Abstract: Method for manufacturing an auxiliary device suitable for the manufacture of a patient customized implant comprising the steps of: 1) obtaining 3D image data, preferably a CT of a defect site of a patient's anatomy (1); 2) generating a computer model of the defect site based on the 3D image data and 3D generic reference data by using image processing techniques; 3) virtually reconstructing the defect site; 4) generating a computer template (30) which represents an auxiliary device (40) that is suitable for sizing, shaping and positioning of alloplastic implants; and 5) manufacturing an auxiliary device (40) using 3D printing. Furthermore, there is provided a method for manufacturing a patient customized implant using the auxiliary device and a method for the reconstruction of a particular anatomy by using the manufactured patient customized implant.

Abstract: Method for manufacturing an auxiliary device suitable for the manufacture of a patient customized implant comprising the steps of: 1) obtaining 3D image data, preferably a CT of a defect site of a patient's anatomy (1); 2) generating a computer model of the defect site based on the 3D image data and 3D generic reference data by using image processing techniques; 3) virtually reconstructing the defect site; 4) generating a computer template (30) which represents an auxiliary device (40) that is suitable for sizing, shaping and positioning of alloplastic implants; and 5) manufacturing an auxiliary device (40) using 3D printing. Furthermore, there is provided a method for manufacturing a patient customized implant using the auxiliary device and a method for the reconstruction of a particular anatomy by using the manufactured patient customized implant.

Abstract: Siloxanes are polymerized by equilibration, condensation and/or ring-opening polymerization using a phosphazene base catalyst. A linear phosphazene base catalyst of the general formula wherein R denotes a C1-10 hydrocarbon or wherein two R groups on one N atom form with the N atom a heterocyclic group, X denotes an anion and n is from 1 to 10 is prepared by reacting a linear phosphonitrile halide compound with a secondary amine or a salt of a secondary amine or a metal amide thereof to form an aminated phosphazene material, followed by an ion exchange reaction replacing the anion with a nucleophile.

Abstract: Phosphonitrile halides are prepared employing the use of disilazanes. The resultant products may be further reacted with cyclosiloxanes to form siloxane containing phosphonitrile halides.