Abstract: A ferrite layer formation process that may be performed at a lower temperature than conventional ferrite formation processes. The formation process may produce highly anisotropic structures. A ferrite layer is deposited on a substrate while the substrate is exposed to a magnetic field. An intermediate layer may be positioned between the substrate and the ferrite to promote bonding of the ferrite to the substrate. The process may be performed at temperatures less than 300° C. Ferrite film anisotropy may be achieved by embodiments of the invention in the range of about 1000 dyn-cm/cm3 to about 2×106 dyn-cm/cm3.

Abstract: A silica sol-gel fabrication process is provided which allows improved control of the shrinkage that takes place during the drying of a gel body. In particular, the invention makes it possible to attain extremely low shrinkage through the completion of the drying stage, e.g., below 1% linear shrinkage, in relatively large sol-gel bodies of (dry weight) 1 kg or more, typically 10 kg or more, or even 40 kg or more, compared to the much higher shrinkages typically encountered. Specifically, use of a particular polymeric additive makes it possible for a gel body to experience linear shrinkage at least 55% less than an identical process without the polymeric additive.

Abstract: A silica-water dispersion suitable for use as a sol for sol-gel fabrication is produced from a silica-water mixture with addition of alkaline agent. The agent functions to increase viscosity so as to improve dispersing efficiency during shear mixing.

Abstract: Silica sols exhibiting desirable yield-dilatancy are fabricated. A mixture comprising silica, water, and a pH-adjusting agent is provided, and the mixture is shear-mixed. The desirable properties of the resultant sol are attained by using a concentration of pH-adjusting agent that provides a viscosity within a particular range during shear mixing. The requisite pH range, however, changes depending on the properties of the silica mixture. A discovered technique for determining this changing pH range is by selecting the pH based on the silica surface area per unit volume of the mixture.

Abstract: The invention provides a device comprising an oriented, perovskite PZT layer on a diamond substrate, or other substrates such as silicon or platinum-coated materials. Vapor phase deposition processes are used to deposit a PZT layer onto a perovskite template layer on the substrate. The template layer is more readily deposited in a perovskite structure compared to PZT, and provides for nucleation and growth of the deposited PZT in perovskite form. The vapor phase deposition promotes the oriented structure of the resulting film. The structure is useful in a variety of devices, including surface acoustic wave devices.

Abstract: The invention provides an improved process for fabricating devices containing metallized magnetic ceramic material, such as inductors, transformers, and magnetic substrates. In particular, the unique vias utilized in the process of the invention allow fabrication of devices from multiple unfired ferrite layers with only a single via-coating step, thereby avoiding the need numerous punching steps. Moreover, there is no need for expanding the dimensions of the vias and thus no need for internal metallization. The invention therefore provides for green tape-type fabrication of devices such as inductors, transformers, and magnetic substrates in a manner faster, less complex, and more reliable than current methods. The invention also relates to use of an improved conductive material in such a process, the conductive material containing silver/palladium particles, ferrite particles, a cellulose-based or other organic binder, and a solvent.

Abstract: The invention is a sol-gel extrusion process which allows fabrication of both thick and thin wall tubes. For example, the process is capable of preparing silica overcladding tubes in a manner easier than sol-gel casting processes, and also capable of preparing relatively thin substrate tubes, which are difficult to cast. According to the invention, a silica dispersion containing a stabilizing agent is provided, a gelling agent is added to the dispersion to induce gellation, and the resultant gel is extruded into a silica body, in the substantial absence of polymeric material from the gel. Substantially avoiding the inclusion of such polymeric material in overcladding and substrate tubes offers significant commercial advantages by reducing the time and energy required to remove organic materials from the tube bodies, by reducing environmental impact, and by reducing the amount of impurities introduced in the tubes.

Abstract: The invention provides an improved process for fabricating devices containing metallized magnetic ceramic material, such as inductors, transformers, and magnetic substrates. In particular, the unique vias utilized in the process of the invention allow fabrication of devices from multiple unfired ferrite layers with only a single via-coating step, thereby avoiding the need numerous punching steps. Moreover, there is no need for expanding the dimensions of the vias and thus no need for internal metallization. The invention therefore provides for green tape-type fabrication of devices such as inductors, transformers, and magnetic substrates in a manner faster, less complex, and more reliable than current methods. The invention also relates to use of an improved conductive material in such a process, the conductive material containing silver/palladium particles, ferrite particles, a cellulose-based or other organic binder, and a solvent.

Abstract: A tunable fiber grating comprises a temperature-sensitive body secured to a fiber having a fiber grating region for transmitting thermally-induced strain to the grating. The amount of strain and hence the degree of wavelength tuning are controlled by adjusting the temperature of the temperature-sensitive body, wherein the extent of adjustment is preferably pre-determined according to feedback from a wavelength detector. Large thermal strains obtainable with the present invention allow a wide range of wavelength tuning with a relatively small and convenient temperature change near ambient temperature. In a preferred embodiment, the temperature-sensitive body is cylindrical and comprised of a nickel-titanium alloy bonded to the grating. In alternative arrangements, the thermal strain effect can be amplified. An add/drop multiplexer employing the tunable gratings is also described.

Abstract: A method for forming a dielectric oxide layer on selected areas of a substrate is disclosed. The dielectric oxide layer is formed on selected areas of the substrate using a sol process. The substrate has an area of a first material and an area of a second material which is different from the first. The first material is coated with a layer of a first compound. The layer of the first compound has a hydrophobic top surface. The second material is coated with a layer of a second compound. The layer of the second compound has a hydrophilic top surface. A layer of hydrous oxide is formed over the second compound by applying an aqueous sol solution on the surface of the substrate. The substrate is then heated to remove the first compound and the second compound from the surface of the substrate. Thereafter, the substrate with the layer of hydrous oxide thereon, is sintered to form the dielectric oxide layer.

Abstract: Cracking in thin sheets of sol-gel-produced material is avoided by use of a support liquid during gelation and drying. Silica glass, as well as other glass and ceramic bodies, is contemplated.

Abstract: An inductor (100) optimized for surface-mount vacuum-pickup automated circuit assembly eliminates the expense of an inductor housing. The inductor has a hollow rectangular ferrite core (101) and a winding defined by a stripline (102) deposited on the core surface. Winding ends are formed by conductive vias (103) in the core that open onto the core surface, where they connect and mount the inductor to a circuit board (150). A flat sheet (104) adhered to one face of the core provides a surface for vacuum pickup and for labeling of the inductor. The core of a passively tuneable inductor (200) defines multiple unconnected winding segments (102-103). Segment ends mount the inductor to the circuit board and connect the segments to circuit board striplines (254) that are laid out in a pattern to interconnect a number of the segments into a winding. The inductor is tuned by changing the stripline layout and thereby varying the number of interconnected segments.

Abstract: A transformer (FIG. 1) optimized for surface-mount vacuum-pickup automated circuit assembly eliminates the expense of a transformer housing. The transformer has a ferrite body (100) that defines a pair of wells (208, 209) each opening onto an opposite face (108, 109) of the ferrite body. Transformer primary and secondary windings are wound in a coil (103) through slots (210, 211) around a transformer core (204) at the bottom of the wells. The windings do not protrude from the wells beyond the faces, resulting in flat faces. A first plurality of conductive vias (104-106), one pair for each winding, are completely embedded in the ferrite body and extend to both of the faces. Each pair of vias serves at one face to attach to the winding and at the other face to attach to solder pods of a PC board. The embedded vias also serve as EMI filters. A plate (107) covers the one face and provides a surface for vacuum pickup and for labeling of the transformer. The ferrite body (500) of a first transformer (FIG.

Abstract: The method of making a metallized magnetic substrate for devices including a magnetic component involves providing an unfired ceramic body. In one exemplary embodiment, the method further involves making one or more vias through the ceramic body, coating the via side walls with conductive material, forming an aperture through the ceramic body, such that an aperture edge intersects the via, and metallizing the unfired ceramic body such that a conductive pathway is formed that includes the conductive material in the via. Finally, the metallized unfired ceramic body is fired in conventional fashion, optionally followed by deposition of additional conductor material.

Abstract: The present invention provides improved techniques for metallizing ceramic substrates. The method comprises providing a ceramic substrate and depositing a layer of reducible material on the ceramic substrate. The layer of reducible material includes a reducible ceramic such as copper oxide. The ceramic substrate having the layer of reducible material disposed thereon is heated and the reducible material is contacted with a reducing agent to create a conductive region. The conductive region is either a metallized region formed by reduction, or it is a conductive ceramic formed through surface reduction. The present invention further provides a metallized ceramic substrate. The metallized layer comprises ceramic regions having at least one constituent in common with the ceramic substrate. The ceramic substrate and the ceramic regions of the metallized layer are sintered to each other such that the metallized region is interspersed between the sintered ceramic regions.

Abstract: Conventional optical gratings are relatively temperature sensitive. This sensitivity is generally undesirable but can be reduced or eliminated by attaching the grating to a support member having a negative coefficient of thermal expansion. Exemplarily the member comprises Zr-tungstate and/or Hf-tungstate. The thermal expansion can be tailored by admixture of positive expansion coefficient material (e.g., Al.sub.2 O.sub.3, SiO.sub.2) to the negative expansion coefficient material (e.g., ZrW.sub.2 O.sub.8), or by a variety of other techniques.