Abstract: A method of forming polymer composites includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including the transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles.

Abstract: A method of forming polymer composites includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including the transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles.

Abstract: A method of forming polymer composites having transition metal oxide nanoparticles dispersed therein includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including a plurality of transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles.

Abstract: A method of forming composite materials includes mixing a first metal precursor with a chelating agent to form a first metal-chelate complex. The first metal-chelate complex is added to a polymer binder having terminating hydroxyl groups to form a polymer binder-first metal-chelate. The polymer binder first metal-chelate complex is mixed with an aluminum precursor. The aluminum precursor decomposes forming aluminum nanoparticles dispersed in a continuous phase material having metallic aluminum cores. At least one of the first metal-chelate complex and the first metal is dissolved in the continuous phase. The aluminum nanoparticles can have a passivating coating layer thereon provided by the polymer binder, or can have a passivating coating layer formed by including an epoxide, alcohol, carboxylic acid, or amine in the adding that forms passivating compound(s) which add further protection that can provide complete protection from oxidation of the metallic aluminum cores by air.

Abstract: A method of forming polymer composites having transition metal oxide nanoparticles dispersed therein includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including a plurality of transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles.

Abstract: A method of forming functionalized fly ash particles includes contacting a plurality of fly ash particles with a hydroxide compound under conditions to directly bond oxygen (O) onto a surface portion of the plurality of fly ash particles. The plurality of fly ash particles having O directly bound to their surface portion are reacted with an organic alcohol or an organic acid to covalently bond hydrophobic groups in the form of condensation residue from the organic alcohol or organic acid to the O to form the plurality of functionalized fly ash particles.

Abstract: A solid rocket motor includes a combustion chamber bounded by an outer casing, a propellant grain within the combustion chamber, and an igniter within the outer casing for igniting the propellant grain. A nozzle is coupled to the combustion chamber for releasing hot gasses evolved from burning the propellant grain to provide thrust for propelling the solid rocket motor. The propellant grain is a self-extinguishing propellant grain that includes at least one fuel, at least one oxidizing agent, at least one binder, and at least one surfactant that imparts the self-extinguishing property. The propellant grain provides a burning rate as a function of pressure that includes a negative pressure dependence portion, wherein the burning rate in the negative pressure dependence portion decreases with increasing pressure until a cutoff pressure is reached which results in extinguishment of the propellant grain.

Abstract: A method of scavenging oil from an oil-water mixture includes providing a plurality of functionalized fly ash particles having functionalized surfaces including reactive groups or reactive materials having hydrophobic groups covalently bound to the reactive groups or reactive materials. The oil-water mixture is contacted with the plurality of functionalized fly ash particles. The plurality of functionalized fly ash particles absorb oil from the oil-water mixture to form oil-laden fly ash particles. The oil-laden fly ash particles can be fed into a combustion process to generate heat from oil absorbed thereon, or absorbed oil from the oil-laden fly ash particles can be separated using a desorption process, and the oil recovered after separating.

Abstract: Solid composite propellant compositions include at least one oxidizing agent, at least one binder, and at least one surfactant. The surfactant provides the solid propellant the property of being “self-extinguishing”, where the burning rate of the solid composite propellant as a function of pressure includes a negative pressure dependence portion, wherein the burning rate in the negative pressure dependence portion decreases with increasing pressure until a cutoff pressure is reached which results in extinguishment of the solid composite propellant. The solid composite propellant can also include at least one catalyst that modifies the burning rate of the solid composite propellant. Solid composite propellants can be extinguished without the need for depressurization by reaching a cutoff pressure, and with a tailored burning rate.

Abstract: A method of scavenging oil from an oil-water mixture includes providing a plurality of functionalized fly ash particles having functionalized surfaces including reactive groups or reactive materials having hydrophobic groups covalently bound to the reactive groups or reactive materials. The oil-water mixture is contacted with the plurality of functionalized fly ash particles. The plurality of functionalized fly ash particles absorb oil from the oil-water mixture to form oil-laden fly ash particles. The oil-laden fly ash particles can be fed into a combustion process to generate heat from oil absorbed thereon, or absorbed oil from the oil-laden fly ash particles can be separated using a desorption process, and the oil recovered after separating.

Abstract: A geolocation system (10) includes an emitter (12), a plurality of collection nodes (14,16,18), and a control station (20). Each collection node includes a receiver (24) that is operable to receive signals transmitted from the emitter (12), generate a reduced data stream that includes only signal data, and communicate the reduced data stream to the control station (20) along with navigation data. The receiver (24) identifies signal data by detecting an energy level of the raw collection data. More specifically, the receiver (24) determines a bandwidth and a signal-to-noise ratio of each portion of the collection data, and identifies each portion as including signal data if both the bandwidth and the signal-to-noise ratio exceed predetermined threshold amounts. The receiver (24) includes a digital signal processing component (36) for performing calculations used by the receiver (24) to determine the bandwidth and the signal-to-noise ratio.

Abstract: Systems and methods for detection and geolocation of multiple emitters that are emitting RF signal energy on a common frequency, and that may be implemented to separate, geolocate, and/or determine the number of emitters (e.g., radio users) emitting on a common RF frequency. Real-time signal qualification processing may be employed to continuously monitor and collect incoming receiver tuner data for signal activity and ignore irrelevant noise data. Each set of data blocks from an emitter transmission signal may be defined as an emission cluster, and a set of time difference of arrival (TDOA)/frequency difference of arrival (FDOA) pairs may be computed for each emission cluster with each TDOA/FDOA pair yielding a geolocation result. A statistical qualification method may be used to produce a final geolocation answer from each set of emission cluster geolocation results, and a geolocation error ellipse computed for the final geolocation answer of each emission cluster.

Abstract: Systems and methods for detection and geolocation of multiple emitters that are emitting RF signal energy on a common frequency, and that may be implemented to separate, geolocate, and/or determine the number of emitters (e.g., radio users) emitting on a common RF frequency. Real-time signal qualification processing may be employed to continuously monitor and collect incoming receiver tuner data for signal activity and ignore irrelevant noise data. Each set of data blocks from an emitter transmission signal may be defined as an emission cluster, and a set of time difference of arrival (TDOA)/frequency difference of arrival (FDOA) pairs may be computed for each emission cluster with each TDOA/FDOA pair yielding a geolocation result. A statistical qualification method may be used to produce a final geolocation answer from each set of emission cluster geolocation results, and a geolocation error ellipse computed for the final geolocation answer of each emission cluster.

Abstract: A method and apparatus for detecting emitter movement. The method and apparatus generally include acquiring a measured signal characteristic corresponding to a signal emitted from an emitter, estimating a signal characteristic corresponding to the signal, and comparing the measured and estimated signal characteristics to determine if the emitter is moving. Such a configuration enables a rapid and accurate detection of emitter movement without requiring multiple measurements, complex systems, or time-consuming calculations.

Abstract: Methods and apparatus operable to estimate the geolocation of a signal emitter. In some embodiments, the methods comprise acquiring collection data from a plurality of collector elements, computing a plurality of candidate geolocations from the acquired collection data, and applying a clustering analysis to the candidate geolocations to estimate the geolocation of the signal emitter.

Abstract: A method and apparatus for reducing geolocation ambiguity in signal tracking. The method and apparatus generally include acquiring a first and a second set of geolocations and comparing the sets to reduce ambiguous geolocations. Such a configuration enables accurate and rapid geolocation determination without requiring complex and time-consuming direction finding devices and methods.

Abstract: Methods and apparatus operable to estimate the geolocation of a signal emitter. In some embodiments, the methods comprise acquiring collection data from a plurality of collector elements, computing a plurality of candidate geolocations from the acquired collection data, and applying a clustering analysis to the candidate geolocations to estimate the geolocation of the signal emitter.

Abstract: A geolocation system (10) includes an emitter (12), a plurality of collection nodes (14,16,18), and a control station (20). Each collection node includes a receiver (24) that is operable to receive signals transmitted from the emitter (12), generate a reduced data stream that includes only signal data, and communicate the reduced data stream to the control station (20) along with navigation data. The receiver (24) identifies signal data by detecting an energy level of the raw collection data. More specifically, the receiver (24) determines a bandwidth and a signal-to-noise ratio of each portion of the collection data, and identifies each portion as including signal data if both the bandwidth and the signal-to-noise ratio exceed predetermined threshold amounts. The receiver (24) includes a digital signal processing component (36) for performing calculations used by the receiver (24) to determine the bandwidth and the signal-to-noise ratio.

Abstract: An oil change interval monitor is provided which senses diesel engine variables such as oil temperature, fuel flow and the volume of oil added to the engine since the last oil change and combines these variables with values determined by known engine parameters to provide a continuously updated indication of the percentage of oil life used by the engine since the last oil change.

Abstract: This disclosure relates to a system for measuring the instantaneous speed of an index point on a rotating part. The part may be a toothed gear or a wheel of an engine, and the index point may be an identifiable point on the part. The system comprises a sensor that is mounted adjacent the part, the sensor including two sensing elements that are spaced apart in the direction of movement of the point as the part rotates. As the point passes the sensor, it causes a first pulse to be produced by one element and then a second pulse to be produced by the other element. The system further includes circuitry that responds to the two time-spaced pulses and produces an indication of the time interval between the two pulses. This time interval is a function of the speed of the point which in turn is proportional to the rate of rotation of the part. In the instance where the part is attached to an engine flywheel, the time interval is also an inverse function of engine RPM.