Abstract: The present invention is directed to a coaxial waveguide applicator for an electromagnetic wave-activated sorption system which comprises at least one sorber having a metallic tubular housing defining an outer conductor and first and second ends which are sealed to define an enclosure within the outer conductor; a sorbate/sorbent compound located within the enclosure; the sorber including a port through which a sorbate may be communicated into or out of the enclosure; a metallic inner conductor extending into the outer conductor and parallel to the longitudinal axis of the sorber; an electromagnetic wave generator; and a waveguide for coupling electromagnetic waves generated by the electromagnetic wave generator to the inner and outer conductors; wherein electromagnetic waves transmitted by the electromagnetic wave generator are propagated through the enclosure by the inner and outer conductors to desorb the sorbate from the sorbate/sorbent compound.