Abstract: A method of making a lithium alkylsiliconate composition comprising adding an alkylalkoxysilane to a first mixture comprising lithium hydroxide and water to form a second mixture comprising a lithium alkylsiliconate and an alcohol, wherein i) the mole ratio of lithium hydroxide to alkylalkoxysilane is from 0.9 to less than 1.1 and the water is from 89 to 93 mol %, or ii) the mole ratio of lithium hydroxide to alkylalkoxysilane is from 1.1 to 1.4 and the water is from greater than 93 to 99 mole %.

Abstract: A method of making a lithium alkylsiliconate composition comprising adding an alkylalkoxysilane to a first mixture comprising lithium hydroxide and water to form a second mixture comprising a lithium alkylsiliconate and an alcohol, wherein i) the mole ratio of lithium hydroxide to alkylalkoxysilane is from 0.9 to less than 1.1 and the water is from 89 to 93 mol %, or ii) the mole ratio of lithium hydroxide to alkylalkoxysilane is from 1.1 to 1.4 and the water is from greater than 93 to 99 mole %.

Abstract: An aqueous emulsion for waterproofing a surface comprising: a) 1 to 85% by weight of an alkylalkoxysilane of the formula R1aSi(OR2)4?a b) 0.1 to 10% by weight of a cationic alkoxysilane of the formula R3bR4Si(OR5)3?b c) up to 20% by weight of a hydroxy terminated polydimethylsiloxane having a degree of polymerization from 1 to 500, said hydroxy terminated polydimethylsiloxane being present in the aqueous emulsion where; R1 is an alkyl group containing 1 to 30 carbon atoms, R2 and R5 are independently selected from the group consisting of hydrogen, alkyl groups containing 1 to 4 carbon atoms, CH3C(O)—, CH3CH2C(O)—, HOCH2CH2—, CH3OCH2CH2—, and C2H5OCH2CH2—, R3 is an alkyl group containing 1 to 4 carbons, R4 is a monovalent hydrocarbon having at least one quaternary ammonium group substituent, a is 1 or 2, b is 0, 1 or 2.

Abstract: Aqueous silicone emulsions are disclosed containing a phenyl silsesquioxane resin, an alkoxysilane, a hydroxy terminated polydialkylsiloxane, and an emulsion of an aminofunctional polysiloxane. The silicone emulsions are useful for imparting water repellency to various surfaces, and in particular, inorganic building surfaces.

Abstract: Aqueous emulsions of certain alkylalkoxysilanes and cationic alkoxysilanes provide water proofing properties to a variety of substances, and in particular to masonry or concrete surfaces.

Abstract: Aqueous silicone emulsions are disclosed containing a phenyl silsesquioxane resin, an alkoxysilane, a hydroxy terminated polydialkylsiloxane, and an emulsion of an aminofunctional polysiloxane. The silicone emulsions are useful for imparting water repellency to various surfaces, and in particular, inorganic building surfaces.

Abstract: A method of improving the release and antideposition characteristics of a hard impermeable surface. A hard impermeable surface is coated with a film of an aqueous solution. The solution is formed by combining (i) a dimer of at least two alkoxy functional silanes, (ii) an aqueous silicone emulsion of a polydiorganosiloxane, and (iii) water. The film is allowed to dry on the hard impermeable surface or the film can be wiped to dryness. The solution may also contain a water soluble hydrophilic solvent such as propylene glycol.

Abstract: A method of improving the release and antideposition characteristics of a hard impermeable surface. A hard impermeable surface is coated with a film of an aqueous solution. The solution is formed by combining (i) a dimer of at least two alkoxy functional silanes, (ii) an aqueous silicone emulsion of a polydiorganosiloxane, and (iii) water. The film is allowed to dry on the hard impermeable surface or the film can be wiped to dryness. The solution may also contain a water soluble hydrophilic solvent such as propylene glycol.

Abstract: A composition is formed by combining water with an organic polymer such as polybutylene or an alkyd resin, and an alkoxysilane of the formula R.sub.n Si(OR').sub.4-n where R is an alkyl radical of 1-10 carbon atoms, an alkenyl radical having 2-8 carbon atoms, phenyl, chloropropyl, or trifluoropropyl, n is 1 or 2, and R' is an alkyl radical having 1-6 carbon atoms. The composition is free of amine or quaternary ammonium functional silanes. It can be emulsified and used to treat a cellulosic or masonry surface to render it water repellent.