Abstract: A method for grinding a solid in a vertical roller mill (VRM), comprising grinding at least one solid in the presence of a grinding stabilizing additive, wherein the grinding stabilizing additive comprises an alkanol amino acid compound or a disodium or dipotassium salt thereof having the structural formula (I): The definitions of variables R1, R2, and R3 are provided herein.

Abstract: The present invention provides a method and system for manufacturing cement wherein ground particles of cement and calcium sulfate are subjected to infrared sensors, laser sensors, or both, so that emanated, irradiated, transmitted, and/or absorbed energy having wavelengths principally within the range of 700 nanometers to 1 millimeter can be monitored and compared to stored data previously obtained from ground cement and sulfate particles and preferably correlated with stored strength, calorimetric, or other data values, such that adjustments can be made to the mill processing conditions, such as the form or amounts of calcium sulfate (e.g., gypsum, plaster, anhydride), or cement additive levels. The strength and other properties of cement can be thus adjusted, and its quality can be more uniform.

Abstract: The present invention provides a method and system for manufacturing cement wherein ground particles of cement and calcium sulfate are subjected to infrared sensors, laser sensors, or both, so that emanated, irradiated, transmitted, and/or absorbed energy having wavelengths principally within the range of 700 nanometers to 1 millimeter can be monitored and compared to stored data previously obtained from ground cement and sulfate particles and preferably correlated with stored strength, calorimetric, or other data values, such that adjustments can be made to the mill processing conditions, such as the form or amounts of calcium sulfate (e.g., gypsum, plaster, anhydride), or cement additive levels. The strength and other properties of cement can be thus adjusted, and its quality can be more uniform.

Abstract: Method for grinding a solid in a vertical roller mill (VRM) and a cement composition prepared by the disclosed methods. A method comprises grinding a solid comprising a cement clinker under a water spray in the presence of a grinding stabilizing additive, wherein the grinding stabilizing additive comprises: (i) an alkanol amino acid compound or a disodium or dipotassium salt thereof having the structural formula: (I), (ii) a glycol; or a mixture of (i) and (ii), wherein the water spray level is reduced by at least 5% compared to a control. Cement compositions prepared by the disclosed methods have the pre-hydration level (Wk) equal to or less than 1.5%. The values and preferred values of R1-3 are disclosed herein.

Abstract: The present invention provides a method and system for manufacturing cement wherein ground particles of cement and calcium sulfate are subjected to infrared sensors, laser sensors, or both, so that emanated, irradiated, transmitted, and/or absorbed energy having wavelengths principally within the range of 700 nanometers to 1 millimeter can be monitored and compared to stored data previously obtained from ground cement and sulfate particles and preferably correlated with stored strength, calorimetric, or other data values, such that adjustments can be made to the mill processing conditions, such as the form or amounts of calcium sulfate (e.g., gypsum, plaster, anhydride), or cement additive levels. The strength and other properties of cement can be thus adjusted, and its quality can be more uniform.

Abstract: This invention relates to apparatus and method for measurement and monitoring of physical properties of materials, such as liquids, and more particularly to acoustic instruments, methods, and systems that automatically measure air content in real-time within liquids, including concrete, mortar, or other hydratable cementitious mix suspensions using resonant electroacoustic transducers that have their radiating surfaces in contact with the liquid.

Abstract: A method of making a cement composition, comprising grinding a cement clinker and a strength-enhancing agent, thereby producing a hydraulic cementitious powder, wherein the strength-enhancing agent is present in the hydraulic cementitious powder in an amount of from 0.001% to 0.09% based on dry weight of the hydraulic cementitious powder. The strength-enhancing agent is a compound represented by the following structural formula (I). The definitions of variables R1, R2, and R3 as well as R10, R20, and R30 are provided herein.

Abstract: A method for grinding a solid in a vertical roller mill (VRM), comprising grinding at least one solid in the presence of a grinding stabilizing additive, wherein the grinding stabilizing additive comprises an alkanol amino acid compound or a disodium or dipotassium salt thereof having the structural formula (I): The definitions of variables R1, R2, and R3 are provided herein.

Abstract: A cementing method includes positioning a bottom plug at a casing shoe, rupturing the bottom plug, signaling when a top plug reaches a target position, and releasing a chemical into a cement slurry below the top plug in response to the signaling. The signal may comprise a mechanical trigger changing its position due to movement of the top plug past the target position.

Abstract: A cementing method includes positioning a bottom plug at a casing shoe, rupturing the bottom plug, signaling when a top plug reaches a target position, and releasing a chemical into a cement slurry below the top plug in response to the signaling. The signaling or releasing involves an electronic signaling interface included with the bottom plug and/or the top plug. A cementing system includes a top plug position interface that identifies when a top plug reaches a target position relative to a bottom plug and a chemical release interface that releases a chemical into a cement slurry below the top plug. The top plug position interface or the chemical release interface include an electronic signaling interface integrated with at least one of the top plug and a bottom plug.

Abstract: Sealant compositions comprising: a wellbore treatment fluid; a set modifier; and, a polymeric component that inhibits release of the set modifier; wherein exposure to ionizing radiation causes degradation of the polymeric component resulting in release of the set modifier and an increase in the mechanical strength of the sealant composition.

Abstract: The present disclosure provides sensing systems and methods that are useful for monitoring materials (e.g., cement) via light diffusion to identify characteristics thereof and changes therein. The systems can utilize a light source, a light sensor, and light transmitting members combined with the material to be monitored. In use, light from the light source can be allowed to scatter through the material via the light transmitting members for detection by the light sensor. The data regarding the light transfer can be transmitted utilizing a communication interface and can be analyzed using data processing equipment. The systems and methods may particularly be utilized in monitoring the reinforcing cement positioned between the casing and the formation in an oil well.

Abstract: Sealant compositions comprising: a wellbore treatment fluid; a set modifier; and, a polymeric component that inhibits release of the set modifier; wherein exposure to ionizing radiation causes degradation of the polymeric component resulting in release of the set modifier and an increase in the mechanical strength of the sealant composition.

Abstract: The present invention includes methods relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore by preparing a sealant composition comprising a fluid component and a polymeric additive component, placing the sealant composition into a wellbore and subjecting the sealant composition to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive components and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition.

Abstract: The present invention includes methods and compositions relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore includes preparing a sealant composition having a fluid component, a polymeric additive constituent, and a set modifier component. The sealant composition is placed into a wellbore and subjected to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive constituents and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition. The ionizing radiation also alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: The present invention relates to methods useful for isolating a portion of a wellbore. In one embodiment, a method includes preparing a sealant composition containing a set modifier component. The sealant composition is placed into the wellbore and is subjected to ionizing radiation that alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: A TSV structure suitable for high speed signal transmission includes a metal strip portion that extends through a long and small diameter hole in a substrate. In one example, the metal strip portion is formed by laser ablating away portions of a metal sheath that lines a cylindrical sidewall of the hole, thereby leaving a longitudinal section of metal that is the metal strip portion. A second metal strip portion, that extends in a direction perpendicular to the hole axis, is contiguous with the metal strip portion that extends through the hole such that the two metal strip portions together form a single metal strip. Throughout its length, the single metal strip has a uniform width and thickness and therefore can have a controlled and uniform impedance. In some embodiments, multiple metal strips pass through the same TSV hole. In some embodiments, the structure is a coaxial TSV.

Abstract: Methods of isolating a portion of a wellbore comprising placing a sealant composition into a subterranean formation after drilling of the wellbore therein and subjecting the sealant composition to ionizing radiation wherein subjecting the sealant composition to the ionizing radiation alters the set modifier. The sealant composition comprises a set modifier selected from the group consisting of an accelerator, an oxidizing agent, a set retarder, and combinations thereof. And the sealant composition comprises a polymeric component.

Abstract: A TSV structure suitable for high speed signal transmission includes a metal strip portion that extends through a long and small diameter hole in a substrate. In one example, the metal strip portion is formed by laser ablating away portions of a metal sheath that lines a cylindrical sidewall of the hole, thereby leaving a longitudinal section of metal that is the metal strip portion. A second metal strip portion, that extends in a direction perpendicular to the hole axis, is contiguous with the metal strip portion that extends through the hole such that the two metal strip portions together form a single metal strip. Throughout its length, the single metal strip has a uniform width and thickness and therefore can have a controlled and uniform impedance. In some embodiments, multiple metal strips pass through the same TSV hole. In some embodiments, the structure is a coaxial TSV.

Abstract: Methods of isolating a portion of a wellbore comprising placing a sealant composition into a subterranean formation after drilling of the wellbore therein and subjecting the sealant composition to ionizing radiation wherein subjecting the sealant composition to the ionizing radiation alters the set modifier. The sealant composition comprises a set modifier selected from the group consisting of an accelerator, an oxidizing agent, a set retarder, and combinations thereof. And the sealant composition comprises a polymeric component.