Patents by Inventor Darryl P. Klein

Darryl P. Klein has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10569254
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (?); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (?) to less than about 1000 ?; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 ?; and (d) a pore mode equal to or greater than about 90 ? and less than about 160 ?. Preferably the support exhibits a d50 greater than about 100 ? and less than about 150 ?.
    Type: Grant
    Filed: March 1, 2017
    Date of Patent: February 25, 2020
    Assignee: Advanced Refining Technologies LLC
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Publication number: 20170165639
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (?); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (?) to less than about 1000 ?; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 ?; and (d) a pore mode equal to or greater than about 90 ? and less than about 160 ?. Preferably the support exhibits a d50 greater than about 100 ? and less than about 150 ?.
    Type: Application
    Filed: March 1, 2017
    Publication date: June 15, 2017
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Patent number: 9605216
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (?); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (?) to less than about 1000 ?; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 ?; and (d) a pore mode equal to or greater than about 90 ? and less than about 160 ?. Preferably the support exhibits a d50 greater than about 100 ? and less than about 150 ?.
    Type: Grant
    Filed: March 2, 2015
    Date of Patent: March 28, 2017
    Assignee: Advanced Refining Technologies LLC
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Publication number: 20150166905
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (?); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (?) to less than about 1000 ?; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 ?; and (d) a pore mode equal to or greater than about 90 ? and less than about 160 ?. Preferably the support exhibits a d50 greater than about 100 ? and less than about 150 ?.
    Type: Application
    Filed: March 2, 2015
    Publication date: June 18, 2015
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Patent number: 8969242
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: March 3, 2015
    Assignee: Advanced Refining Technologies LLC
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Publication number: 20140174983
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.
    Type: Application
    Filed: August 3, 2012
    Publication date: June 26, 2014
    Applicant: ADVANCED REFINING TECHNOLOGIES LLC
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Patent number: 8021538
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Grant
    Filed: April 16, 2008
    Date of Patent: September 20, 2011
    Assignee: Advanced Refining Technologies LLC
    Inventor: Darryl P. Klein
  • Patent number: 7642212
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at a low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Grant
    Filed: April 16, 2008
    Date of Patent: January 5, 2010
    Assignee: Advanced Refining Technologies LLC
    Inventor: Darryl P. Klein
  • Patent number: 7560407
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Grant
    Filed: April 16, 2008
    Date of Patent: July 14, 2009
    Assignee: Advanced Refining Technologies, LLC
    Inventor: Darryl P. Klein
  • Publication number: 20080207435
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Application
    Filed: April 16, 2008
    Publication date: August 28, 2008
    Applicant: Advanced Refining Technologies LLC
    Inventor: Darryl P. Klein
  • Publication number: 20080200330
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Application
    Filed: April 16, 2008
    Publication date: August 21, 2008
    Applicant: Advanced Refining Technologies LLC
    Inventor: Darryl P. Klein
  • Publication number: 20080190812
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Application
    Filed: April 16, 2008
    Publication date: August 14, 2008
    Applicant: Advanced Refining Technologies LLC
    Inventor: Darryl P. Klein
  • Patent number: 7390766
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Grant
    Filed: November 20, 2003
    Date of Patent: June 24, 2008
    Inventor: Darryl P. Klein
  • Patent number: 6837989
    Abstract: The invention relates to a process for converting cycle oils produced in catalytic cracking reactions into olefin and naphtha. More particularly, the invention relates to a process for hydroprocessing a catalytically cracked light cycle oil, and then re-cracking it in an upstream zone of the primary FCC riser reactor.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: January 4, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gordon F. Stuntz, George A. Swan, III, William E. Winter, Michel Daage, Michele S. Touvelle, Darryl P. Klein
  • Patent number: 6811682
    Abstract: The invention relates to a process for converting cycle oils produced in catalytic cracking reactions into light olefin and naphtha. More particularly, the invention relates to a process for hydroprocessing a catalytically cracked light cycle oil in order to form a hydroprocessed cycle oil containing a significant amount of tetralins. The hydroprocessed cycle oil is then re-cracked in an upstream zone of the primary FCC riser reactor.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: November 2, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gordon F. Stuntz, George A. Swan, III, William E. Winter, Michel Daage, Michele S. Touvelle, Darryl P. Klein
  • Patent number: 6723230
    Abstract: A process to regenerate iron-based hydrogen sulfide sorbents using steam. The steam is preferably mixed with hydrogen-containing gas and/or an inert gas, such as nitrogen. In a preferred embodiment, the sorbent is first exposed to the steam and then exposed to a hydrogen-containing gas at regeneration conditions.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: April 20, 2004
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Jingguang G. Chen, Leo D. Brown, William C. Baird, Jr., Gary B. McVicker, Edward S. Ellis, Michele S. Touvelle, Darryl P. Klein, David E. W. Vaughan
  • Patent number: 6683020
    Abstract: Disclosed is a process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The ring opening is accomplished using a ring opening catalyst comprising Ir on a composite support of alumina and acidic silica-alumina molecular sieve. The ring opening activity is not significantly deactivated by exposure to oxygen at greater than about 250° C.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: January 27, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: William C. Baird, Jr., Darryl P. Klein, Jingguang G. Chen, Gary B. McVicker
  • Patent number: 6652737
    Abstract: Disclosed is a method for treating naphtha. The method comprises providing naphtha feed, and the naphtha feed comprises naphthene ring-containing compounds. The naphtha feed is contacted with a ring opening catalyst containing a Group VIII metal under conditions effective to ring open the naphthene rings to form a ring opened product. The ring open product can then be contacted with a catalytic cracking catalyst under effective cracking conditions to form an olefin product. The olefin product will be particularly high in ethylene and propylene content.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: November 25, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Michele S. Touvelle, Darryl P. Klein, Tan-Jen Chen, Luc R. Martens, Edward S. Ellis
  • Patent number: 6649043
    Abstract: A process to regenerate metal oxide desulfurization sorbents using an oxidizing and reducing atmosphere. The sorbents may be mono- or multi-metallic in nature, and preferably comprise Cu, Ni and/or Co. If desired, secondary metals may be incorporated to increase regeneration efficiency and/or capacity. Other additives may be used to suppress hydrocarbon cracking. A sorbent containing Zn may be combined with an Fe, Co, Ni, Mo, or W catalyst or a noble metal catalyst and combinations thereof.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: November 18, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jingguang G. Chen, Leo D. Brown, William C. Baird, Jr., Gary B. McVicker, Edward S. Ellis, Michele S. Touvelle, Darryl P. Klein, David E. W. Vaughan
  • Publication number: 20030178343
    Abstract: A process to regenerate a spent hydrogen sulfide sorbent comprised of a sorbent metal selected from Fe, Ni, Co, and Cu on a refractory oxide support using hydrogen gas. The sorbent metal component may be mono- or multi-metallic in nature, and preferably comprise Ni and/or Co. If desired, secondary metals may be incorporated to increase regeneration efficiency and/or capacity. Other additives suppress hydrocarbon cracking.
    Type: Application
    Filed: January 6, 2003
    Publication date: September 25, 2003
    Inventors: Jingguang G. Chen, Leo D. Brown, William C. Baird, Gary B. McVicker, Edward S. Ellis, Michele S. Touvelle, Darryl P. Klein, David E. W. Vaughan