Abstract: A method of producing an organic non-wettable superhydrophobic fullerite film is presented. Non-wettable superhydrophobic fullerite films can be easily produced by growing nanofullerites via a sonication coupled crystallization protocol followed by multiple washings to obtain a pellet of nanofullerites. The pellet is aged for at least several weeks to allow for agglomeration into a gel which may then be applied to a substrate as a non-wettable superhydrophobic fullerite film.

Abstract: An inorganic paint pigment may include a fluid matrix, and paint flakes carried within the fluid matrix. Each paint flake may include a common aluminum layer having a first major surface and a second major surface opposing the first major surface, a first plasmonic aluminum reflector layer carried by the first major surface, and a second plasmonic aluminum reflector layer carried by the second major surface.

Abstract: An active IR camouflage device may include a base layer, a first dielectric layer over the base layer, a phase transition material layer over the first dielectric layer, a second dielectric layer over the phase transition material layer, and a first metal layer over the second dielectric layer and defining a pattern of openings therein. The active IR camouflage device may have circuitry configured to selectively cause a transition from a first phase state to a second phase state of the phase transition material layer to control IR reflectance/emission of a top plasmonic layer, making it appear/disappear from the IR detector/camera. In some embodiments, the active IR camouflage device may also include a second metal layer between the base layer and the first dielectric layer.

Abstract: A subwavelength gold hole/disk array that when coupled with a ground plane induces extraordinary transmission through the hole/disk array and zero back reflection. The hole/disk array functions as a “light funnel” in couling incident radiation into the cavity with about 100% efficiency over a narrow resonant bandwidth, which results in frequency-selective perfect (˜100%) absorption of the incident radiation. Such an optical frequency-selective absorber enables flexible scaling of detector response to any wavelength range by pattern dimensional changes, enabling uncooled frequency selective detection and “color” imaging in the infrared domain. Methods and applications are disclosed.

Abstract: Various methods and devices for ultrasensitive infrared photodetection, infrared imaging, and other optoelectronic applications using the plasmon assisted thermoelectric effect in graphene are described. Infrared detection by the photo-thermoelectric uses the generation of a temperature gradient (?T) for the efficient collection of the generated hot-carriers. An asymmetric plasmon-induced hot-carrier Seebeck photodetection scheme at room temperature exhibits a remarkable responsivity along with an ultrafast response in the technologically relevant 8-12 ?m band. This is achieved by engineering the asymmetric electronic environment of the generated hot carriers on chemical vapor deposition (CVD) grown large area nanopatterned monolayer graphene, which leads to a record ?T across the device terminals thereby enhancing the photo-thermoelectric voltage beyond the theoretical limit for graphene. The results provide a strategy for uncooled, tunable, multispectral infrared detection.

Abstract: Various methods and devices for ultrasensitive infrared photodetection, infrared imaging, and other optoelectronic applications using the plasmon assisted thermoelectric effect in graphene are described. Infrared detection by the photo-thermoelectric uses the generation of a temperature gradient (?T) for the efficient collection of the generated hot-carriers. An asymmetric plasmon-induced hot-carrier Seebeck photodetection scheme at room temperature exhibits a remarkable responsivity along with an ultrafast response in the technologically relevant 8-12 ?m band. This is achieved by engineering the asymmetric electronic environment of the generated hot carriers on chemical vapor deposition (CVD) grown large area nanopatterned monolayer graphene, which leads to a record ?T across the device terminals thereby enhancing the photo-thermoelectric voltage beyond the theoretical limit for graphene. The results provide a strategy for uncooled, tunable, multispectral infrared detection.

Abstract: Color derived from metallic nanostructures are often more efficient, more robust to environmental changes, and near impossible to damage or bleach due to overexposure. The embodiments combine these advantages with the millisecond re-configurability of liquid crystals to actively control a reflective color of a metallic nanostructure. Of the current technologies that boast active color tunability, many are pigmentation based (e-ink in e-readers) and/or need seconds to change color (photonic ink, electrochromic materials). Speed is an advantage of the embodiments and is comparable to current liquid crystal displays (˜120 Hz). Traditional LC displays use static polymer films (color filters) and white back light to generate color. Being able to actively tune the color from a single metallic nanostructure allows for smaller pixel size, increased resolution, and decreased fabrication cost compared to a conventional RGB color pixel without needing external white light source for extremely low power operations.

Abstract: A display device may include a substrate, a plasmonic aluminum reflector layer over the substrate, and a conducting oxide layer over the plasmonic aluminum reflector layer. The display device may have a circular polarizer over the conducting oxide layer and configured to receive incident visible radiation. The incident visible radiation may cause plasmon resonance within the plasmonic aluminum reflector layer. The display device may include a circuit configured to apply a voltage between the conducting oxide layer and the plasmonic aluminum reflector layer to cause the plasmonic aluminum reflector layer to selectively reflect the incident visible radiation based on the voltage.

Abstract: A method for molecular chirality detection is described. The method includes providing a substrate defining an array of hole-disks, each hole-disk coupled with an asymmetric optical cavity. Each asymmetric optical cavity having a back reflector separating a plasmonic pattern by an appropriate selection of thickness. The substrate is illuminated to simultaneously excite two degenerate localized surface plasmon modes producing a strong chiral near-field. The method may also include generating a characterization of chiral molecules on the substrate based on the strong chiral near-field. Substrates and detectors for molecular chirality detection are also described.

Abstract: A method is for making an optical detector device. The method may include forming a reflector layer carried by a substrate, forming a first dielectric layer over the reflector layer, and forming a graphene layer over the first dielectric layer and having a perforated pattern therein.

Abstract: An inorganic paint pigment may include a fluid matrix, and paint flakes carried within the fluid matrix. Each paint flake may include a common aluminum layer having a first major surface and a second major surface opposing the first major surface, a first plasmonic aluminum reflector layer carried by the first major surface, and a second plasmonic aluminum reflector layer carried by the second major surface.

Abstract: A method for molecular chirality detection is described. The method includes providing a substrate defining an array of hole-disks, each hole-disk coupled with an asymmetric optical cavity. Each asymmetric optical cavity having a back reflector separating a plasmonic pattern by an appropriate selection of thickness. The substrate is illuminated to simultaneously excite two degenerate localized surface plasmon modes producing a strong chiral near-field. The method may also include generating a characterization of chiral molecules on the substrate based on the strong chiral near-field. Substrates and detectors for molecular chirality detection are also described.

Abstract: A method is for making an optical detector device. The method may include forming a reflector layer carried by a substrate, forming a first dielectric layer over the reflector layer, and forming a graphene layer over the first dielectric layer and having a perforated pattern therein.

Abstract: An optical detector device may include a substrate, a reflector layer carried by the substrate, and a first dielectric layer over the reflector layer. The optical detector device may include a graphene layer over the first dielectric layer and having a perforated pattern.

Abstract: Dynamic, color-changing surfaces have many applications including but not limited to displays, wearables, and active camouflage. Plasmonic nanostructures can fill this role with the advantages of ultra-small pixels, high reflectivity, and post-fabrication tuning through control of the surrounding media. However, while post-fabrication tuning have yet to cover a full red-green-blue (RGB) color basis set with a single nanostructure of singular dimensions, the present invention contemplates a novel LC-based apparatus and methods that enable such tuning and demonstrates a liquid crystal-plasmonic system that covers the full red/green/blue (RGB) color basis set, as a function only of voltage. This is accomplished through a surface morphology-induced, polarization dependent, plasmonic resonance and a combination of bulk and surface liquid crystal effects that manifest at different voltages.

Abstract: Dynamic, color-changing surfaces have many applications including but not limited to displays, wearables, and active camouflage. Plasmonic nanostructures can fill this role with the advantages of ultra-small pixels, high reflectivity, and post-fabrication tuning through control of the surrounding media. However, while post-fabrication tuning have yet to cover a full red-green-blue (RGB) color basis set with a single nanostructure of singular dimensions, the present invention contemplates a novel LC-based apparatus and methods that enable such tuning and demonstrates a liquid crystal-plasmonic system that covers the full red/green/blue (RGB) color basis set, as a function only of voltage. This is accomplished through a surface morphology-induced, polarization dependent, plasmonic resonance and a combination of bulk and surface liquid crystal effects that manifest at different voltages.

Abstract: An optical detector device may include a substrate, a reflector layer carried by the substrate, and a first dielectric layer over the reflector layer. The optical detector device may include a graphene layer over the first dielectric layer and having a perforated pattern.

Abstract: A subwavelength gold hole/disk array that when coupled with a ground plane induces extraordinary transmission through the hole/disk array and zero back reflection. The hole/disk array functions as a “light funnel” in couling incident radiation into the cavity with about 100% efficiency over a narrow resonant bandwidth, which results in frequency-selective perfect (˜100%) absorption of the incident radiation. Such an optical frequency-selective absorber enables flexible scaling of detector response to any wavelength range by pattern dimensional changes, enabling uncooled frequency selective detection and “color” imaging in the infrared domain. Methods and applications are disclosed.

Abstract: An electronic device is for identifying the plastic composition of an unknown plastic object. The electronic device may include a spectrometer configured to receive the unknown plastic object and generate a MIR reflectance spectra characteristic of the unknown plastic object, a memory configured to store a multi-spectral fingerprint library for plastic types, and a processor coupled to the spectrometer and the memory. The processor is configured to analyze in real-time the MIR reflectance spectra characteristic of the unknown plastic object, and identify the plastic composition based upon at least comparing the MIR reflectance spectra characteristic of the unknown plastic object to the multi-spectral fingerprint library. The processor may be configured to expand the fingerprint library upon initial baseline characterization.

Abstract: Color derived from metallic nanostructures are often more efficient, more robust to environmental changes, and near impossible to damage or bleach due to overexposure. The embodiments combine these advantages with the millisecond re-configurability of liquid crystals to actively control a reflective color of a metallic nanostructure. Of the current technologies that boast active color tunability, many are pigmentation based (e-ink in e-readers) and/or need seconds to change color (photonic ink, electrochromic materials). Speed is an advantage of the embodiments and is comparable to current liquid crystal displays (˜120 Hz). Traditional LC displays use static polymer films (color filters) and white back light to generate color. Being able to actively tune the color from a single metallic nanostructure allows for smaller pixel size, increased resolution, and decreased fabrication cost compared to a conventional RGB color pixel without needing external white light source for extremely low power operations.