean-burn internal combustion engine (12) comprises a first substrate monolith (16) comprising a catalyst for oxidizing nitric oxide (NO) comprising a catalytic oxidation component followed downstream by a second substrate monolith (18) which is a wall-flow filter having inlet channels and outlet channels, wherein the inlet channels comprise a NOx absorber catalyst (20) and the outlet channels comprise a catalyst for selective catalytic reduction (22) of nitrogen oxides with nitrogenous reductant.

Abstract: A NOx trap, and its use in an exhaust system for internal combustion engines, is disclosed. The NOx trap comprises a substrate and three layers on the substrate. The first layer comprises a first platinum group metal, a first NOx storage component, and a first support; the second layer comprises a second platinum group metal, a second NOx storage component, and a second support; and the third layer comprises rhodium and a third support. The platinum group metal loading in the first layer is from 1 to 40 percent of the platinum group metal loading in the second layer. In addition, the first NOx storage component and the second NOx storage component are the same, and the first support and the second support are the same. The NOx trap is less prone to deactivation over numerous desulfation/NOx trap regeneration cycles.

Abstract: An exhaust system for treating an exhaust gas from an internal combustion engine is disclosed. The system comprises a modified lean NO trap (LNT), a urea injection system, and an ammonia-selective catalytic reduction catalyst. The modified LNT comprises a first layer and a second layer. The first layer comprises a NO adsorbent component and one or more platinum group metals. The second layer comprises a diesel oxidation catalyst zone and an NO oxidation zone. The diesel oxidation catalyst zone comprises a platinum group metal, a zeolite, and optionally an alkaline earth metal. The NO oxidation zone comprises a platinum group metal and a carrier. The modified LNT stores NO at temperatures below about 200° C. and releases at temperatures above about 200° C. The modified LNT and a method of using the modified LNT are also disclosed.

Abstract: An apparatus is disclosed. The apparatus comprises a lean-burn internal combustion engine, engine management means and an exhaust system for treating exhaust gas of the engine. The exhaust system comprises a first oxidation catalyst disposed on a first honeycomb monolith substrate. The first oxidation catalyst comprises platinum supported on a first metal oxide support comprising at least one reducible oxide, and is substantially free of alkali metals and alkaline earth metals. The engine management means is arranged, when in use, intermittently to modulate the lambda composition of the exhaust gas entering the first oxidation catalyst to a rich lambda composition.

Abstract: An apparatus is disclosed. The apparatus comprises a lean-burn internal combustion engine, engine management means and an exhaust system for treating exhaust gas of the engine. The exhaust system comprises a first oxidation catalyst disposed on a first honeycomb monolith substrate. The first oxidation catalyst comprises platinum supported on a first metal oxide support comprising at least one reducible oxide, and is substantially free of alkali metals and alkaline earth metals. The engine management means is arranged, when in use, intermittently to modulate the lambda composition of the exhaust gas entering the first oxidation catalyst to a rich lambda composition.

Abstract: A zoned catalysed substrate monolith comprises a first zone and a second zone that are arranged axially in series. The first zone comprises a platinum group metal loaded on a support and a first base metal oxide or a first base metal loaded on an inorganic oxide. The first base metal oxide is iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, or mixtures thereof. The first base metal is iron, manganese, copper, zinc, nickel, or mixtures thereof. The second zone comprises copper or iron loaded on a zeolite and a second base metal oxide or a second base metal loaded on an inorganic oxide. The second base metal oxide is iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, or mixtures thereof. The second base metal is iron, manganese, copper, zinc, nickel, or mixtures thereof. The second base metal is different from the first base metal.

Abstract: A NOx absorber catalyst comprising a substrate monolith coated with one or more washcoat layers and comprising a first component comprising a nitrogen oxide storage component, at least one precious metal and a dispersed rare earth oxide supported on a refractory support material, and a second component comprising a precious metal supported on a bulk reducible oxide that is substantially free of nitrogen oxide storage material, wherein the precious metal present in the second component comprises Pt, Pd or a combination of both Pt and Pd and wherein the bulk reducible oxide is an oxide, a composite oxide or a mixed oxide comprising at least one of manganese, iron, cobalt, copper, tin or cerium.

Abstract: An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising a first platinum group metal (PGM), a first support material and a NOx storage component; a second washcoat region comprising platinum (Pt), manganese (Mn) and a second support material; and a substrate having an inlet end and an outlet end.

Abstract: A NOx trap, and its use in an exhaust system for internal combustion engines, is disclosed. The NOx trap comprises a substrate and three layers on the substrate. The first layer comprises a first platinum group metal, a first NOx storage component, and a first support; the second layer comprises a second platinum group metal, a second NOx storage component, and a second support; and the third layer comprises rhodium and a third support. The platinum group metal loading in the first layer is from 1 to 40 percent of the platinum group metal loading in the second layer. In addition, the first NOx storage component and the second NOx storage component are the same, and the first support and the second support are the same. The NOx trap is less prone to deactivation over numerous desulfation/NOx trap regeneration cycles.

Abstract: An exhaust system for treating an exhaust gas from an internal combustion engine is disclosed. The system comprises a modified lean NOx trap (LNT), a urea injection system, and an ammonia-selective catalytic reduction (NH3-SCR) catalyst. The modified LNT comprises platinum, palladium, barium, and a ceria-containing material, and has a platinum:palladium molar ratio of at least 3:1. The modified LNT stores NOx at temperatures below about 200° C. and releases the stored NOx at temperatures above about 200° C. The urea injection system injects urea at temperatures above about 180° C.

Abstract: An exhaust system (10) for a lean-burn internal combustion engine (12) comprises a first substrate monolith (16) comprising a catalyst for oxidising nitric oxide (NO) comprising a catalytic oxidation component followed downstream by a second substrate monolith (18) which is a wall-flow filter having inlet channels and outlet channels, wherein the inlet channels comprise a NOx absorber catalyst (20) and the outlet channels comprise a catalyst for selective catalytic reduction (22) of nitrogen oxides with nitrogenous reductant.

Abstract: An exhaust system, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NOx trap and the catalyzed substrate. The catalyzed substrate has a first zone, having a platinum group metal loaded on a support, and a second zone, having copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH3 generated in rich purging, reacting the NH3 with slip NOx, controlling H2S released from NOx trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.

Abstract: An exhaust system (10) for a lean-burn internal combustion engine (12) comprises a first substrate monolith (16) comprising a catalyst for oxidizing nitric oxide (NO) comprising a catalytic oxidation component followed downstream by a second substrate monolith (18) which is a wall-flow filter having inlet channels and outlet channels, wherein the inlet channels comprise a NO x absorber catalyst (20) and the outlet channels comprise a catalyst for selective catalytic reduction (22) of nitrogen oxides with nitrogenous reductant.

Abstract: An exhaust system for internal combustion engines, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NOx trap and the catalyzed substrate. The catalyzed substrate has a first zone and a second zone, wherein the first zone comprises a platinum group metal loaded on a support and the second zone comprises copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH3 generated in rich purging, reacting the NH3 with slip NOx from the NOx trap, controlling H2S released from NOx trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.

Abstract: A NOx absorber catalyst comprising an extruded solid body comprises either: (A) 10-95% by weight of at least one binder/matrix component; and 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof, which catalyst comprising at least one metal comprising (a) at least one precious metal; and (b) at least one alkali metal or at least one alkaline earth metal, wherein (a) and (b) are carried in one or more coating layer(s) on a surface of the extruded solid body; or (B) 10-95% by weight of at least one binder/matrix component; and 5-80% by weight optionally stabilized ceria, which catalyst comprising at least one metal comprising (a) at least one precious metal; and (b) at least one alkali metal or at least one alkaline earth metal.

Abstract: An apparatus is disclosed. The apparatus comprises a lean-burn internal combustion engine, engine management means and an exhaust system for treating exhaust gas of the engine. The exhaust system comprises a first oxidation catalyst disposed on a first honeycomb monolith substrate. The first oxidation catalyst comprises platinum supported on a first metal oxide support comprising at least one reducible oxide, and is substantially free of alkali metals and alkaline earth metals. The engine management means is arranged, when in use, intermittently to modulate the lambda composition of the exhaust gas entering the first oxidation catalyst to a rich lambda composition.

Abstract: A NOx absorber catalyst comprising a substrate monolith coated with one or more washcoat layers and comprising a first component comprising a nitrogen oxide storage component, at least one precious metal and a dispersed rare earth oxide supported on a refractory support material, and a second component comprising a precious metal supported on a bulk reducible oxide that is substantially free of nitrogen oxide storage material, wherein the precious metal present in the second component comprises Pt, Pd or a combination of both Pt and Pd and wherein the bulk reducible oxide is an oxide, a composite oxide or a mixed oxide comprising at least one of manganese, iron, cobalt, copper, tin or cerium.

Abstract: An exhaust system, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NOx trap and the catalyzed substrate. The catalyzed substrate has a first zone, having a platinum group metal loaded on a support, and a second zone, having copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH3 generated in rich purging, reacting the NH3 with slip NOx, controlling H2S released from NOx trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.

Abstract: An exhaust system, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NO trap and the catalyzed substrate. The catalyzed substrate has a first zone, having a platinum group metal loaded on a support, and a second zone, having copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH3 generated in rich purging, reacting the NH3 with slip NOX, controlling H2S released from NO trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.