Abstract: A method of making an optical article having a gradient tint and a gradient polarization. The method includes contacting one or more dye compositions including at least one of a dichroic dye, a photochromic-dichroic dye, or any combination thereof, with an optical element having a continuous coating including at least one alignment zone. At least a portion of the dye composition diffuses into the coating at a predetermined concentration gradient along at least a portion of the coating.

Abstract: An optical article that includes an optical element and an anisotropic coating layer formed over at least a portion of the optical element. The anisotropic coating layer can include a first light-influencing zone comprising at least one first anisotropic material and a second light-influencing zone comprising at least one second anisotropic material. The at least one of the first light-influencing zone and the second light-influencing zone further include at least one dichroic material and/or at least one photochromic-dichroic material such that the first light-influencing zone and the second light-influencing zone exhibit a different color property, a different photochromic-dichroic reversible change, a different amount of polarization, or a combination thereof.

Abstract: A method of making an optical article having a gradient tint and a gradient polarization. The method includes providing an optical element including a coating having at least one alignment zone. A dye composition is contacted with the coating. The dye composition includes at least one of: a dichroic dye, a photochromic-dichroic dye, or a combination thereof to diffuse at least a portion of the dye composition into the coating at a predetermined concentration gradient along at least a portion of the coating to provide the gradient tint and the gradient polarization. A kit for making an optical article having a gradient tint and a gradient polarization. An optical article prepared from a method for making an optical article having a gradient tint and a gradient polarization.

Abstract: A method of producing an optical article includes applying an imbibition composition having at least one dye onto at least a portion of at least one imbibable surface (45) of a substrate (20) to form a coated substrate (10). The method further includes irradiating at least a portion of the coated substrate with heat from a heat source (80) to form a heat gradient across the coated substrate (10) to diffuse the at least one dye into the imbibable surface to form an at least partially imbibed substrate having a dye concentration gradient corresponding to the heat gradient. The method further includes removing a residual component of the imbibition composition from the at least partially imbibed substrate. The dye concentration gradient forms a gradient pattern upon exposure to actinic radiation.

Abstract: An optical article that includes an optical element and an anisotropic coating layer formed over at least a portion of the optical element. The anisotropic coating layer can include a first light-influencing zone comprising at least one first anisotropic material and a second light-influencing zone comprising at least one second anisotropic material. The at least one of the first light-influencing zone and the second light-influencing zone further include at least one dichroic material and/or at least one photochromic-dichroic material such that the first light-influencing zone and the second light-influencing zone exhibit a different color property, a different photochromic-dichroic reversible change, a different amount of polarization, or a combination thereof.

Abstract: A method of making an optical article having a gradient tint and a gradient polarization. The method includes providing an optical element including a coating having at least one alignment zone. A dye composition is contacted with the coating. The dye composition includes at least one of: a dichroic dye, a photochromic-dichroic dye, or a combination thereof to diffuse at least a portion of the dye composition into the coating at a predetermined concentration gradient along at least a portion of the coating to provide the gradient tint and the gradient polarization. A kit for making an optical article having a gradient tint and a gradient polarization. An optical article prepared from a method for making an optical article having a gradient tint and a gradient polarization.

Abstract: An optical article that includes an optical element and an anisotropic coating layer formed over at least a portion of the optical element. The anisotropic coating layer can include a first light-influencing zone comprising at least one first anisotropic material and a second light-influencing zone comprising at least one second anisotropic material. The at least one of the first light-influencing zone and the second light-influencing zone further include at least one dichroic material and/or at least one photochromic-dichroic material such that the first light-influencing zone and the second light-influencing zone exhibit a different color property, a different photochromic-dichroic reversible change, a different amount of polarization, or a combination thereof.

Abstract: A method of making an optical article having a gradient tint and a gradient polarization. The method includes providing an optical element including a coating having at least one alignment zone. A dye composition is contacted with the coating. The dye composition includes at least one of: a dichroic dye, a photochromic-dichroic dye, or a combination thereof to diffuse at least a portion of the dye composition into the coating at a predetermined concentration gradient along at least a portion of the coating to provide the gradient tint and the gradient polarization. A kit for making an optical article having a gradient tint and a gradient polarization. An optical article prepared from a method for making an optical article having a gradient tint and a gradient polarization.

Abstract: A method of producing an optical article includes applying an imbibition composition having at least one dye onto at least a portion of at least one imbibable surface (45) of a substrate (20) to form a coated substrate (10). The method further includes irradiating at least a portion of the coated substrate with heat from a heat source (80) to form a heat gradient across the coated substrate (10) to diffuse the at least one dye into the imbibable surface to form an at least partially imbibed substrate having a dye concentration gradient corresponding to the heat gradient. The method further includes removing a residual component of the imbibition composition from the at least partially imbibed substrate. The dye concentration gradient forms a gradient pattern upon exposure to actinic radiation.

Abstract: A method of making an optical article having a gradient tint and a gradient polarization. The method includes providing an optical element including a coating having at least one alignment zone. A dye composition is contacted with the coating. The dye composition includes at least one of: a dichroic dye, a photochromic-dichroic dye, or a combination thereof to diffuse at least a portion of the dye composition into the coating at a predetermined concentration gradient along at least a portion of the coating to provide the gradient tint and the gradient polarization. A kit for making an optical article having a gradient tint and a gradient polarization. An optical article prepared from a method for making an optical article having a gradient tint and a gradient polarization.

Abstract: An optical article that includes an optical element and an anisotropic coating layer formed over at least a portion of the optical element. The anisotropic coating layer can include a first light-influencing zone comprising at least one first anisotropic material and a second light-influencing zone comprising at least one second anisotropic material. The at least one of the first light-influencing zone and the second light-influencing zone further include at least one dichroic material and/or at least one photochromic-dichroic material such that the first light-influencing zone and the second light-influencing zone exhibit a different color property, a different photochromic-dichroic reversible change, a different amount of polarization, or a combination thereof.

Abstract: A method of making an optical article having a gradient tint and a gradient polarization. The method includes contacting one or more dye compositions including at least one of a dichroic dye, a photochromic-dichroic dye, or any combination thereof, with an optical element having a continuous coating including at least one alignment zone. At least a portion of the dye composition diffuses into the coating at a predetermined concentration gradient along at least a portion of the coating.