Abstract: Processes, catalysts and systems for preparing a composition comprising aliphatic, olefinic, cyclic and/or aromatic hydrocarbons of seven or greater carbon atoms per molecule are provided.

Abstract: Methods and systems for processing a first composition of a light hydrocarbon mixture with a 100° F. vapor pressure range from 2 to 51 psia into a second composition of aromatic hydrocarbons are provided. The method comprises contacting the first composition with a reaction zone comprising three or more operating fixed bed reactors in series, each reactor containing porous solid acid catalyst, said method further comprising the step of adding a toluene feedstock to said reaction zone under conditions in which the first composition is transformed to a second composition in an amount greater and at a percentage higher in aromatics than produced via a parallel or single reactor process with the same catalyst without the toluene feedstock, and/or contacting said second composition comprising heavy aromatics with said reaction zone to further increase amount and percentage of aromatics.

Abstract: Processes, catalysts and systems for preparing a composition comprising aliphatic, olefinic, cyclic and/or aromatic hydrocarbons of seven or greater carbon atoms per molecule are provided.

Abstract: Described herein are materials and methods for improved catalytic oligomerization of an ethylene monomer and/or propylene monomer. The present disclosure teaches oligomerizing the ethylene monomer or propylene monomer to produce oligomers. Also described is a heterogeneous catalyst comprising sulfate modified nickel on titanium modified alumina and a surface modification with yttrium (Y) suitable for use in the disclosed oligomerization.

Abstract: Described herein are processes for the conversion of ethylene into CS+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dearomatization catalyst.

Abstract: Described herein are processes for the conversion of ethylene into CS+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dehydroaromatization catalyst.

Abstract: Described herein are processes for the conversion of ethylene into C5+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dehydroaromatization catalyst.

Abstract: Described herein are processes for the conversion of ethylene into CS+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dehydroaromatization catalyst.

Abstract: Described herein are materials and methods for improved catalytic oligomerization of an ethylene monomer and/or propylene monomer. The present disclosure teaches oligomerizing the ethylene monomer or propylene monomer to produce oligomers. Also described is a heterogeneous catalyst comprising sulfate modified nickel on titanium modified alumina and a surface modification with yttrium (Y) suitable for use in the disclosed oligomerization.

Abstract: Described herein are processes for the conversion of ethylene into C5+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dehydroaromatization catalyst.

Abstract: A catalyst comprising palladium supported on a titania-alumina extrudate is disclosed. The extrudate comprises at least 80 wt % titania and 0.1 to 15 wt % alumina. A palladium catalyst prepared from the titania-alumina extrudate has significantly higher crush strength. Its catalytic performance in vinyl acetate production is improved.

Abstract: A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. The catalyst is useful in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.

Abstract: An extrudate comprising titania, a carboxyalkyl cellulose, and a hydroxyalkyl cellulose is disclosed. The extrudates have a smooth outer surface when they exit the extruder. The extrusion processibility is improved.

Abstract: A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. The catalyst is useful in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.

Abstract: A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. After calcination, the in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.

Abstract: An extrudate comprising at least 50 wt % titania, 0.5 to 25 wt % tungsta, and 0.5 to 35 wt % alumina is disclosed. The extrudate has improved crush strength compared with a titania-tungsta extrudate. A palladium catalyst prepared from the extrudate has good activity in preparing an acetoxylated olefin from an olefin, oxygen, and acetic acid.

Abstract: A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. The catalyst is useful in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.

Abstract: A method for preparing a palladium-gold catalyst containing a titania extrudate is disclosed. The titania extrudate is produced by using a carboxyalkyl cellulose and a hydroxyalkyl cellulose as extrusion aids. The titania extrudate has improved processibility and/or mechanical properties. After calcination, the extrudate is used as a carrier for the palladium-gold catalyst. The catalyst is useful in producing vinyl acetate by oxidizing ethylene with oxygen in the presence of acetic acid.

Abstract: An extrudate comprising titania, a carboxyalkyl cellulose, and a hydroxyalkyl cellulose is disclosed. The extrudates have a smooth outer surface when they exit the extruder. The extrusion processibility is improved.

Abstract: Disclosed is a catalyst. The catalyst comprises palladium, gold, and a support comprising titanium dioxide and tungsten trioxide. The support preferably comprises from 75 wt % to 99 wt % of titanium dioxide and from 1 wt % to 25 wt % of tungsten trioxide. A method for preparing the catalyst is also disclosed. The method comprises impregnating the support with a palladium compound and a gold compound, calcining the impregnated support, and then reducing the calcined support. Further disclosed is a method for preparing vinyl acetate with the catalyst. The catalyst exhibits improved catalytic activity and selectivity.