Patents by Inventor Daniel W. Klosiewicz

Daniel W. Klosiewicz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7176259
    Abstract: This invention relates High Density Polyethylene (HDPE) films having improved barrier properties. More particularly, the invention relates to HDPE films containing hydrocarbon resins having improved moisture barrier. The invention also relates to masterbatches for use in producing High Density Polyethylene films having improved barrier properties.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: February 13, 2007
    Assignee: Eastman Chemical Resins, Inc.
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6969740
    Abstract: This invention relates High Density Polyethylene (HDPE) films having improved barrier properties. More particularly, the invention relates to HDPE films containing hydrocarbon resins having improved moisture barrier. The invention also relates to masterbatches for use in producing High Density Polyethylene films having improved barrier properties.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: November 29, 2005
    Assignee: Eastman Chemical Resins, Inc.
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6663970
    Abstract: The instant invention relates to an epoxy/alkylation-type hydrocarbon resin alloy comprising an epoxy resin, an alkylation-type hydrocarbon resin, and a curative. The alkylation-type hydrocarbon resin is characterized as a product formed by an alkylation reaction between a cyclic diolefin and aromatic solvent. A particularly effective alkylation-type hydrocarbon resin in this invention is the alkylation resin formed by the reaction of dicyclopentadiene (DCPD) with alkylnaphthalene solvent. The alkylation-type hydrocarbon resin can be readily dissolved into various epoxy resins and easily processed into resin impregnated glass cloth prepreg for ultimate conversion into electronic laminate products. These epoxy/alkylation-type hydrocarbon resin alloys retain high Tg values with minimal increase in thermal expansion.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: December 16, 2003
    Assignee: Eastman Chemical Resins Inc.
    Inventor: Daniel W. Klosiewicz
  • Publication number: 20030055175
    Abstract: This invention relates High Density Polyethylene (HDPE) films having improved barrier properties. More particularly, the invention relates to HDPE films containing hydrocarbon resins having improved moisture barrier. The invention also relates to masterbatches for use in producing High Density Polyethylene films having improved barrier properties.
    Type: Application
    Filed: May 24, 2002
    Publication date: March 20, 2003
    Applicant: Eastman Chemical Resins Inc.
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6432496
    Abstract: This invention relates High Density Polyethylene (HDPE) films having improved barrier properties. More particularly, the invention relates to HDPE films containing hydrocarbon resins having improved moisture barrier. The invention also relates to masterbatches for use in producing High Density Polyethylene films having improved barrier properties.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: August 13, 2002
    Assignee: Eastman Chemical Company
    Inventor: Daniel W. Klosiewicz
  • Publication number: 20020103300
    Abstract: This invention relates High Density Polyethylene (HDPE) films having improved barrier properties. More particularly, the invention relates to HDPE films containing hydrocarbon resins having improved moisture barrier. The invention also relates to masterbatches for use in producing High Density Polyethylene films having improved barrier properties.
    Type: Application
    Filed: June 5, 1998
    Publication date: August 1, 2002
    Inventor: DANIEL W. KLOSIEWICZ
  • Patent number: 6281290
    Abstract: Masterbatches comprising high density polyethylene (HDPE) are used for the production of polyolefin articles, particularly films. Employing HDPE in a masterbatch alone or in combination with a hydrocarbon resin and/or a polyolefin ultimately results in extruded polyolefin articles of optimal stiffness and ductility. Employing a high density polyethylene in combination with a hydrocarbon resin and a polyolefin in a masterbatch causes the masterbatch to solidify more rapidly and be pelletized more efficiently.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: August 28, 2001
    Assignee: Eastman Chemical Company
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6255395
    Abstract: Masterbatch including at least about 65 wt % of resin having a R&B softening point as measured in accordance with ASTM 28-67. The masterbatch also includes a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin. A masterbatch pellet made by a method, including mixing a resin having a R&B softening point as measured in accordance with ASTM 28-67, and a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin, to form masterbatch composition including at least about 65 wt % of resin. The method of making the masterbatch pellet also includes pelletizing the masterbatch composition into masterbatch pellet. Methods of making a masterbatch, methods for making polymer product, and a polymer product.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: July 3, 2001
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6087446
    Abstract: Masterbatches comprising high density polyethylene (HDPE) are used for the production of polyolefin articles, particularly films. Employing HDPE in a masterbatch alone or in combination with a hydrocarbon resin and/or a polyolefin ultimately results in extruded polyolefin articles of optimal stiffness and ductility. Employing a high density polyethylene in combination with a hydrocarbon resin and a polyolefin in a masterbatch causes the masterbatch to solidify more rapidly and be pelletized more efficiently.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: July 11, 2000
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 5391670
    Abstract: The alkylation resins of this invention comprise the alkylation reaction product of (a) at least one substituted or unsubstituted polycyclic aromatic compound and (b) at least one ethylenically unsaturated hydrocarbon monomer having at least two carbon-carbon double bonds that reacts with the polycyclic aromatic compound by alkylation in the presence of an acid catalyst, wherein the ratio of (a) to (b) in the resin is about 1:9 to about 3:1 by weight. The resins have a weight average molecular weight of less than 10,000 measured by size exclusion chromatography, and a Ring & Ball softening point of about 50.degree. to about 250.degree. C. Because of their high softening point and low molecular weight, the resins are useful in a variety of applications such as flow rate modifiers for engineering polymers, tackifiers for adhesives, and flushing agents for inks.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: February 21, 1995
    Assignee: Hercules Incorporated
    Inventors: Atanu Biswas, Daniel W. Klosiewicz
  • Patent number: 5292590
    Abstract: An innerliner for tubeless tires is comprised of at least one barrier layer such as poly(vinylidene chloride) or ethylene--vinyl alcohol copolymer film with each barrier layer sandwiched between two layers of an elastomeric material adhering to the rubber stock employed in the carcass of the tire. The innerliner has the advantage of imparting equal or better air retention properties to the tire with a substantial reduction in the thickness and weight relative to conventional halobutyl rubber innerliners.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: March 8, 1994
    Assignee: Hercules Incorporated
    Inventors: Kuang F. Lin, Daniel W. Klosiewicz, Gregory I. Brodsky
  • Patent number: 5156921
    Abstract: An innerliner for tubeless tires is comprised of at least one non-elastomeric barrier layer such as poly(vinylidene chloride) or ethylene--vinyl alcohol copolymer film with each barrier layer sandwiched between two layers of an elastomeric material adhering to the rubber stock employed in the carcass of the tire. The innerliner has the advantage of imparting equal or better air retention properties to the tire with a substantial reduction in the thickness and weight relative to conventional halobutyl rubber innerliners.
    Type: Grant
    Filed: May 16, 1991
    Date of Patent: October 20, 1992
    Assignee: Hercules Incorporated
    Inventors: Kuang F. Lin, Daniel W. Klosiewicz
  • Patent number: 5040583
    Abstract: An innerliner for tubeless tires is comprised of at least one non-elastomeric barrier layer such as poly(vinylidene chloride) or ethylene--vinyl alcohol copolymer film with each barrier layer sandwiched between two layers of an elastomeric material adhering to the rubber stock employed in the carcass of the tire. The innerliner has the advantage of imparting equal or better air retention properties to the tire with a substantial reduction in the thickness and weight relative to conventional halobutyl rubber innerliners.
    Type: Grant
    Filed: March 13, 1990
    Date of Patent: August 20, 1991
    Assignee: Hercules Incorporated
    Inventors: Kuang F. Lin, Daniel W. Klosiewicz
  • Patent number: 4699963
    Abstract: A polymerization catalyst composition including ##STR1## wherein R is an alkyl group having 3 to 20 carbon atoms; m is 4 or 6 and n is 0 or 1. Preferably the composition also includes, ##STR2## wherein R.sub.1 and R.sub.2 are independently hydrogen, an alkyl or alkoxy group of from 1 to 5 carbons. Preferably r is 1; m is 4 and R is nonyl and the molar ratio of WCl.sub.m O.sub.n to ##STR3## is from about 1:1 to about 1:3.
    Type: Grant
    Filed: December 6, 1985
    Date of Patent: October 13, 1987
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 4664984
    Abstract: Disclosed are graft copolymers of polypropylene containing 3 to 100% by weight based on the weight of the polypropylene backbone, preferably 3 to 30%, of an alkyl methacrylate moiety. These are useful as adhesives for bonding polypropylene to chlorinated hydrocarbon polymers. Laminated structures of polypropylene and chlorinated hydrocarbon polymers, which make use of the aforesaid adhesives, are also disclosed.
    Type: Grant
    Filed: April 3, 1986
    Date of Patent: May 12, 1987
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 4657981
    Abstract: A composition comprising a polymer of dicyclopentadiene containig an elastomer.
    Type: Grant
    Filed: March 7, 1986
    Date of Patent: April 14, 1987
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 4595726
    Abstract: Disclosed are graft copolymers of polypropylene containing 3 to 100% by weight based on the weight of the polypropylene backbone, preferably 3 to 30%, of an alkyl methacrylate moiety. These are useful as adhesives for bonding polypropylene to chlorinate-hydrocarbon polymers.
    Type: Grant
    Filed: October 4, 1984
    Date of Patent: June 17, 1986
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 4568660
    Abstract: A polymerization catalyst composition including ##STR1## wherein R is an alkyl group having 3 to 20 carbon atoms; m is 4 or 6 and n is 0 or 1. Preferably the composition also includes, ##STR2## wherein R.sub.1 and R.sub.2 are independently hydrogen, an alkyl or alkoxy group of form 1 to 5 carbons. Preferably r is 1; m is 4 and R is nonyl and the molar ratio of WCl.sub.m O.sub.n to ##STR3## is from about 1:1 to about 1:3.
    Type: Grant
    Filed: November 16, 1984
    Date of Patent: February 4, 1986
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 4520181
    Abstract: A method of making a thermoset polydicyclopentadiene by first combining a plurality of reactant streams, one containing the activator of a metathesis-catalyst system, a second containing the catalyst of a metathesis-catalyst system and at least one containing dicylopentadiene; then immediately injecting this combination into a mold where polymerization results in the formation of a tough, rigid thermoset polymer with high modulus and excellent impact strength.
    Type: Grant
    Filed: March 7, 1983
    Date of Patent: May 28, 1985
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 4485208
    Abstract: Incorporation of an ester plasticizer having a solubility parameter from about 7.8 to about 10.2 (cal/cc).sup.1/2 increases the flexibility and impact strength of poly(dicyclopentadiene). In a preferred embodiment of the method for poly(dicyclopentadiene) synthesis, the plasticizer is incorporated into at least one of two parts of a metathesis-catalyst system: a catalyst/monomer solution or an activator/monomer solution. The two parts are then combined in the mixing head of a reaction injection molding machine and injected into a mold where the reaction mixture rapidly sets up into a thermoset polymer with greater flexibility and impact strength than is found in the corresponding unplasticized poly(dicyclopentadiene).
    Type: Grant
    Filed: November 15, 1983
    Date of Patent: November 27, 1984
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz