Abstract: A computer-implemented method for determining a concentration of a component of an electrolyte in a lithium-ion or for a lithium-ion cell is provided. The method includes providing, to a spectrometer, instructions to capture a spectrum of a sample solution of the electrolyte and generate a signal. The method includes analyzing the signal to determine one or more spectral features of the spectrum. The method includes preparing a database of spectra corresponding to solutions having predetermined concentrations of the component of the electrolyte wherein the database includes a plurality for spectral features for each solution. The method further includes determining a machine learning (ML) model using the database of spectra. The method includes determining the concentration of the component of the electrolyte in the sample solution using the machine learning model.

Abstract: Improved battery systems have been developed for lithium-ion based batteries. The improved systems include a nonaqueous electrolyte including one or more lithium salts, one or more nonaqueous solvents, and an additive or additive mixture comprising one or more operative additives selected from a group of disclosed compounds, including 3-aryl substituted 1,4,2-dioxazol-5-ones and 3-phenyl-1,3,2,4-dioxathiazole 2-oxide.

Abstract: Improved battery systems have been developed for lithium-ion based batteries. The improved systems include a nonaqueous electrolyte including one or more lithium salts, one or more nonaqueous solvents, and an additive or additive mixture comprising one or more operative additives selected from a group of disclosed compounds, including 3-aryl substituted 1,4,2-dioxazol-5-ones and 3-phenyl-1,3,2,4-dioxathiazole 2-oxide.

Abstract: A computer-implemented method for determining a concentration of a component of an electrolyte in a lithium-ion or for a lithium-ion cell is provided. The method includes providing, to a spectrometer, instructions to capture a spectrum of a sample solution of the electrolyte and generate a signal. The method includes analyzing the signal to determine one or more spectral features of the spectrum. The method includes preparing a database of spectra corresponding to solutions having predetermined concentrations of the component of the electrolyte wherein the database includes a plurality for spectral features for each solution. The method further includes determining a machine learning (ML) model using the database of spectra. The method includes determining the concentration of the component of the electrolyte in the sample solution using the machine learning model.