Abstract: A method of stabilizing a thermally beneficiated carbonaceous material is disclosed. The method includes the steps of supplying a charge of the carbonaceous material at an elevated temperature to a process vessel to form a packed bed and cooling the carbonaceous material to a target temperature by indirect heat exchange. The method is characterised by supplying an oxygen-containing gas to the packed bed to partially oxidise the carbonaceous material to a required degree to stabilize the carbonaceous material prior to the carbonaceous material reaching the target temperature. The method is also characterised by removing heat from the packed bed that is produced by oxidation of carbonaceous material to control the temperature of the carbonaceous material during oxidation to avoid thermal runaway.

Abstract: A method and an apparatus for upgrading a solid material is disclosed. The method comprises heating the solid material to an elevated temperature to remove water and thereafter cooling the upgraded solid material. The method includes providing a plurality of vessels containing packed beds of the solid material and one or more than one heat exchange circuit for heating and cooling the solid material in the packed beds in the vessels by heat exchange with a heat transfer fluid. The method is controlled so that the solid material in a first group of the vessels is at one or more stages of a heating cycle and the solid material in a second group of vessels is at one or more stages of a cooling cycle.

Abstract: A method and an apparatus for heating a solid material in a process vessel are disclosed. The method includes the steps of: (a) supplying a charge of the solid material to the vessel to form a packed bed; (b) supplying a fluid to the packed bed to pressurise the contents of the vessel; (c) supplying steam to the vessel to heat the solid material in the packed bed by indirect heat exchange while maintaining the contents of the vessel under pressure; and (d) controlling the operating conditions in step (c). The operating conditions in step (c) are controlled to transfer heat to the solid material and allow water in the solid material to be removed as a liquid phase in a first “wet” stage of the method and to transfer heat to the solid material to boil at least a part of the remaining water from the solid material as a vapor phase in a second “dry” stage of the method.

Abstract: A reactor (20) and a process for upgrading solid materials, such as coal, having low thermal conductivity are disclosed. The reactor includes an outer shell (10) that defines an internal volume for retaining a packed bed of solid materials to be treated and a plurality of plates (12a to 12h) of a thermally conductive material positioned within the internal volume. Each plate includes one or more passageways (14a to 14h) through which a heat transfer fluid can flow. In use, each plate defines one or more thermally conductive bypass or bypasses between the heat transfer fluid and the solid materials in the region of the plate so that in use substantially all of the solids are heated or cooled to a desired temperature range by heat exchange between the heat transfer fluid and the solids via the plates.

Abstract: A process and an apparatus for processing a charge of a solid material under conditions which include high mass flow rate of gas through the apparatus and which produce liquid from the solid material is disclosed. The apparatus includes a vessel having (i) an inlet end having an inlet for supplying the solid material to form a packed bed in the vessel; and (ii) an outlet end having at least one solids outlet, at least one liquids outlet. The apparatus is characterised by the at least one gas outlet being positioned above the solids/liquid outlets.

Abstract: A method and apparatus for heating or cooling a solid material (93) in a process vessel (80) is disclosed. The Method includes supplying a working fluid to a vessel which holds a packed bed (93) of the solid material. The method is characterised by reversing the flow of the working fluid to enhance heat transfer between a heat exchange fluid and the solid material.

Abstract: A method of treating inorganic solid waste in a bath of molten metal contained in a vessel (3) which has a space above the bath and a waste gas outlet (11) is disclosed. The method comprises injecting waste into the bath to form a primary reaction zone (13) in which there are reactions between the waste and the bath or in which the waste undergoes a change of phase to convert the waste into more readily recoverable or disposable products. The method further comprises injecting oxygen-containing gas towards the surface of the bath to form a secondary reaction zone (17) in a section above the bath through which oxidisable products released from the primary reaction zone (13) flow to reach the waste gas outlet (11) in the vessel (3) and in which the oxidisable products are oxidised and the heat released by such oxidation is transferred into the bath.