Patents by Inventor David L. Dauplaise

David L. Dauplaise has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7943789
    Abstract: The invention relates to an aqueous sizing composition comprising (a) an emulsion comprising an alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles suspended in a first starch component containing emulsifying starch selected from the group consisting of non-ionic starches, ionic starches, and mixtures thereof, and (b) a second starch component selected from the group consisting of non-ionic starches, ionic starches and mixtures thereof, such that the alkenylsuccinic anhydride and the starch in the emulsion and the second starch component are present at a starch: alkenylsuccinic anhydride weight ratio that is sufficiently high to enable the sizing composition to impart useful sizing properties to a fibrous substrate when the sizing composition contacts the fibrous substrate. The invention also relates to fibrous substrates treated with the sizing composition, processes for making the composition and processes for using such a composition, and other compositions.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: May 17, 2011
    Assignee: Kemira OYJ
    Inventors: Harold A. Goldsberry, III, Kimberly C. Dilts, Charles R. Hunter, Michael P. O'Toole, Robert J. Proverb, Lucyna Pawlowska, Glenn E. Baikow, Katarzyna Komarowska, David L. Dauplaise, Michael J. Scanlon
  • Patent number: 7767059
    Abstract: The invention relates to a flushable paper product comprising a fibrous substrate having (i) at least one strength region comprising a reacted cationic or a reacted nonionic strength agent and (ii) at least one dispersibility region, wherein the paper product has (a) a dispersibility of at least one tenth of a second, (b) a dry strength, and (c) a wet strength of at least about five percent of the dry strength.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: August 3, 2010
    Assignee: Kemira Oyj
    Inventors: Michael Ryan, David L. Dauplaise
  • Publication number: 20090277355
    Abstract: The invention relates to an aqueous sizing composition including: (a) a first component comprising an emulsion having an alkenylsuccinic anhydride component containing alkenylsuccinic anhydride particles and a surfactant component; suspended in water; and (b) a second component selected from the group consisting of cationic starches, non-ionic starches, anionic starches, water, water-soluble polymers, and mixtures thereof; such that the alkenylsuccinic anhydride component and the second component are sufficiently diluted to enable the sizing composition to impart useful sizing properties to a fibrous substrate when the sizing composition contacts the fibrous substrate. The invention also relates to fibrous substrates treated with such a composition as well as processes for making and using the composition. In one embodiment, alkyl ketene dimer is used instead of alkenylsuccinic anhydride.
    Type: Application
    Filed: July 20, 2009
    Publication date: November 12, 2009
    Inventors: Lucyna Pawlowska, Kimberly C. Dilts, Charles R. Hunter, Michael P. O'Toole, Robert J. Proverb, Thomas T. Long, Gina Garro, David L. Dauplaise, Katarzyna Komarowska, Harold A. Goldsberry, III, Glenn E. Baikow
  • Patent number: 6666952
    Abstract: This invention relates to paper sizing compositions comprised of at least one sizing agent selected from ASA, AKD and rosin where the at least one sizing agent is emulsified in water, at least one emulsion stabilizer, and from about 0.01% to about 15% by weight of at least one hydrophobic substance, based on the total weight of sizing agent present, provided that the hydrophobic substance is not highly alkoxylated. The sizing promotion efficiency of the paper sizing compositions, as determined by at least one method selected from the Cytec size testing method, the Hercules size testing method, and the Cobb size testing method, is greater than or equal to about 4. Exemplary hydrophobic substances include fatty acid esters, triglycerides, hydrocarbons, esters and/or amides derived from ASA, silicone oils, alcohols, and stearic anhydride. The invention also relates to methods for sizing paper products with these paper sizing compositions and paper or paperboard treated with these sizing compositions.
    Type: Grant
    Filed: May 6, 2003
    Date of Patent: December 23, 2003
    Assignee: Bayer Chemicals Corporation
    Inventors: Kimberly C. Dilts, Robert J. Proverb, David L. Dauplaise
  • Publication number: 20030205167
    Abstract: This invention relates to paper sizing compositions comprised of at least one sizing agent selected from ASA, AKD and rosin where the at least one sizing agent is emulsified in water, at least one emulsion stabilizer, and from about 0.01% to about 15% by weight of at least one hydrophobic substance, based on the total weight of sizing agent present, provided that the hydrophobic substance is not highly alkoxylated. The sizing promotion efficiency of the paper sizing compositions, as determined by at least one method selected from the Cytec size testing method, the Hercules size testing method, and the Cobb size testing method, is greater than or equal to about 4. Exemplary hydrophobic substances include fatty acid esters, triglycerides, hydrocarbons, esters and/or amides derived from ASA, silicone oils, alcohols, and stearic anhydride. The invention also relates to methods for sizing paper products with these paper sizing compositions and paper or paperboard treated with these sizing compositions.
    Type: Application
    Filed: May 6, 2003
    Publication date: November 6, 2003
    Inventors: Kimberly C. Dilts, Robert J. Proverb, David L. Dauplaise
  • Patent number: 6576049
    Abstract: This invention relates to paper sizing compositions comprised of at least one sizing agent selected from ASA, AKD and rosin where the at least one sizing agent is emulsified in water, at least one emulsion stabilizer, and from about 0.01% to about 15% by weight of at least one hydrophobic substance, based on the total weight of sizing agent present, provided that the hydrophobic substance is not highly alkoxylated. The sizing promotion efficiency of the paper sizing compositions, as determined by at least one method selected from the Cytec size testing method, the Hercules size testing method, and the Cobb size testing method, is greater than or equal to about 4. Exemplary hydrophobic substances include fatty acid esters, triglycerides, hydrocarbons, esters and/or amides derived from ASA, silicone oils, alcohols, and stearic anhydride. The invention also relates to methods for sizing paper products with these paper sizing compositions and paper or paperboard treated with these sizing compositions.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: June 10, 2003
    Assignee: Bayer Corporation
    Inventors: Kimberly C. Dilts, Robert J. Proverb, David L. Dauplaise
  • Patent number: 6210475
    Abstract: The present invention is directed to paper sizing emulsions, a method of making sizing emulsions, a method of sizing paper products, such as paper and board, and paper or board made using the method and the sizing emulsions of the invention. The paper sizing emulsions of the invention contains at least one sizing agent and a cationic liquid hydroxyalkylated starch that is pumpable and at least partially degraded. Typically, before dilution for mixing with the sizing material, the starch exists as a liquid in water and contains solids in an amount up to about 30 percent by weight, and has a viscosity of up to about 30,000 cps. The starch is diluted with water, before emulsifying the sizing agent to reduce the solids to an amount suitable for emulsification, and used to emulsify the sizing agent. The resulting emulsion can then be used to size paper and board.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: April 3, 2001
    Assignee: Bayer Corporation
    Inventors: David L. Dauplaise, Robert Joseph Proverb, Katarzyna Komarowska
  • Patent number: 5512184
    Abstract: Quatemary dialkylaminomethyl polymers derived from (alk)acrylamide and about 1 to about 15 mole percent ethylenically unsaturated anionic comonomer wherein the resulting ampholytic polymer has a standard viscosity of at least about 2.1 cps am disclosed. Processes for the preparation of these polymers and their use in flocculating suspended material in a variety of aqueous dispersions are also disclosed.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: April 30, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Michael S. Ryan, David L. Dauplaise, Robert J. Proverb
  • Patent number: 5393827
    Abstract: A novel method for preparing anionic, cationic or non-ionic polymeric microemulsions comprising a multi-step process to achieve high solids and low emulsifier and oil content. The polymeric microemulsions are useful in papermaking as retention aids, in solid-liquid separation as flocculants and in enhanced oil recovery as a drive fluid.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: February 28, 1995
    Assignee: Cytec Technology Corp.
    Inventors: David L. Dauplaise, Michael P. O'Toole
  • Patent number: 5380444
    Abstract: Quaternary dialkylaminomethyl polymers derived from (alk)acrylamide and about 1 to about 15 mole percent ethylenically unsaturated anionic comonomer wherein the resulting ampholytic polymer has a standard viscosity of at least about 2.1 cps are disclosed. Processes for the preparation of these polymers and their use in flocculating suspended material in paper deinking sludges and deinking process waters are also disclosed.
    Type: Grant
    Filed: February 23, 1994
    Date of Patent: January 10, 1995
    Assignee: Cytec Technology Corp.
    Inventors: Michael S. Ryan, David L. Dauplaise, Robert J. Proverb
  • Patent number: 5320711
    Abstract: Compositions comprising microparticles of a cross-linkable, glyoxalated (meth)acrylamide containing, polymeric material are disclosed. They are prepared using inverse microemulsion polymerization techniques and are useful as wet- and dry-strength agents in paper production.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: June 14, 1994
    Assignee: Cytec Technology Corp.
    Inventors: David L. Dauplaise, Joseph J. Kozakiewicz, Joseph M. Schmitt
  • Patent number: 5139614
    Abstract: A process is disclosed for the preparation of styrene/acrylic type polymers which are useful in the sizing of paper. The process comprises polymerizing the monomers in an alcohol/water mixture at reflux temperature in the presence of a free-radical generating catalyst. The catalyst is added portion-wise over the course of the reaction and the resultant polymer is neutralized while substantially simultaneously separating the alcohol/water mixture and adding water to recover a product of less than 25% polymer solids.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: August 18, 1992
    Assignee: American Cyanamid Company
    Inventors: Otto S. dePierne, David L. Dauplaise, Robert J. Proverb
  • Patent number: 5138004
    Abstract: A process is disclosed for the preparation of styrene/acrylic type polymers which are useful in the sizing of paper. The process comprises polymerizing the monomers in an alcohol/water mixture at reflux temperature in the presence of a free-radical generating catalyst. The catalyst is added portion-wise over the course of the reaction and the resultant polymer is neutralized while substantially simulaneously separating the alcohol/water mixture and adding water to recover a product of less than 25% polymer solids.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: August 11, 1992
    Inventors: Otto S. dePierne, David L. Dauplaise, Robert J. Proverb
  • Patent number: 5122568
    Abstract: A process is disclosed for the preparation of styrene/acrylic type polymers which are useful in the sizing of paper. The process comprises polymerizing the monomers in an alcohol/water mixture at reflux temperature in the presence of a free-radical generating catalyst. The catalyst is added portion-wise over the course of the reaction and the resultant polymer is neutralized while substantially simultaneously separating the alcohol/water mixture and adding water to recover a product of less than 25% polymer solids.
    Type: Grant
    Filed: February 6, 1991
    Date of Patent: June 16, 1992
    Assignee: American Cyanamid Company
    Inventors: Otto S. dePierne, David L. Dauplaise, Robert J. Proverb
  • Patent number: 5093091
    Abstract: Iron is removed from concentrated alum solutions by contacting said solutions with a polymer containing hydroxamic acid or salt groups.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: March 3, 1992
    Assignee: American Cyanamid Company
    Inventors: David L. Dauplaise, Wei S. Yen
  • Patent number: 5041503
    Abstract: Compositions comprising microparticles of a cross-linkable, glyoxalated (meth)acrylamide containing, polymeric material are disclosed. They are prepared using inverse mircoemulsion polymerization techniques and are useful as wet- and dry-strength agents in paper production.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: August 20, 1991
    Assignee: American Cyanamid Company
    Inventors: David L. Dauplaise, Joseph J. Kozakiewicz, Joseph M. Schmitt
  • Patent number: 5037863
    Abstract: Functionalized polymer microparticles having particle diameters of from about 200 to about 4000.ANG. are prepared and are useful in facilitating a variety of flocculation and thickening of dispersions of suspended solids applications.
    Type: Grant
    Filed: June 13, 1990
    Date of Patent: August 6, 1991
    Inventors: Joseph J. Kozakiewicz, David L. Dauplaise, Joseph M. Schmitt, Sun-Yi Huang
  • Patent number: 4956400
    Abstract: Functionalized polymer microparticles having particle diameters of from about 200 to about 4000 .ANG. are prepared and are useful in facilitating a variety of flocculation and thickening of dispersions of suspended solids applications.
    Type: Grant
    Filed: October 30, 1989
    Date of Patent: September 11, 1990
    Assignee: American Cyanamid Company
    Inventors: Joseph J. Kozakiewicz, David L. Dauplaise
  • Patent number: 4954538
    Abstract: Compositions comprising microparticles of a cross-linkable, glyoxalated (meth) acrylamide containing, polymeric material are disclosed. They are prepared using inverse microemulsion polymerization techniques and are useful as wet- and dry-strength agents in paper production.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: September 4, 1990
    Assignee: American Cyanamid Company
    Inventors: David L. Dauplaise, Joseph J. Kozakiewicz, Joseph M. Schmitt
  • Patent number: 4696770
    Abstract: An improved process for the production of sulfonated rubrene is disclosed whereby fuming sulfuric acid is employed as the sulfonating agent. The resultant sulfonated rubrene is used as a fluorescer in water-soluble chemiluminescent mixtures e.g. in combination with a water-soluble amide of oxalic acid and hydrogen peroxide or a source of hydrogen peroxide.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: September 29, 1987
    Assignee: American Cyanamid Company
    Inventors: David L. Dauplaise, William J. Trzaskos