Abstract: Homogeneously dispersed solid reaction promoters having an average particle size from 0.01 ?m to 500 ?m are disclosed for preparing curable mixtures of at least one Michael donor and at least one Michael acceptor. The resulting curable mixtures are useful as coatings, adhesives, sealants and elastomers.

Abstract: Homogeneously dispersed solid reaction promoters having an average particle size from 0.01 ?m to 500 ?m are disclosed for preparing curable mixtures of at least one Michael donor and at least one Michael acceptor. The resulting curable mixtures are useful as coatings, adhesives, sealants and elastomers.

Abstract: Functional mixtures and polymer compositions are provided, each comprising at least one multi-functional Michael acceptor, at least one multi-functional Michael donor, in which at least 20% of either the donor or acceptor or a combination of the donor and acceptor is derived from bio-based materials and at least one catalyst.

Abstract: A functional mixture is provided that comprises at least one multi-functional Michael acceptor, at least one multi-functional Michael donor, and at least one weakly basic catalyst.

Abstract: A method is provided for bonding substrates using a homogeneous fluid and a polymerizing condition. Also provided are composite articles formed by such a method. The composite articles show improved adhesion between the substrates and the adhesive composition over a wide range of temperatures.

Abstract: Provided are improved coatings, polymeric dispersions, and polymeric composites, which include crosslinked polymeric nanoparticles (hereafter “PNPs”). Also provided are methods for forming improved coatings, polymeric dispersions, and polymeric composites, which include PNPs. The PNPs have polymerized units of at least one multi-ethylenically-unsaturated monomer have a mean diameter of from 1 to 50 nanometers. PNPs having polymerized units of at least one multi-ethylenically-unsaturated monomer and at least one surface-active monomer are also provided.

Abstract: A method of preparing a cured laminate employing electron beam radiation is provided. The cured laminate is prepared from an uncured laminate including a prepolymer composition containing oligomer, tackifying resin, and optionally, monomer. Also provided are a prepolymer composition and an article including the cured laminate prepared by the method of this invention. The method is useful for preparing cured laminates such as flexible laminates for food packaging.

Abstract: An extended release dosage form and an extended release polymeric dispenser containing polymer-clay nanocomposite are provided. The polymer-clay nanocomposite contains exfoliated clay platelets dispersed in a polymer matrix. The extended release dosage form contains active ingredient in the polymer-clay nanocomposite. The extended release polymeric dispenser contains a reservoir of an active ingredient partially or completely encapsulated by a polymer-clay nanocomposite layer. Also provided are a method of providing release of an active ingredient from the extended release dosage form and a method or providing release of an active ingredient from the extended release polymeric dispenser. The extended release dosage form and the extended release polymeric dispenser are useful for the application of pharmaceutical compounds, agricultural compounds, and perfumes.

Abstract: A curable composition containing at least one ethylenically unsaturated compound and at least one liquid elastomer is provided. The curable composition is useful for preparing a cold seal adhesive. A method is provided for preparing the cold seal adhesive, which includes the use of electron beam radiation to initiate polymerization of the curable composition.

Abstract: Curable clay compositions containing at least one ethylenically unsaturated compound and exfoliated clay platelets are provided. The curable clay compositions are useful for preparing articles having improved barrier properties to oxygen, moisture, or odor such as flexible laminates. Methods including polymerization of the curable clay composition using electron beam radiation are provided and are suitable for preparing laminates or coatings with improved barrier properties. Also provided is a method for preparing the curable clay composition using a moving media mill.

Abstract: A method is provided for bonding substrates using a homogeneous fluid and a polymerizing condition. Also provided are composite articles formed by such a method. The composite articles show improved adhesion between the substrates and the adhesive composition over a wide range of temperatures.

Abstract: Provided is a curable fluid with relatively low viscosity capable of forming a polymeric composition, subsequent to exposure to cure conditions. Also provided are coated articles made of substrates coated by such compositions, and further provided are composite articles made of substrates bonded by such compositions; further provided are methods of making such coated and composite articles.

Abstract: A method of preparing a curable coating and a method of curing the curable coating are disclosed. The curable composition from which the curable coating is prepared may be applied to the surface of a substrate in neat form or in aqueous medium to produce the coating. Curing of the curable coating may be accomplished by chemical generation of free radicals, by electrochemical generation of free radicals, by electron beam, by photochemical generation of free radicals, or by other electromagnetic irradiation.

Abstract: A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: (1) forming a reaction mixture, substantially free of carboxylic acid-containing monomers and their salts, containing: (i) 0.5 to 99.95% by weight of the reaction mixture of at least one ethylenically unsaturated monomer; and (ii) 0.05 to 25% by weight, based on the weight of the ethylenically unsaturated monomer, of at least one free-radical initiator; and (2) continuously passing the reaction mixture through a heated zone wherein the reaction mixture is maintained at a temperature of at least 150° C. and a pressure of at least 30 bars for from 0.1 seconds to 4 minutes to form terminally-unsaturated oligomers. In addition, processes for forming oligomers of vinyl acetate and oligomers of vinyl alcohol are disclosed. Mixtures of fully saturated and terminally unsaturated oligomers are also disclosed.

Abstract: A method of preparing a curable coating and a method of curing the curable coating are disclosed. The curable composition from which the curable coating is prepared may be applied to the surface of a substrate in neat form or in aqueous medium to produce the coating. Curing of the curable coating may be accomplished by chemical generation of free radicals, by electrochemical generation of free radicals, by electron beam, by photochemical generation of free radicals, or by other electromagnetic irradiation.

Abstract: A method of preparing a cured laminate employing electron beam radiation is provided. The cured laminate is prepared from an uncured laminate including a prepolymer composition containing oligomer, tackifying resin, and optionally, monomer. Also provided are a prepolymer composition and an article including the cured laminate prepared by the method of this invention. The method is useful for preparing cured laminates such as flexible laminates for food packaging.

Abstract: Provided are improved coatings, polymeric dispersions, and polymeric composites, which include PNPs. Also provided are methods for forming improved coatings, polymeric dispersions, and polymeric composites, which include PNPs. The PNPs have polymerized units of at least one multi-ethylenically-unsaturated monomer have a mean diameter of from 1 to 50 nanometers. PNPs having polymerized units of at least one multi-ethylenically-unsaturated monomer and at least one surface-active monomer are also provided.

Abstract: The present invention relates to an oligomer with a semi-telechelic nitrogen-functionality and at least one ethylenic unsaturation pendant to the backbone of the oligomer. In addition, a process is provided to prepare the semi-telechelic nitrogen-functional oligomer. The semi-telechelic nitrogen-functional oligomer is useful as a dispersant for pigments in radiation curable formulations.

Abstract: A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of:

Abstract: A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: