Abstract: Films including solvent barriers and primer layers are described. In particular, films including a substrate, the substrate including polylactic acid, a primer layer disposed on the substrate, a barrier layer disposed on the surface of the primer layer opposite the substrate, and an adhesive layer disposed on a surface of the barrier layer opposite the primer layer. The barrier layer includes an amorphous aliphatic polyamide with a glass transition temperature of at least 40 #C. Such films can provide acceptable adhesion and barrier performance to polylactic acid based graphics film systems.

Abstract: Conformable, stretchable, printable films are described. In particular, films that include a film substrate, a pressure sensitive adhesive, and a hybrid solvent barrier/primer layer including a blend of two copolyamides that are not miscible are described. Such hybrid solvent barrier and primer layers may be effective as both a solvent barrier and a primer layer.

Abstract: Disclosed are various fluoropolymer blend combinations and multilayer articles comprising a blend in a first layer and a second layer comprising a polymer bonded to the first layer. The invention also provides an article comprising a first layer comprising a blend of two or more fluoropolymers, and a second layer bonded to the first layer, the second layer comprising a partially-fluorinated thermoplastic polymer, a perfluorinated thermoplastic polymer, or a combination thereof. The invention also provides an article comprising a first layer comprising a blend of two or more fluoropolymers, at least one of which comprises a partially-fluorinated thermoplastic polymer, and optionally at least one perhalogenated polymer, and a second layer bonded to the first layer, the second layer comprising an at least partially-fluorinated thermoplastic polymer. The invention also provides processes for preparing blended fluoropolymers and multilayer articles comprising a fluoropolymer layer.

Abstract: Disclosed are various fluoropolymer blend combinations and multilayer articles comprising a blend in a first layer and a second layer comprising a polymer bonded to the first layer. The invention also provides an article comprising a first layer comprising a blend of two or more fluoropolymers, and a second layer bonded to the first layer, the second layer comprising a partially-fluorinated thermoplastic polymer, a perfluorinated thermoplastic polymer, or a combination thereof. The invention also provides an article comprising a first layer comprising a blend of two or more fluoropolymers, at least one of which comprises a partially-fluorinated thermoplastic polymer, and optionally at least one perhalogenated polymer, and a second layer bonded to the first layer, the second layer comprising an at least partially-fluorinated thermoplastic polymer. The invention also provides processes for preparing blended fluoropolymers and multilayer articles comprising a fluoropolymer layer.

Abstract: An article comprising a first layer consisting essentially of a substantially solid perhalogenated polymer, a second layer consisting essentially of a substantially solid partially-fluorinated polymer, and a bonding interface between said first layer and said second layer consisting essentially of a first material having the composition of said first layer and a second material having the composition of said second layer. Also provided is a sheet comprising a first layer comprising a perhalogenated polymer, a second layer comprising a partially-fluorinated polymer, and a bonding interface between said first layer and said second layer consisting essentially of a first material having the composition of said first layer and a second material having the composition of said second layer. The layers may also include adjuvants.