Abstract: Some variations provide a permanent-magnet structure comprising: a region having a plurality of magnetic domains and a region-average magnetic axis, wherein each of the magnetic domains has a domain magnetic axis that is substantially aligned with the region-average magnetic axis, and wherein the plurality of magnetic domains is characterized by an average magnetic domain size. Within the region, there is a plurality of metal-containing grains characterized by an average grain size, and each of the magnetic domains has a domain easy axis that is dictated by a crystallographic texture of the metal-containing grains. The region has a region-average easy axis based on the average value of the domain easy axis within that region. The region-average magnetic axis and the region-average easy axis form a region-average alignment angle that has a standard deviation less than 30° within the plurality of magnetic domains. Many permanent-magnet structures are disclosed herein.

Abstract: Some variations provide a permanent-magnet structure comprising: a region having a plurality of magnetic domains and a region-average magnetic axis, wherein each of the magnetic domains has a domain magnetic axis that is substantially aligned with the region-average magnetic axis, and wherein the plurality of magnetic domains is characterized by an average magnetic domain size. Within the region, there is a plurality of metal-containing grains characterized by an average grain size, and each of the magnetic domains has a domain easy axis that is dictated by a crystallographic texture of the metal-containing grains. The region has a region-average easy axis based on the average value of the domain easy axis within that region. The region-average magnetic axis and the region-average easy axis form a region-average alignment angle that has a standard deviation less than 30° within the plurality of magnetic domains. Many permanent-magnet structures are disclosed herein.

Abstract: Some variations provide a method of tailoring the surface of a soft magnet, comprising: depositing an austenite-phase-stabilizing donor material on one or more first surface regions of a ferromagnetic receiver material; not depositing the austenite-phase-stabilizing donor material on one or more second surface regions of the ferromagnetic receiver material; laser melting the austenite-phase-stabilizing donor material into the first surface regions; and solidifying the molten austenite-phase-stabilizing donor material within the first surface regions, thereby selectively alloying the ferromagnetic receiver material in the first surface regions. Laser ablation may be utilized instead of laser melting. The first surface regions have a significantly higher magnetic permeability, following the selective alloying of the donor material, compared to the second surface regions. Soft magnets with surface-tailored magnetic permeability are provided by this technology, which is demonstrated using several examples.

Abstract: This invention provides methods for fabricating a hard or soft magnet with tailorable magnetic and crystallographic orientations. Methods are disclosed to individually tailor three-dimensional voxels for selected crystallographic orientations and, independently, selected magnetic orientations with location specificity throughout a magnet.

Abstract: The disclosed technology provides a cladded permanent magnet comprising: a core magnet region containing a core magnetic material; and a magnet cladding containing a shell magnetic material comprising (i) a magnetic compound that is chemically the same as the core magnetic material, (ii) one or more rare earth elements, and (iii) metal-containing inoculant nanoparticles, wherein the magnet cladding is disposed on the core magnet region, wherein the magnet cladding has at least 10% higher ambient-temperature magnetic coercivity compared to the core magnet region. The cladded permanent magnet is made via high-throughput laser-based additive manufacturing to optimize the architecture of NdFeB or other magnets, generating site-specific, demagnetization-resistant microstructures. This disclosure teaches a rapid, single-step laser-based process to tailor the easy axis alignment, grain size, and microstructure of a permanent magnet at corners and edges to resist demagnetization.

Abstract: The disclosed technology provides a nanofunctionalized magnetic material feedstock comprising: from 50 wt % to 99.5 wt % of magnetic microparticles having an average microparticle effective diameter from 1 micron to 500 microns; from 0.4 wt % to 40 wt % of one or more rare earth elements; and from 0.1 wt % to 10 wt % of metal-containing inoculant nanoparticles, wherein at least 1 wt % of the inoculant nanoparticles are chemically and/or physically disposed on surfaces of the magnetic microparticles. The nanofunctionalized magnetic material feedstock is processed using high-throughput laser-based additive manufacturing to optimize the architecture of NdFeB or other magnets, generating site-specific, demagnetization-resistant microstructures. This disclosure teaches a rapid, single-step laser-based process to tailor the easy axis alignment, grain size, and microstructure of a permanent magnet at corners and edges to resist demagnetization.

Abstract: This invention provides methods for fabricating a hard or soft magnet with tailorable magnetic and crystallographic orientations. Methods are disclosed to individually tailor three-dimensional voxels for selected crystallographic orientations and, independently, selected magnetic orientations with location specificity throughout a magnet.

Abstract: The present disclosure provides a methodology in which nanoparticle-coated microparticles are rapidly quality-checked for verification of surface functionalization of a commercial quantities of hierarchical powder. Some variations provide a method for inspecting surface-functionalized microparticles, comprising: selecting samples of hierarchical powders comprising microparticles and surface-coated nanoparticles; subjecting the hierarchical powders to a sample particle-size measurement; comparing the sample particle-size measurement to a baseline measurement; and determining the relative concentration of free nanoparticles, based on particle-size distributions. If the sample particle-size measurement is statistically equivalent to the baseline measurement, that is verification of complete surface functionalization.

Abstract: Some variations provide an aluminum (Al) alloy containing at least 0.1 at % zirconium (Zr) and/or at least 0.1 at % chromium (Cr), wherein the aluminum alloy is in the form of an additively manufactured object. Other variations provide an aluminum-containing powder comprising Al particles, Cr particles, and Zr particles, wherein at least some of the Cr particles as well as at least some of the Zr particles are physically and/or chemically assembled on surfaces of the Al particles, and wherein the aluminum-containing powder contains at least 0.1 at % Zr and at least 0.1 at % Cr. In this invention, the combination of surface functionalization and additive manufacturing has fundamentally created a new composition space of valuable aluminum alloys. The disclosed Al alloys are strong, thermally stable, and corrosion-resistant.

Abstract: This invention provides methods for fabricating a hard or soft magnet with tailorable magnetic and crystallographic orientations. Methods are disclosed to individually tailor three-dimensional voxels for selected crystallographic orientations and, independently, selected magnetic orientations with location specificity throughout a magnet.

Abstract: Some variations provide a permanent-magnet structure comprising: a region having a plurality of magnetic domains and a region-average magnetic axis, wherein each of the magnetic domains has a domain magnetic axis that is substantially aligned with the region-average magnetic axis, and wherein the plurality of magnetic domains is characterized by an average magnetic domain size. Within the region, there is a plurality of metal-containing grains characterized by an average grain size, and each of the magnetic domains has a domain easy axis that is dictated by a crystallographic texture of the metal-containing grains. The region has a region-average easy axis based on the average value of the domain easy axis within that region. The region-average magnetic axis and the region-average easy axis form a region-average alignment angle that has a standard deviation less than 30° within the plurality of magnetic domains. Many permanent-magnet structures are disclosed herein.

Abstract: Some variations provide an aluminum (Al) alloy containing at least 0.1 at % zirconium (Zr) and/or at least 0.1 at % chromium (Cr), wherein the aluminum alloy is in the form of an additively manufactured object. Other variations provide an aluminum-containing powder comprising Al particles, Cr particles, and Zr particles, wherein at least some of the Cr particles as well as at least some of the Zr particles are physically and/or chemically assembled on surfaces of the Al particles, and wherein the aluminum-containing powder contains at least 0.1 at % Zr and at least 0.1 at % Cr. In this invention, the combination of surface functionalization and additive manufacturing has fundamentally created a new composition space of valuable aluminum alloys. The disclosed Al alloys are strong, thermally stable, and corrosion-resistant.