Abstract: A balloon formed from a lamination. The lamination includes a first layer, a second layer, a graphic design and a third layer. The first layer including from about 10 to about 90 wt. % crystalline polyester and from about 10 to about 90 wt. % of a formability enhancer to assist in increasing the polymeric chain flexibility. The formability enhancer has a melting point less than about 230° C. The first layer has a MD and a TD Young's Modulus of at least 10% lower than a crystalline polyester film in the absence of the formability enhancer. The second layer is a metallic barrier layer. The graphic design is printed onto a surface of the metallic barrier layer. The third layer is a sealant layer. The first layer is located between the second and third layers. The balloon contains a gas lighter than air.

Abstract: A balloon formed from a lamination. The lamination includes a first layer, a second layer, a graphic design and a third layer. The first layer including from about 10 to about 90 wt. % crystalline polyester and from about 10 to about 90 wt. % of a formability enhancer to assist in increasing the polymeric chain flexibility. The formability enhancer has a melting point less than about 230° C. The first layer has a MD and a TD Young's Modulus of at least 10% lower than a crystalline polyester film in the absence of the formability enhancer. The second layer is a metallic barrier layer. The graphic design is printed onto a surface of the metallic barrier layer. The third layer is a sealant layer. The first layer is located between the second and third layers. The balloon contains a gas lighter than air.

Abstract: Described are stretchable and formable lighter than air balloons including a high barrier lamination. The stretchable and formable balloons stretch when overinflated instead of failing. The balloons are formed from a lamination including a polyester film with a total thickness of 4 ?m to 12 ?m including a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The polyester film has an Elongation % in the transverse direction (TD) or machine direction (MD) of greater than 125%.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.

Abstract: The present invention relates to articles and methods for producing non-latex balloons with low surface electrical conductivities and an extended product life. In a preferred embodiment, a multilayer composite film having an exposed metalized layer is coated with an elastomeric sealant layer that increases electrical resistivity of the balloon product to greater than 1.08 Ohms/sq. The invention relates to articles and methods for producing needed bonds and seal strength required to manufacture non latex balloons. The balloons of this invention have an extended product life because they are more resistant to common defects like pin holing and stress cracks than conventional balloon systems.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.

Abstract: The present invention relates to articles and methods for producing non-latex balloons with low surface electrical conductivities and an extended product life. In a preferred embodiment, a multilayer composite film having an exposed metallized layer is coated with an elastomeric sealant layer that increases electrical resistivity of the balloon product to greater than 1.08 Ohms/sq. The invention relates to articles and methods for producing needed bonds and seal strength required to manufacture non latex balloons. The balloons of this invention have an extended product life because they are more resistant to common defects like pin holing and stress cracks than conventional balloon systems.

Abstract: The present invention relates to articles and methods for producing non-latex balloons with low surface electrical conductivities and an extended product life. In a preferred embodiment, a multilayer composite film having an exposed metallized layer is coated with an elastomeric sealant layer that increases electrical resistivity of the balloon product to greater than 1.08 Ohms/sq. The invention relates to articles and methods for producing needed bonds and seal strength required to manufacture non latex balloons. The balloons of this invention have an extended product life because they are more resistant to common defects like pin holing and stress cracks than conventional balloon systems.

Abstract: The present invention relates to articles and methods for producing non-latex balloons with low surface electrical conductivities and an extended product life. In a preferred embodiment, a multilayer composite film having an exposed metallized layer is coated with an elastomeric sealant layer that increases electrical resistivity of the balloon product to greater than 1.08 Ohms/sq. The invention relates to articles and methods for producing needed bonds and seal strength required to manufacture non latex balloons. The balloons of this invention have an extended product life because they are more resistant to common defects like pin holing and stress cracks than conventional balloon systems.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.