Patents by Inventor David M. Minahan
David M. Minahan has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7888278Abstract: The present invention relates to stabilized supports stable at temperatures above 800° C., and method of preparing such supports, which includes adding a rare earth metal to an aluminum-containing precursor prior to calcining. The present invention can be more specifically seen as a support, process and catalyst wherein the stabilized alumina catalyst support comprises a rare earth aluminate with a molar ratio of aluminum to rare earth metal greater than 5:1 and, optionally, an aluminum oxide. More particularly, the invention relates to the use of catalysts comprising rhodium, ruthenium, iridium, or combinations thereof, loaded onto said stabilized supports for the synthesis gas production via partial oxidation of light hydrocarbons, and further relates to gas-to-liquids conversion processes.Type: GrantFiled: November 12, 2003Date of Patent: February 15, 2011Assignee: ConocoPhillips CompanyInventors: Charles R. Rapier, Shuibo Xie, Baili Hu, Beatrice C. Ortego, David E. Simon, David M. Minahan
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Patent number: 7416571Abstract: Embodiments include methods and apparatus for mixing feedgases and producing synthesis gas. The apparatus includes a vessel containing a mixing system comprising one or more channels and a reaction zone downstream of the mixing system. A first feedgas and a second feedgas are separately injected into different injection portions of each channel, such that the second feedgas is injected in an acute direction into the first feedgas flowstream. The injected feedgases thereafter mix in a mixing portion of the channel. The mixing portion of each channel may have a reduced cross-sectional area so as to increase the total velocity of the feedgases while they mix. A feedgas mixture exits each channel of the mixing system to feed the reaction zone where it gets converted. Preferred embodiments include mixing O2 with a hydrocarbon gas and converting the mixture in a catalytic reaction zone to produce synthesis gas.Type: GrantFiled: March 9, 2005Date of Patent: August 26, 2008Assignee: ConocoPhillips CompanyInventors: Jamie D. Lucas, Guy H. Lewis, Harold A. Wright, Dale R. McIntyre, David M. Minahan, David H. Anderson
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Patent number: 7226548Abstract: The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions. Preferred embodiments of the present invention comprise catalyst compositions having high melting point metallic alloys, and methods of preparing and using the catalysts. In particular, the metallic alloys are preferably rhodium alloys. Accordingly, the present invention also encompasses an improved method for converting a hydrocarbon containing gas and an atomic oxygen-containing gas to a gas mixture comprising hydrogen and carbon monoxide, i.e., syngas, using the catalyst compositions in accordance with the present invention. In addition, the present invention contemplates an improved method for converting hydrocarbon gas to liquid hydrocarbons using the novel syngas catalyst compositions described herein.Type: GrantFiled: November 12, 2003Date of Patent: June 5, 2007Assignee: ConocoPhillips CompanyInventors: Shuibo Xie, Chad M. Ricketson, David M. Minahan, Yaming Jin, Harold A. Wright
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Patent number: 7223354Abstract: A process and catalyst are disclosed for the catalytic partial oxidation of light hydrocarbons to produce synthesis gas at superatmospheric pressures. A preferred catalyst used in the process includes a nickel-magnesium oxide solid solution and at least one promoter chosen from Cr, Mn, Mo, W, Sn, Re, Rh, Ru, Ir, Pt, La, Ce, Sm, Yb, Lu, Bi, Sb, In and P, and oxides thereof, carried on a refractory support.Type: GrantFiled: January 9, 2003Date of Patent: May 29, 2007Assignee: ConocoPhillips CompanyInventors: Sriram Ramani, Joe D. Allison, David M. Minahan, Harold A. Wright
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Patent number: 7097787Abstract: A method of partially oxidizing a feed gas comprises providing a reactor containing a catalyst, providing a gas distributor comprising a body having a plurality of channels therethrough and a plurality of outlets from said channels for distributing gas across the catalyst, feeding the feed gas and the oxygen-containing gas into the gas distributor and allowing the feed gas and the oxygen-containing gas to flow through the gas distributor and out through the outlets into contact with the catalyst. The gas distributor preferably comprises a micro-channel gas distributor, which can be assembled by providing a plurality of etched plates defining flow channels, and stacking and fusing the plates. The reactant gases can be mixed within the gas distributor or maintained separately until they have exited the gas distributor.Type: GrantFiled: July 15, 2003Date of Patent: August 29, 2006Assignee: ConocoPhillips CompanyInventors: Guy H. Lewis, Chien-Ping Pan, Harold A. Wright, David H. Anderson, David M. Minahan, Vincent H. Melquist, Cemal Ercan, Gloria I. Straguzzi, Stephen R. Landis, Phillipp R. Ellison
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Patent number: 7056488Abstract: Controlled pore structure catalysts are disclosed that are active for catalyzing the partial oxidation of methane to CO and H2 and, advantageously, are capable of initiating the reaction without the need for an additional ignition source. A preferred catalyst comprises rhodium and samarium supported on an alumina or modified alumina support having certain surface area, pore volume, pore size and metal dispersion characteristics that permit light-off of the reaction at temperatures below 500° C. and with little or no use of an ignition agent. A method of partially oxidizing a light hydrocarbon to form synthesis gas, and a method of enhancing low-temperature light-off of the process are also described.Type: GrantFiled: November 19, 2002Date of Patent: June 6, 2006Assignee: ConocoPhillips CompanyInventors: Tianyan Niu, Daxiang Wang, David M. Minahan, Harold A. Wright, Gloria I. Straguzzi
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Patent number: 7008560Abstract: A method for converting light hydrocarbons (e.g. methane or natural gas) to synthesis gas employs a silicon carbide-supported catalyst that catalyzes a net partial oxidation reaction. Certain preferred catalysts include a catalytically active metal disposed on a silicon carbide support.Type: GrantFiled: February 10, 2003Date of Patent: March 7, 2006Assignee: ConocoPhillips CompanyInventors: Sriram Ramani, David M. Minahan, Yi Jiang
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Patent number: 6946114Abstract: Lanthanide-promoted rhodium-containing supported catalysts that are active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and high efficiency processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises highly dispersed, high surface area rhodium on a granular zirconia support with an intermediate coating of a lanthanide metal and/or oxide thereof and is thermally conditioned during catalyst preparation. In a preferred syngas production process a stream of methane-containing gas and O2 is passed over a thermally conditioned, high surface area Rh/Sm/zirconia granular catalyst in a short contact time reactor to produce a mixture of carbon monoxide and hydrogen.Type: GrantFiled: September 5, 2001Date of Patent: September 20, 2005Assignee: ConocoPhillips CompanyInventors: Joe D. Allison, Larry D. Swinney, Tianyan Niu, Kevin L. Ricketson, Daxiang Wang, Sriram Ramani, Gloria I. Straguzzi, David M. Minahan, Harold A. Wright, Baili Hu
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Publication number: 20040157939Abstract: A method for converting light hydrocarbons (e.g. methane or natural gas) to synthesis gas employs a silicon carbide-supported catalyst that catalyzes a net partial oxidation reaction. Certain preferred catalysts include a catalytically active metal disposed on a silicon carbide support.Type: ApplicationFiled: February 10, 2003Publication date: August 12, 2004Applicant: ConocoPhillips CompanyInventors: Sriram Ramani, David M. Minahan, Yi Jiang
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Publication number: 20040147619Abstract: The present invention discloses synthesis gas catalysts, and methods for making such catalysts, that are active for promoting partial oxidation of light hydrocarbons to CO and H2. The catalysts comprise a support and an active metal. The catalysts may further comprise a promoter and halide or a rare earth oxyhalide. The present invention further discloses a method for producing synthesis gas by net partial oxidation of light hydrocarbons by contacting O2 and light hydrocarbons in the presence of a synthesis gas catalyst as previously described. The present invention also describes a method for extending the life of a synthesis gas catalyst by contacting the catalyst with a halide. A method for making middle distillates from light hydrocarbons by partial oxidation of light hydrocarbons over a synthesis gas catalyst as previously described and Fischer-Tropsch reaction is also disclosed.Type: ApplicationFiled: January 23, 2003Publication date: July 29, 2004Applicant: ConocoPhillips CompanyInventors: Tianyan Niu, Kevin L. Coy, David M. Minahan, Harold A. Wright
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Publication number: 20040138060Abstract: The present invention relates to stabilized supports stable at temperatures above 800° C., and method of preparing such supports, which includes adding a rare earth metal to an aluminum-containing precursor prior to calcining. The present invention can be more specifically seen as a support, process and catalyst wherein the stabilized alumina catalyst support comprises a rare earth aluminate with a molar ratio of aluminum to rare earth metal greater than 5:1 and, optionally, an aluminum oxide. More particularly, the invention relates to the use of catalysts comprising rhodium, ruthenium, iridium, or combinations thereof, loaded onto said stabilized supports for the synthesis gas production via partial oxidation of light hydrocarbons, and further relates to gas-to-liquids conversion processes.Type: ApplicationFiled: November 12, 2003Publication date: July 15, 2004Applicant: ConocoPhillips CompanyInventors: Charles R. Rapier, Shuibo Xie, Baili Hu, Beatrice C. Ortego, David E. Simon, David M. Minahan
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Publication number: 20040138317Abstract: The present invention relates to thermally stable, high surface area alumina supports and method of preparing such supports with at least one modifying agent. The method includes adding the modifying agent to the alumina prior to calcining. More particularly, the invention relates to the use of such catalysts for the catalytic partial oxidation of light hydrocarbons (e.g., methane or natural gas) to produce primarily synthesis gas. The present invention further relates to gas-to-liquids conversion processes, more specifically for producing C5+ hydrocarbons.Type: ApplicationFiled: November 12, 2003Publication date: July 15, 2004Applicant: ConocoPhillips CompanyInventors: Shuibo Xie, Mary E. Wolf, Harold A. Wright, Rafael L. Espinoza, Tianyan Niu, David M. Minahan, Kevin L. Coy
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Publication number: 20040067180Abstract: A method of partially oxidizing a feed gas comprises providing a reactor containing a catalyst, providing a gas distributor comprising a body having a plurality of channels therethrough and a plurality of outlets from said channels for distributing gas across the catalyst, feeding the feed gas and the oxygen-containing gas into the gas distributor and allowing the feed gas and the oxygen-containing gas to flow through the gas distributor and out through the outlets into contact with the catalyst. The gas distributor preferably comprises a micro-channel gas distributor, which can be assembled by providing a plurality of etched plates defining flow channels, and stacking and fusing the plates. The reactant gases can be mixed within the gas distributor or maintained separately until they have exited the gas distributor.Type: ApplicationFiled: July 15, 2003Publication date: April 8, 2004Applicant: ConocoPhillips CompanyInventors: Guy H. Lewis, Chien-Ping Pan, Harold A. Wright, David H. Anderson, David M. Minahan, Vincent H. Melquist, Cemal Ercan, Gloria I. Straguzzi, Stephen R. Landis, Phillipp R. Ellison
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Publication number: 20030180215Abstract: Controlled pore structure catalysts are disclosed that are active for catalyzing the partial oxidation of methane to CO and H2 and, advantageously, are capable of initiating the reaction without the need for an additional ignition source. A preferred catalyst comprises rhodium and samarium supported on an alumina or modified alumina support having certain surface area, pore volume, pore size and metal dispersion characteristics that permit light-off of the reaction at temperatures below 500° C. and with little or no use of an ignition agent. A method of partially oxidizing a light hydrocarbon to form synthesis gas, and a method of enhancing low-temperature light-off of the process are also described.Type: ApplicationFiled: November 19, 2002Publication date: September 25, 2003Applicant: Conoco, Inc.Inventors: Tianyan Niu, Daxiang Wang, David M. Minahan, Harold A. Wright, Gloria I. Straguzzi
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Publication number: 20030165424Abstract: A process and catalyst are disclosed for the catalytic partial oxidation of light hydrocarbons to produce synthesis gas at superatmospheric pressures. A preferred catalyst used in the process includes a nickel-magnesium oxide solid solution and at least one promoter chosen from Cr, Mn, Mo, W, Sn, Re, Rh, Ru, Ir, Pt, La, Ce, Sm, Yb, Lu, Bi, Sb, In and P, and oxides thereof, carried on a refractory support.Type: ApplicationFiled: January 9, 2003Publication date: September 4, 2003Applicant: Conoco Inc.Inventors: Sriram Ramani, Joe D. Allison, David M. Minahan, Harold A. Wright
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Publication number: 20030045423Abstract: A family of supported hexagonal phase mixed metal oxide catalysts are disclosed that have the general formula M2.5LnRh6O13 (expressed as atomic ratios), wherein M refers to Group II elements such as Mg, Ca, Ba, Sr and Be or a Group VIII transition metal that can exist in a +2 oxidation state, such as Ti, V, Mn, Fe, Co, Ni, Cu, Zn, Nb, Pd, Cd and Ta. Ln refers to the rare earth lanthanide group of elements, such as La, Yb, Sm and Ce. This family of catalysts demonstrate unexpected activity for efficiently catalyzing the net partial oxidation of methane in a short contact time reactor, with high selectivities for H2 product.Type: ApplicationFiled: June 4, 2002Publication date: March 6, 2003Applicant: Conoco Inc.Inventors: Hasan Dindi, William H. Manogue, Norman Herron, Tianyan Niu, Daxiang Wang, David M. Minahan
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Publication number: 20020115730Abstract: Lanthanide-promoted rhodium-containing supported catalysts that are active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and high efficiency processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises highly dispersed, high surface area rhodium on a granular zirconia support with an intermediate coating of a lanthanide metal and/or oxide thereof and is thermally conditioned during catalyst preparation. In a preferred syngas production process a stream of methane-containing gas and O2 is passed over a thermally conditioned, high surface area Rh/Sm/zirconia granular catalyst in a short contact time reactor to produce a mixture of carbon monoxide and hydrogen.Type: ApplicationFiled: September 5, 2001Publication date: August 22, 2002Inventors: Joe D. Allison, Larry D. Swinney, Tianyan Niu, Kevin L. Ricketson, Daxiang Wang, Sriram Ramani, Gloria I. Straguzzi, David M. Minahan, Harold A. Wright, Baili Hu
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Patent number: 5112795Abstract: A process for preparing a supported silver catalyst for the production of alkylene oxide by the vapor phase oxidation of alkylene with an oxygen-containing gas is disclosed and comprises contacting a silver-contacting support with a solution comprising a metal-containing promoter other than alkali metals or alkaline earth metals. The solution is chosen so that the metal-containing promoter has an increased affinity to the silver-containing carrier relative to its affinity to the carrier without silver. Alkene epoxidation catalysts and alkene epoxidation processes are also disclosed.Type: GrantFiled: October 12, 1990Date of Patent: May 12, 1992Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: David M. Minahan, Erlind M. Thorsteinson, Albert C. Liu
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Patent number: 5051395Abstract: Catalysts for the production of alkylene oxide by the epoxidation of alkene with oxygen comprise a silver impregnated support containing a sufficient amount of scandium component to enhance at least one of activity and/or efficiency as compared to a similar catalyst which does not contain scandium component.Type: GrantFiled: September 25, 1989Date of Patent: September 24, 1991Assignee: Union Carbide Chemicals and Plastics Technology CorporationInventors: Scott F. Mitchell, David M. A. Minahan, Madan M. Bhasin