Abstract: A reactor (12) and method for the conversion of hydrocarbons utilizes a reactor (12) having a unique feed assembly (56) that creates an inwardly spiraling fluid flow pattern of the feed gases to form a swirling gas mixture that passes through a conduit (46) with a constricted neck portion or nozzle (52). At least a portion of the swirling gas mixture forms a thin, annular mixed gas flow layer immediately adjacent to the conduit (46). A portion of the swirling gas mixture is combusted as the swirling gas mixture passes through the conduit (46) for conversion of hydrocarbons.

Abstract: The invention relates to a composition containing an oxide supported oxidative coupling of methane catalyst having an excellent balance of catalytic activity and selectivity while retaining desired levels mechanical stability suitable for commercial reactor application. Particularly, the inventive catalyst is an oxide supported catalyst with the oxide catalyst support having a spherical diameter of less than 2 mm and a surface area of less than less than 9.5 m2/g while retaining a water sorption volume of at least 0.2 cc/g. The invention further provides a method for preparing such a composition containing an oxide supported catalyst, using a combination of thermal treatment of the oxide catalyst support, active component impregnation and followed up by calcination. Additionally, the invention also describes a process for producing C2+ hydrocarbons, using such a catalyst composition.

Abstract: A method for producing lower hydrocarbons by a thermal cracking reaction from mixed waste plastic (MWP) is disclosed herein. The method includes: a. forming a mixed gas comprising methane and hydrogen, b. combining the mixed gas with the MWP to form a reaction mixture, c. reacting the reaction mixture in a reactor at a pressure of 1 to 40 bars, a temperature of 800° C. to 1200° C. and a residence time of 10 to 300 milliseconds in the reactor, and d. producing a lower hydrocarbon product stream through the outlet of the reactor. The methane/hydrogen mol ratio in the mixed gas is from 0.1 to 5.

Abstract: The invention is directed to a chemical reactor (100) having (a) two or more gas reactor elements (12) with each gas reactor element (12) having (i) a first reaction chamber (38), and (ii) a feed assembly unit (36), (b) a second reaction chamber (20) coupled with each of the two or more gas reactor elements (12) and configured to independently receive two or more product streams from the two or more gas reactor elements (12); and optionally, (c) a gas converging section (40) located downstream to the second reaction chamber (20). The invention is further directed to a method of producing chemical products using the chemical reactor (100) of the present invention.

Abstract: The invention is directed to a chemical reactor (100) having (a) two or more gas reactor elements (12) with each gas reactor element (12) having (i) a first reaction chamber (38), and (ii) a feed assembly unit (36), (b) a second reaction chamber (20) coupled with each of the two or more gas reactor elements (12) and configured to independently receive two or more product streams from the two or more gas reactor elements (12); and optionally, (c) a gas converging section (40) located downstream to the second reaction chamber (20). The invention is further directed to a method of producing chemical products using the chemical reactor (100) of the present invention.

Abstract: An oxidative methane coupling (OCM) reactor has a reactor vessel that defines a reactor vessel interior. The reactor vessel having opposite ends and a central longitudinal axis that extends between the opposite ends. A catalyst bed assembly is positioned within the reactor vessel interior having a catalyst bed containing a layer of OCM catalyst of a uniform thickness. The catalyst bed assembly divides the reactor vessel interior into an upstream zone and a downstream zone. The catalyst bed has an upstream face for receiving the one or more flowing feed gases of methane and oxygen gas as a flowing mixture from the upstream zone. The upstream face of the catalyst bed is configured to have a total area that exceeds the largest transverse cross-sectional area of the interior of the reactor vessel that is perpendicular to the central longitudinal axis of the reactor vessel.

Abstract: Polymeric compositions that include a polymer matrix and a germicidal additive dispersed in the polymer matrix are described. The germicidal additive includes a metal complexed cyanurate composition having a general formula of Ax[My(C3O3N3Cl2)z], where A is a counterion, x, y, and z are each independently 1 to 6, and M is a transition metal.

Abstract: A fluid-solids contactor comprising an annular rotating fluidized bed and a method of using the same are disclosed. The fluid-solids contactor includes a vessel and a plurality feed inlets disposed thereon. The vessel comprises a stationary inner wall, an outer wall, and a chamber formed between the stationary inner wall and the outer wall. The feed inlets are configured to create an annular rotating bed with mixture of solids and a fluid when the solid particles and a fluid are fed into the chamber. The stationary inner wall of the vessel is permeable to the fluid such that the fluid from the chamber can be continuously withdrawn from the solids to the space within the stationary inner wall of the vessel.

Abstract: Disclosed is a method of preparing a polymer composite component, wherein the method comprises uniformly dispersing glycerol and metal ions on a polymer powder to create a polymer composite powder, extruding the polymer composite powder at a temperature of at least 80° C., thereby converting a portion of the metal ions to metal atoms, and then forming the component from the extruded polymer composite. The component can be a thin film, to be applies to surfaces to increase antimicrobial properties.

Abstract: A catalyst composition, suitable for producing ethylene and other C2+ hydrocarbons, from methane. The composition comprises a blended product of two distinct catalyst components, blended at such synergistic proportions that results in a catalyst having high ethylene selectivity while maintaining low ethyne selectivity and sufficient catalytic activity rate. The invention further provides a method for preparing such a catalyst composition and a process for producing ethylene and other C2+ hydrocarbons, using such a catalyst composition.

Abstract: The invention relates to a composition containing a catalyst having high catalytic stability for conducting oxidative coupling of methane (OCM) at high carbon efficiency, while improving both methane and oxygen conversion. Particularly, the inventive catalyst is a metal oxide supported catalyst, which contains an alkali metal promoter and a mixed metal oxide component having at least one alkali earth metal and at least one rare earth metal. The metal oxide support is selected in a manner, such that at least a portion of the metal oxide support is capable of reacting with at least a part or whole of the alkali metal promoter under conditions of calcination during catalyst preparation. The invention further provides a method for preparing such a metal oxide supported catalyst composition, using a calcination process. Additionally, the invention further describes a process for producing C2+ hydrocarbons, using such a catalyst composition.

Abstract: The invention relates to a reactor system for oxidative coupling of methane (OCM), comprising: reactor system for oxidative coupling of methane (OCM), comprising: (a) an inlet configured to receive a reactant mixture; (b) a reaction chamber having an upstream end and a downstream end such that the reaction chamber extends from the upstream end to the downstream end, and the reaction chamber comprises a catalyst bed having a catalyst composition having at least two catalyst components: (i) a low selectivity catalyst component; and (ii) a high selectivity catalyst component; and (c) an outlet configured to recover a C2+ hydrocarbon product mixture from the reactor system; wherein the reactor system is configured such that the reactant mixture substantially contacts the high selectivity catalyst component prior to contacting the low selectivity catalyst component. The invention further describes a process for the production of C2+ hydrocarbon product mixture using the present reactor system.

Abstract: A reactor (12) and method for the conversion of hydrocarbons utilizes a reactor (12) having a unique feed assembly (56) that creates an inwardly spiraling fluid flow pattern of the feed gases to form a swirling gas mixture that passes through a conduit (46) with a constricted neck portion or nozzle (52). At least a portion of the swirling gas mixture forms a thin, annular mixed gas flow layer immediately adjacent to the conduit (46). A portion of the swirling gas mixture is combusted as the swirling gas mixture passes through the conduit (46) for conversion of hydrocarbons.

Abstract: A pyrolysis reactor (12) and method for the pyrolysis of hydrocarbon gases (e.g., methane) utilizes a pyrolysis reactor (12) having a unique burner assembly (44) and pyrolysis feed assembly (56) that creates an inwardly spiraling fluid flow pattern of the feed gases to form a swirling gas mixture that passes through a burner conduit (46) with a constricted neck portion or nozzle (52). At least a portion of the swirling gas mixture forms a thin, annular mixed gas flow layer immediately adjacent to the burner conduit (46). A portion of the swirling gas mixture is combusted as the swirling gas mixture passes through the burner conduit (46) and a portion of combustion products circulates in the burner assembly (44). This provides conditions suitable for pyrolysis of hydrocarbons or light alkane gas, such as methane or natural gas.

Abstract: The invention relates to a reactor system for oxidative coupling of methane (OCM), comprising: reactor system for oxidative coupling of methane (OCM), comprising: (a) an inlet configured to receive a reactant mixture; (b) a reaction chamber having an upstream end and a downstream end such that the reaction chamber extends from the upstream end to the downstream end, and the reaction chamber comprises a catalyst bed having a catalyst composition having at least two catalyst components: (i) a low selectivity catalyst component; and (ii) a high selectivity catalyst component; and (c) an outlet configured to recover a C2+ hydrocarbon product mixture from the reactor system; wherein the reactor system is configured such that the reactant mixture substantially contacts the high selectivity catalyst component prior to contacting the low selectivity catalyst component. The invention further describes a process for the production of C2+ hydrocarbon product mixture using the present reactor system.

Abstract: A multilayer supported oxidative coupling of methane (OCM) catalyst composition (alpha-Al2O3 support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/alpha-Al2O3; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts alpha-Al2O3 support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.

Abstract: The invention is directed to a chemical reactor (100) having (a) two or more gas reactor elements (12) with each gas reactor element (12) having (i) a first reaction chamber (38), and (ii) a feed assembly unit (36), (b) a second reaction chamber (20) coupled with each of the two or more gas reactor elements (12) and configured to independently receive two or more product streams from the two or more gas reactor elements (12); and optionally, (c) a gas converging section (40) located downstream to the second reaction chamber (20). The invention is further directed to a method of producing chemical products using the chemical reactor (100) of the present invention.

Abstract: A reactor and method for the conversion of hydrocarbon gases utilizes a reactor (12, 312, 412, 512, 612, 712) having a unique feed assembly with an original vortex combustion chamber (40, 340, 436, 536, 636, 736), a diverging conduit (48, 348, 448, 548, 648, 748), and a cylindrical reactor chamber (40, 340, 436, 536, 636, 736). This design creates a compact combustion zone and an inwardly swirling fluid flow pattern of the feed gases to form a swirling gas mixture that passes through a diverging conduit (48, 348, 448, 548, 648, 748). The feed streams can be introduced into the reactor at any angle (perpendicular, axial, or something between, or a combination of the above forms) with swirling flow components. This provides conditions suitable for efficient cracking of hydrocarbons, such as ethane, to form olefins.

Abstract: The invention is directed to a chemical reactor (100) having (a) two or more gas reactor elements (12) with each gas reactor element (12) having (i) a first reaction chamber (38), and (ii) a feed assembly unit (36), (b) a second reaction chamber (20) coupled with each of the two or more gas reactor elements (12) and configured to independently receive two or more product streams from the two or more gas reactor elements (12); and optionally, (c) a gas converging section (40) located downstream to the second reaction chamber (20). The invention is further directed to a method of producing chemical products using the chemical reactor (100) of the present invention.