Patents by Inventor Daniela Mileva
Daniela Mileva has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11981781Abstract: The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-?-olefin plastomer having—a density of from 850 kg/m3 to 900 kg/m3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-?-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt. % with respect to the grafted ethylene-?-olefin plastomer; (c) contacting said grafted ethylene-?-olefin plastomer with 2 to 8 wt. % of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-?-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.Type: GrantFiled: September 26, 2019Date of Patent: May 14, 2024Assignee: Borealis AGInventors: Oscar Prieto, Jeroen Oderkerk, Jari-Jussi Ruskeeniemi, Stefan Hellström, Tanja Piel, Daniela Mileva
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Patent number: 11952482Abstract: A heterophasic polypropylene composition (C) comprising: a. 60.0 to 85.0 wt.-% of a first heterophasic propylene ethylene copolymer (HECO1), having: i. 75.0 to 92.0 wt.-% of a CRYSTEX QC crystalline fraction (CF); ii. 8.0 to 25.0 wt.-% of a CRYSTEX QC soluble fraction (SF); iii. an IV(SF) of 2.00 to 4.00 dl/g; b. 5.0 to 20.0 wt.-% of a second heterophasic propylene ethylene copolymer (HECO2), having i. 15.0 to 30.0 wt.-% of a CRYSTEX QC soluble fraction (SF); ii. an IV(SF) of 2.5 to 5.0 dl/g; and c. 5.0 to 20.0 wt.-% of a polymer of ethylene (PE), being selected from an ethylene-based plastomer and an LDPE, having a density in the range from 895 to 925 kg/m3; wherein the heterophasic polypropylene composition (C) has an MFR2 in the range from 15.0 to 40.0 g/10 min, and 5.0 to 23.0 wt.-% of a CRYSTEX QC soluble fraction (SF).Type: GrantFiled: July 8, 2021Date of Patent: April 9, 2024Assignee: BOREALIS AGInventors: Cornelia Tranninger, Daniela Mileva, Georg Grestenberger
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Patent number: 11945926Abstract: The present invention is directed to a polypropylene composition (C) a melt flow rate MFR2 (230° C.) determined according to ISO 1133 in the range of 15 to 40 g/10 min, the use of said polypropylene composition (C) for the production of a foamed article and a foamed article comprising said polypropylene composition (C).Type: GrantFiled: May 14, 2019Date of Patent: April 2, 2024Assignees: Abu Dhabi Polymers Co. Ltd (Borouge) LLC., Borealis AGInventors: Susanne Kahlen, Daniela Mileva, Georg Grestenberger, Andreas Fuchs, Stefanie Engleder, Jürgen Huber, Shengquan Zhu
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Patent number: 11845836Abstract: Articles comprising a polymer composition, wherein the polymer composition is obtainable by grafting an ethylene copolymer with comonomer units comprising hydrolysable silane groups, wherein the polymer composition shows high gel content and low compression set at ?25° C. These articles have applications in automotive weather-stripping, such as sealing systems for doors, trunks and hoods.Type: GrantFiled: September 30, 2019Date of Patent: December 19, 2023Assignee: BOREALIS AGInventors: Jari-Jussi Ruskeeniemi, Jeroen Oderkerk, Oscar Prieto, Stefan Hellström, Tanja Piel, Daniela Mileva, Floran Prades
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Publication number: 20230257563Abstract: A composition suitable for automotive application obtainable by blending at least components a) to f), or a), b), c), d), C and f) under the proviso that e) is not present a) 12 to 40 wt.-%, preferably 14 to 38 wt. %, more preferably 15 to 35 wt.-% of a first heterophasic polypropylene copolymer (HECO 1) b) 12 to 40 wt.-%, preferably 14 to 38 wt.-%, more preferably 15 to 35 wt.-% of a second heterophasic polypropylene copolymer (HECO 2) c) 15 to 65 wt.-%, preferably 18 to 60 wt.-%, more preferably 20 to 55 wt.-% of a polypropylene-polyethylene blend (A) d) 3.0 to 20 wt.-%, preferably 5.0 to 15 wt.-% and more preferably 6.0 to 15 wt.-% of an inorganic filler e) 0 to 15 wt.-% HDPE f) 0.01 to 4.0 wt.-% of additives.Type: ApplicationFiled: August 11, 2021Publication date: August 17, 2023Inventors: Susanne Kahlen, Angelica Legras, Hermann Braun, Michael Jerabek, Christophe Salles, Daniela Mileva
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Publication number: 20230257570Abstract: A heterophasic polypropylene composition (C) comprising: a. 60.0 to 85.0 wt.-% of a first heterophasic propylene ethylene copolymer (HECO1), having: i. 75.0 to 92.0 wt.-% of a CRYSTEX QC crystalline fraction (CF); ii. 8.0 to 25.0 wt.-% of a CRYSTEX QC soluble fraction (SF); iii. an IV(SF) of 2.00 to 4.00 dl/g; b. 5.0 to 20.0 wt.-% of a second heterophasic propylene ethylene copolymer (HECO2), having i. 15.0 to 30.0 wt.-% of a CRYSTEX QC soluble fraction (SF); ii. an IV(SF) of 2.5 to 5.0 dl/g; and c. 5.0 to 20.0 wt.-% of a polymer of ethylene (PE), being selected from an ethylene-based plastomer and an LDPE, having a density in the range from 895 to 925 kg/m3; wherein the heterophasic polypropylene composition (C) has an MFR2 in the range from 15.0 to 40.0 g/10 min, and 5.0 to 23.0 wt.-% of a CRYSTEX QC soluble fraction (SF).Type: ApplicationFiled: July 8, 2021Publication date: August 17, 2023Inventors: Cornelia Tranninger, Daniela Mileva, Georg Grestenberger
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Patent number: 11685840Abstract: The present invention provides a polyolefin composition, said composition comprising a terpolymer comprising a cross-linkable polyolefin comprising hydrolysable silane groups and a polar comonomer, the polyolefin composition further comprising a cross-linking catalyst and a silicon containing compound. The polar comonomer Is present in an amount of 5-35 wt %.Type: GrantFiled: October 11, 2018Date of Patent: June 27, 2023Assignee: BOREALIS AGInventors: Jeroen Oderkerk, Jari-Jussi Ruskeeniemi, Oscar Prieto, Stefan Hellström, Tanja Piel, Daniela Mileva
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Patent number: 11643537Abstract: The present invention relates to a polypropylene based composition comprising: (A) from 40.0 to 85.0 wt % of a heterophasic propylene copolymer having a content of xylene cold soluble (XCS) fraction in the range of 15 wt % to 35 wt %, based on the total weight of the heterophasic propylene copolymer; (B) from 5.0 to 15.0 wt % of a terpolymer of propylene with ethylene and 1-butene comonomer units having a melting temperature Tm as measured in differential scanning calorimetry (DSC) of less than 140° C.; (C) from 5.0 to 25.0 wt % of an ethylene copolymer with alpha-olefin comonomer units having from 4 to 12 carbon atoms with a density of from 850 kg/m3 to 900 kg/m3; and (D) from 5.0 to 25.0 wt % of an inorganic filler, wherein the amounts of components (A), (B), (C), and (D) are all based on the total weight amount of the polypropylene based composition, said polypropylene based composition having a melt flow rate (MFR2) as measured at 230° C. and 2.16 kg load in accordance with ISO 1133 in the range of 2.Type: GrantFiled: August 23, 2019Date of Patent: May 9, 2023Assignee: BOREALIS AGInventors: Jingbo Wang, Friedrich Berger, Daniela Mileva, Georg Grestenberger, Markus Gahleitner
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Publication number: 20220411618Abstract: A polypropylene composition (C) comprising: i) from 55.0 to 95.0 wt.-% of a heterophasic propylene copolymer (HECO), ii) from 5.0 to 45.0 wt. -% of a copolymer (CP), preferably a random copolymer, of propylene and at least one comonomer selected from the group of C4-C10 alpha-olefins that has been synthesized in the presence of a single-site catalyst, wherein the polypropylene composition (C) has a melt flow rate MFR2 of from 1.0 to 30.0 g/10 min, and wherein the polypropylene composition (C) has a Charpy Notched Impact Strength NIS of greater than or equal to 16.0 kJ/m2.Type: ApplicationFiled: November 9, 2020Publication date: December 29, 2022Inventors: Daniela Mileva, Jingbo Wang, Klaus Bernreitner, Markus Gahleitner
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Publication number: 20220325017Abstract: The present invention refers to a method for improving the storage stability and/or transport stability of polymer (A) comprising the following steps: a) providing polymer (A) selected from the group consisting of copolymers of ethylene and a C4C12 alpha olefin comonomer, copolymers of propylene and mixtures thereof containing additionally comonomer units comprising hydrolysable silane groups; b) providing a stabilizer (B) selected from the group consisting of sterically hindered phenols, alkyltri-alkoxysilanes, alkenyltrialkoxysilanes and mixtures thereof; c) mixing polymer (A) and stabilizer (B) to obtain a stabilized polymer composition (I); and d) transferring the stabilized polymer composition (I) obtained in step c) in a container comprising at least one barrier layer. In addition, the present invention relates to the use of stabilizer (B) for improving the storage stability and/or transport stability of polymer (A) stored and/or transported in a container having a barrier layer.Type: ApplicationFiled: September 2, 2020Publication date: October 13, 2022Inventors: Jari-Jussi RUSKEENIEMI, Jeroen ODERKERK, Juha HARTIKAINEN, Tanja PIEL, Daniela MILEVA, Oscar PRIETO, Stefan HELLSTROEM
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Publication number: 20220315716Abstract: The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-?-olefin plastomer having—a density of from 850 kg/m3 to 900 kg/m3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-?-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt.-% with respect to the grafted ethylene-?-olefin plastomer; (c) contacting said grafted ethylene-?-olefin plastomer with 2 to 8 wt.-% of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-?-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.Type: ApplicationFiled: September 26, 2019Publication date: October 6, 2022Applicant: BOREALIS AGInventors: Oscar PRIETO, Jeroen ODERKERK, Jari-Jussi RUSKEENIEMI, Stefan HELLSTRÖM, Tanja PIEL, Daniela MILEVA
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Publication number: 20220298341Abstract: The present invention is directed to articles comprising a heterophasic polypropylene composition. The articles exhibit a combination of high stiffness, good dimensional stability, low shrinkage and reduced warpage properties and fast cycle times. Such articles are suitable in the rigid packaging area. The articles comprise a polypropylene composition comprising a heterophasic propylene copolymer which comprises a) a matrix phase (A) comprising at least one propylene homopolymer and/or a propylene copolymer, and b) a disperse phase (B) comprising a propylene copolymer rubber dispersed in the matrix phase (A), wherein the propylene copolymer rubber of the disperse phase (B) has a comonomer content of 30 to 55 wt. %, wherein the weight ratio of the matrix phase (A) and the disperse phase (B) is from 20:80 to 80:20; and the polypropylene composition has (i) a melt flow rate MFR2 of 1 g/10 min to 500 g/10 min, determined according to ISO 1133 (230° C., 2.Type: ApplicationFiled: June 12, 2020Publication date: September 22, 2022Inventors: Friedrich Berger, Juliane Braun, Daniela Mileva, Anton Sageder, Claudia Kniesel
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Patent number: 11396593Abstract: The present invention relates to a polypropylene composition, an injection molded article comprising the polypropylene composition, a foamed article comprising the polypropylene composition as well as the use of a polypropylene homopolymer (H-PP1) for reducing the 5stiffness reduction factor of a foamed injection molded article by at least 40 as determined by the difference of the flexural modulus measured according to ISO 178 of the non-foamed and foamed injection molded article and compared to an article comprising the same amount of a polypropylene which has been polymerized in the presence of a Ziegler-Natta catalyst.Type: GrantFiled: October 2, 2019Date of Patent: July 26, 2022Assignee: BOREALIS AGInventors: Daniela Mileva, Susanne Kahlen, Patrick Rover, Georg Grestenberger, Jingbo Wang, Klaus Bernreitner, Markus Gahleitner
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Publication number: 20220227030Abstract: A process for producing a cap or closure comprising obtaining a polypropylene composition by sequential polymerization comprising the steps: A) polymerizing in a first reactor, preferably a slurry reactor, in the presence of a Ziegler-Natta catalyst monomers comprising propylene and optionally one or more comonomers selected from ethylene and C4-C10 alpha-olefins, to obtain a first propylene polymer fraction having a comonomer content in the range of 0.0 to 1.8 wt %, and a MFR2 in the range of from 12.0 to 40.0 g/10 min, as measured according to ISO 1133 at 230° C. under a load of 2.16 kg; B) polymerizing in a second reactor, preferably a first gas-phase reactor, monomers comprising propylene and one or more comonomers selected from ethylene and C4-C10 alpha-olefins, in the presence of the first propylene polymer fraction, to obtain a second propylene polymer fraction, wherein the polypropylene composition comprising said first and second propylene polymer fractions has an MFR2 in the range of from 12.Type: ApplicationFiled: April 28, 2020Publication date: July 21, 2022Inventors: Jingbo WANG, Markus GAHLEITNER, Elisabeth POTTER, Luc MONNISSEN, Meta CIGON, Daniela MILEVA
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Patent number: 11377543Abstract: The present invention is directed to a heterophasic polypropylene composition (HC) comprising a modified polypropylene composition (mPP), a process for preparing said heterophasic polypropylene composition (HC) and an article comprising said heterophasic polypropylene composition (HC). The present invention is further directed to the use of a composition comprising a peroxide (PO) and a crosslinking agent (CA) to reduce tigerskin of a polypropylene composition (PP).Type: GrantFiled: June 21, 2018Date of Patent: July 5, 2022Assignee: BOREALIS AGInventors: Thomas Lummerstorfer, Daniela Mileva, Georg Grestenberger
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Patent number: 11345804Abstract: The present invention is directed to the use of a polypropylene composition comprising at least one heterophasic polypropylene and a filler for the production of at least partially painted articles which show both a good paintability and a good surface appearance; and the painted articles produced therefrom. Further the invention is directed to a polypropylene composition showing improved surface appearance and paintability.Type: GrantFiled: January 30, 2018Date of Patent: May 31, 2022Assignee: Borealis AGInventors: Susanne Kahlen, Claudia Kniesel, Thomas Lummerstorfer, Daniela Mileva, Milorad Bogdanovic
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Patent number: 11332603Abstract: The present invention is directed to a polypropylene composition (C) comprising a heterophasic propylene copolymer (HECO1) having an intrinsic viscosity (IV) of the xylene soluble fraction (XCS) above 3.5 dl/g, an inorganic filler (F) and a nucleating agent (NU) being a dicarboxylic acid and/or a salt thereof. Further, the present invention is directed to the use of said polypropylene composition (C) for the production of a foamed article as well as a foamed article comprising said polypropylene composition (C). The present invention is also directed to the use of a nucleating agent (NU) being dicarboxylic acid and/or a salt thereof for the reduction of tigerskin of a polypropylene composition.Type: GrantFiled: June 26, 2018Date of Patent: May 17, 2022Assignee: BOREALIS AGInventors: Daniela Mileva, Susanne Kahlen, Georg Grestenberger, Anton Sageder, Christof Wurnitsch, Anna Hartl, Patrick Rover, Erwin Pirklbauer
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Patent number: 11299617Abstract: The present invention relates to silane crosslinking catalyst comprising: —75 to 85 wt.-% of an olefin acrylate interpolymer and—15 to 25 wt.-% of a hindered amine light stabilizer (HALS) having a number average molecular weight Mn of 1500 to 4000 g/mol; and—optionally up to 5 wt.-% wax, wherein the silane crosslinking catalyst is free of tin, carboxylic acid(s) and sulphonic acid(s), all weight percentages with respect to the total weight of the silane crosslinking catalyst.Type: GrantFiled: September 26, 2019Date of Patent: April 12, 2022Assignee: Borealis AGInventors: Oscar Prieto, Jeroen Oderkerk, Jari-Jussi Ruskeeniemi, Stefan Hellström, Tanja Piel, Daniela Mileva
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Publication number: 20220033588Abstract: Articles comprising a polymer composition, wherein the polymer composition is obtainable by grafting an ethylene copolymer with comonomer units comprising hydrolysable silane groups, wherein the polymer composition shows high gel content and low compression set at ?25° C. These articles have applications in automotive weather-stripping, such as sealing systems for doors, trunks and hoods.Type: ApplicationFiled: September 30, 2019Publication date: February 3, 2022Inventors: Jari-Jussi Ruskeeniemi, Jeroen Oderkerk, Oscar Prieto, Stefan Hellström, Tanja Piel, Daniela Mileva, Floran Prades
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Publication number: 20210363319Abstract: The present invention is directed to a foamable polyolefin composition which is crosslinkable by silane groups, to a crosslinked foam obtained from such a foamable polyolefin composition, and to a process for producing a crosslinked foam based on the foamable polyolefin composition. The foamable polyolefin composition comprises a polyethylene bearing hydrolysable silane groups and comonomer units comprising a polar group selected from the group consisting of acrylic acid, methacrylic acid, acrylates, methacrylates, vinyl esters, and mixtures thereof, a silanol condensation catalyst, a physical blowing agent, and a cell nucleating agent.Type: ApplicationFiled: November 5, 2019Publication date: November 25, 2021Inventors: Tanja Piel, Antti Tynys, Stefan Hellström, Jeroen Oderkerk, Oscar Prieto, Jari-Jussi Ruskeeniemi, Daniela Mileva, Johan Defoer