Patents by Inventor Dean Thetford

Dean Thetford has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6723782
    Abstract: A dispersant which is a phosphate ester of a polymer which contains at least one ether group and a poly(oxyalkylenecarbonyl) chain (POAC chain) derivable from two or more different hydroxycarboxyl acids or lactones thereof. Also disclosed is the use of the dispersants in paints and printing inks including millbases. The preferred dispersants are phosphate esters of an alkyl end-capped poly(oxyalkylenecarbonyl) chain alcohol where the POAC chain is derived from &egr;-caprolactone and &dgr;-valerolactone and the alkyl group is derived from a monohydroxypolyalkyleneglycol.
    Type: Grant
    Filed: April 1, 2003
    Date of Patent: April 20, 2004
    Assignee: Avecia Limited
    Inventor: Dean Thetford
  • Publication number: 20040007153
    Abstract: A polymer comprising the addition reaction product of a polyisocyanate having a functionality of from 2 to 10 and a succinylpolyether having a C6-30-alk(en)yl group and at least one group which is capable of reacting with the polyisocyanate and where the number of recurring ethyleneoxy groups in the polyether is from 4 to 800
    Type: Application
    Filed: April 2, 2003
    Publication date: January 15, 2004
    Inventors: Dean Thetford, Stuart Barnett
  • Publication number: 20030204012
    Abstract: A dispersant which is a phosphate ester of a polymer which contains at least one ether group and a poly(oxyalkylenecarbonyl) chain (POAC chain) derivable from two or more different hydroxycarboxyl acids or lactones thereof. Also disclosed is the use of the dispersants in paints and printing inks including millbases. The preferred dispersants are phosphate esters of an alkyl end-capped poly(oxyalkylenecarbonyl) chain alcohol where the POAC chain is derived from &egr;-caprolactone and &dgr;-valerolactone and the alkyl group is derived from a monohydroxypolyalkyleneglycol.
    Type: Application
    Filed: April 1, 2003
    Publication date: October 30, 2003
    Applicant: Avecia Limited of Blackley
    Inventor: Dean Thetford
  • Publication number: 20030181544
    Abstract: Basic and acid dispersants derived from branched alkyl aliphatic acids and alcohols and one or more hydroxy carboxylic acid or lactone to give a polyoxyalkylenecarbonyl chain (POAC) having a terminal carboxylic acid group (TPOAC acid) or terminal hydroxy group (TPOAC alcohol). Preferred basic dispersants are obtained by reaching one or more TPOAC acids with a polyamine or polyimine such as polyethyleneimine and preferred anionic dispersants are prepared by forming a phosphate ester of a TPOAC alcohol.
    Type: Application
    Filed: February 6, 2003
    Publication date: September 25, 2003
    Inventors: Dean Thetford, Patrick John Sunderland, Tom Annable
  • Publication number: 20030172844
    Abstract: A dispersion comprising a particulate solid, a polar organic liquid and a dispersant of formula (1) wherein R is optionally substituted C4-50-hydrocarbyl; X is —O—, —S— or —NR2—; R1 is hydrogen or C1-6, -alkyl which may be linear or branched; R2 is hydrogen or C1-6, alkyl which may be linear or branched or a group —(C2H4O)n(AO)p—R1; AO is alkyleneoxy containing 3 or more carbon atoms; n is 0 to 30; p is 4 to 100; and p>n; and a is from 1 to 3. Preferred compounds are where R1 is hydrogen, X is —O— and a is 1 and R is the residue of 2-naphthol.
    Type: Application
    Filed: February 13, 2003
    Publication date: September 18, 2003
    Inventor: Dean Thetford
  • Publication number: 20030171485
    Abstract: The use of an amine functional polymer, including salts thereof, as a rheology modifier for solvent-based paints, inks, filled thermosetting resins and thermosetting resin-based gelcoats whereby the amine functional polymer contains not less that 42% by weight of the residue of one or more amine-containing monomers, or salts thereof, relative to the weight of the polymer. Preferably the amine functional polymer is obtainable from two or more monomers which contain at least one ethylenically unsaturated group such as styrene and 2-dimethylaminoethylmethacrylate.
    Type: Application
    Filed: December 5, 2002
    Publication date: September 11, 2003
    Inventors: David John Catridge, Dean Thetford, John David Schofield, Paul Gough, Stuart Nicholas Richards
  • Patent number: 6599947
    Abstract: A dispersant of formula 1 wherein R is hydrogen or a polymerisation termination group; Z is an acidic or basic group or a moiety containing either an acidic or basic group; A is C3-7alkylene optionally substituted by alkyl; Gly is oxymethylenecarbonyl; n and m are integers; and n+m is from 2 to 100. The dispersants are used to disperse particulate solids such as pigments in paints and inks. Examples of the dispersants include mixed polyester chains derived from &egr;-caprolactone and/or &dgr;-valerolactone with glycolic acid where the mixed polyester chain is reacted with either a polyalkyleneimine or with a phosphating agent.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: July 29, 2003
    Assignee: Avecia Limited
    Inventor: Dean Thetford
  • Patent number: 6583213
    Abstract: An amine dispersant containing one or more amino and/or imino groups, a poly(oxy-C1-6-alkylene carbonyl) chain (POAC chain) obtainable from two or more different linear hydroxycarboxylic acids or lactones thereof and a residue of an ethylenically unsaturated group wherein the amino and/or imino groups are attached via the ethylenically unsaturated group. The POAC chain may be made from 2-hydroxyethylacrylate, &egr;-caprolactone and &dgr;-valerolactone and the amine and/or imino groups may be provided by polyethyleneimine.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: June 24, 2003
    Assignee: Avecia Limited
    Inventors: David Melville Fawkes, Dean Thetford
  • Patent number: 6562897
    Abstract: A dispersant which is a phosphate ester of a polymer which contains at least one ether group and a poly(oxyalkylenecarbonyl) chain (POAC chain) derivable from two or more different hydroxycarboxyl acids or lactones thereof. Also disclosed is the use of the dispersants in paints and printing inks including millbases. The preferred dispersants are phosphate esters of an alkyl end-capped poly(oxyalkylenecarbonyl) chain alcohol where the POAC chain is derived from &egr;-caprolactone and &dgr;-valerolactone and the alkyl group is derived from a monohydroxypolyalkyleneglycol.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: May 13, 2003
    Assignee: Avecia Limited
    Inventor: Dean Thetford
  • Publication number: 20030027873
    Abstract: A dispersant of formula 1 1
    Type: Application
    Filed: September 28, 2000
    Publication date: February 6, 2003
    Inventor: Dean Thetford
  • Patent number: 6509409
    Abstract: A dispersant comprising the addition product of a polyisocyanate having an average functionality of from 2 to 10 and one or more poly(oxyalkylene carbonyl) chains (POAC chain) such as those containing a POAC chain derived from &egr;-caprolactone and &dgr;-valerolactone. The dispersants are used to disperse pigments in paints and printing inks.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: January 21, 2003
    Assignee: Avecia Limited
    Inventor: Dean Thetford
  • Patent number: 6197877
    Abstract: A dispersant of general Formula I T—(A)n(B)p—Z   (1) wherein T is hydrogen or a polymerisation terminating group; Z is an acidic or basic group or a moiety containing either an acidic or basic group; A and B are each, independently, oxyalkylene carbonyl groups derivable from &dgr;-valerolactone, &egr;-caprolactone or alkyl substituted &egr;-caprolactone provided that both are not &egr;-caprolactone or &dgr;-valerolactone; n and p are integers; and n+p is from 2 to 100; including salts thereof. Specific examples of dispersants are the reaction product of lauric acid, &dgr;-caprolactone, 7-methyl-&egr;-caprolactone with PEI, the reaction product of lauric acid, &egr;-caprolactone, &dgr;-valerolactone with PEI and the phosphate of the reaction product of dodecanol, &egr;-caprolactone and &dgr;-valerolactone.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: March 6, 2001
    Assignee: Zeneca Limited
    Inventors: Dean Thetford, John David Schofield, Patrick John Sunderland
  • Patent number: 6191253
    Abstract: A dispersant for aqueous mill-bases obtainable by reacting a polyethylene glycol with a molar excess of a hydroxycarboxylic acid containing from 4 to 17 carbon atoms or lactone thereof and/or with a C3-4-alkylene oxide to form a polymeric diol and phosphating the diol. The preferred hydroxycarboxylic acid or lactone is &egr;-caprolactone.
    Type: Grant
    Filed: June 9, 1998
    Date of Patent: February 20, 2001
    Assignee: Zeneca Limited
    Inventors: John David Schofield, Dean Thetford
  • Patent number: 6133366
    Abstract: A dispersant which is a phosphate ester of a block copolymer of formula MeO(C.sub.2 H.sub.4 O).sub.m (PES).sub.n --H wherein PES is derived from .epsilon.-caprolactone, m is 5-60, n is 2-30 and the MW of MeO(C.sub.2 H.sub.4 O).sub.m is greater than the MW of (PES).sub.n and use in aqueous-based paints and printing inks.
    Type: Grant
    Filed: June 1, 1998
    Date of Patent: October 17, 2000
    Assignee: Zeneca Limited
    Inventors: Dean Thetford, Mark Holbrook
  • Patent number: 6069210
    Abstract: A composition comprising a particulate solid and a dispersant which is a phosphate ester of a compound of formula 1: ##STR1## wherein Y is methoxy or H--(EO).sub.q, m and q are each independently from 5 to 50 and n is from 5 to 70. When Y is a methoxy, n is preferably 20 and m is preferably 10. When Y is H--(EO).sub.q, m and q are preferably 13 and n is preferably 30.
    Type: Grant
    Filed: November 4, 1998
    Date of Patent: May 30, 2000
    Assignee: Zeneca Limited
    Inventors: David John Cartridge, Dean Thetford
  • Patent number: 6051627
    Abstract: A dispersant which is a phosphate ester of a polyalkylene ether block copolymer of formula MeO(C.sub.2 H.sub.4 O).sub.m (C.sub.3 H.sub.6 O).sub.n --H wherein m and n are each, independently, 2 to 60 and use in aqueous based paints and printing inks.
    Type: Grant
    Filed: June 1, 1998
    Date of Patent: April 18, 2000
    Assignee: Zeneca Limited
    Inventors: Dean Thetford, Mark Holbrook
  • Patent number: 5981624
    Abstract: A reduced shade paint or ink comprising(a) a base paint or ink comprising a base pigment such as titanium dioxide, a film-forming resin and a non-polar liquid such as white spirits;(b) one or more dispersant which is a phosphate ester of a compound of formula 1 ##STR1## wherein Y is a group RO-- or a group H--(EO).sub.q --;R is C.sub.1-10 -alkyl;m and q are each, independently, from 5 to 50;n is from 5 to 70; and(c) a tinter composition comprising a colored pigment, water and/or a water-miscible solvent such as ethyleneglycol.
    Type: Grant
    Filed: November 4, 1997
    Date of Patent: November 9, 1999
    Inventors: Dean Thetford, David J. Cartridge
  • Patent number: 5847114
    Abstract: The use of substituted phthalocyanines for the generation of singlet oxygen in which at least one of the peripheral carbon atoms in the 1-16 positions of the phthalocyanine nucleus (M.sub.k Pc) of Formula (1): ##STR1## wherein: M is selected from H, metal, halometal, oxymetal and hydroxymetal; andk is the inverse of 1/2 of the valency of M; is linked via an oxygen atom to an aromatic radical and the remaining peripheral carbon atoms are unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof provided that the phthalocyanine absorbs electromagnetic radiation at a wavelength from 650 nm to 800 nm.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: December 8, 1998
    Assignee: Zeneca Limited
    Inventors: Dean Thetford, Peter Gregory
  • Patent number: 5785894
    Abstract: A dispersant for aqueous mill-bases obtainable by reacting a polyethylene glycol with a molar excess of a hydroxycarboxylic acid containing from 4 to 17 carbon atoms or lactone thereof and/or with a C.sub.3-4 -alkylene oxide to form a polymeric diol and phosphating the diol. The preferred hydroxycarboxylic acid or lactone is .epsilon.-caprolactone.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: July 28, 1998
    Assignee: Zeneca Limited
    Inventors: John David Schofield, Dean Thetford
  • Patent number: 5753022
    Abstract: A method of preparing a non-aqueous dispersion of CuPc which comprises milling crude CuPc in a high boiling liquid at a temperature from 50.degree. to 150.degree. C. in the presence of a polyester amine or polyesterammonium salt and a CuPc fluidising agent. Preferred polyesterammonium salt is obtainable by reacting polyhydroxystearic acid with 3-dimethylaminopropylamine quaternised with dimethylsulphate.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: May 19, 1998
    Assignee: Zeneca Limited
    Inventors: John David Schofield, Dean Thetford