Abstract: A two stage Fluid Catalytic Cracking process and an apparatus for simultaneous production of light olefins such as ethylene and propylene and middle distillate range hydrocarbons, wherein a first flow reactor, preferably a downer and a second flow reactor, preferably a riser are operating at varying reaction severities using different catalyst systems with the regenerated catalyst entering the reactors inlet through independent regenerators. Mild cracking of the fresh feedstock is carried out in the first flow reactor of short residence time and the effluent of first flow reactor is separated in an intermediate separator/fractionator followed by re-cracking of the C4 hydrocarbons and naphtha range hydrocarbons, preferably C5-150° C. from the second product separation section and unconverted hydrocarbons (370° C.+) of first flow reactor, in the second flow reactor at higher severity employing different catalyst system.

Abstract: The invention provides for a process and apparatus for simultaneous conversion of lighter and heavier hydrocarbon feedstocks into improved yields of light olefins in the range of C2 to C4, liquid aromatics in the range C6 to C8 mainly benzene, toluene, xylene and ethyl benzene and other useful products employing at least two different reactors operated in series with respect to catalyst flow and parallel with respect to feed flow under different regimes and process conditions with same catalyst system.

Abstract: The present invention relates to a process for production of oligomer products from olefinic C4 feed stocks comprising isobutene, butenes, butanes, butadienes and mixture thereof. Particularly, the present invention relates to a process for the preparation of oligomers using olefinic C4 feed stock in presence of tertiary butyl alcohol (TBA) and iso propyl alcohol (IPA).

Abstract: The present invention relates to a liquid phase additive comprising an alkyl nitrate; a petroleum sulphonates; an aliphatic, aromatic, cyclohexylamines or hetroalkylated lower amines; a hindered phenol based compounds; a phosphate esters and an aliphatic alcohols for use in delayed coking process with decreased coke yield and increased yield of liquid and/or gaseous product and a process for preparing the liquid phase additive. The present invention also relates to a process for thermal cracking of petroleum residue producing petroleum coke and lighter hydrocarbon products by using liquid phase additive.

Abstract: The present invention provides a delayed coking process comprising a step of subjecting a mixed feed comprises residual heavy hydrocarbon feedstock and bio oil obtained from fast pyrolysis of lignocellulosic biomass of one or more of Jatropha, Cashew nut, Karanjia and Neem to a delayed coking process and a system for the delayed coking process.

Abstract: The present invention is directed to novel thermal cracking additive compositions for reduction of coke yield in Delayed Coking process and method for preparing the same. The present invention also provides that the thermal cracking additive compositions of the present invention are in micron-size and nano-size. Further, the present invention provides a process of thermal cracking of heavy petroleum residue used in petroleum refineries using Delayed Coking process to produce petroleum coke and lighter hydrocarbon products with decreased coke yield and increased yield of liquid and/or gaseous products.

Abstract: An apparatus which is an integral hardware consisting of an annular downer reactor and a concentric upflow riser regenerator for catalytic cracking of hydrocarbon feed to is disclosed. The annular downer reactor terminates in annular stripper which is also concentric with the regenerator. The regenerator, reactor and stripper are in fluid connection with each other. The apparatus is highly compact and provides efficient contact between circulating catalyst and hydrocarbon feed. The proposed hardware includes a novel radial distributor for providing improved control and radial distribution of catalyst inside the downflow reactor. The radial distributor has equal numbers of stationary and movable parts placed one after another to cover the entire annular opening at the bottom of the regenerated catalyst vessel. The radial distributor is concentric with regenerator and located between the catalyst holding vessel and the reactor. A process for catalytic cracking using the invented apparatus is also disclosed.

Abstract: An apparatus for catalytic cracking of feedstock includes a first channel in which a feedstock is treated with an adsorbent to obtain a treated intermediate. The apparatus further comprises a separator-reactor vessel. The separator-reactor vessel includes an adsorbent separating region to remove the adsorbent from the treated intermediate. The separator-reactor vessel further includes a second channel connected to the adsorbent separating region. The treated intermediate is contacted with a catalyst in the second channel to produce a cracking yield. The second channel terminates in a catalyst separating region of the separator-reactor vessel. The catalyst is removed from the cracking yield in the catalyst separating region. The separator-reactor vessel further includes a physical partition disposed between the adsorbent separating region and the catalyst separating region to separate the two regions.

Abstract: A process for increasing the yield of C3 olefin in fluidized bed catalytic cracking of hydrocarbon feedstocks is disclosed. C4 fraction produced from the cracking of hydrocarbon feedstock in the primary reaction zone (riser), optionally with external source of C4 stream is fed into the stripper which acts as a secondary reaction zone at an elevated temperature and at an optimum WHSV. The elevated temperature is achieved by injecting a part of the regenerated catalyst from regenerator, which is at a higher temperature, directly into the stripper through a dedicated additional lift line. This raises the activity of catalyst inside the stripper. The direct injection of regenerated catalyst into the stripper, besides producing higher yields of propylene, improves the stripping efficiency leading to enhanced recovery of strippable hydrocarbons.

Abstract: An apparatus for supplying additives into a coker drum includes an inlet for supplying a hydrocarbon feed stream into the coker drum and conduits along the circumference of walls of the coker drum. Each conduit has an injection nozzle to supply additives inside the coker drum. An injection control system controls the operation of the injection nozzles such that 1) one or more of the injection nozzles placed within a first distance above a vapour liquid interphase of the hydrocarbon feed stream are configured to supply the additives; and 2) supply of the additive discontinues from a particular injection nozzle when a distance between the injection nozzle and the vapour liquid interphase is less than or equal to a second distance. The apparatus optionally includes a mechanical drive system moving at least one of the conduits based on the level of the vapour liquid interphase in the coker drum.

Abstract: This invention provides a fluidized catalytic cracking apparatus and process for converting a hydrocarbon feedstock containing higher concentrations of Conradson Carbon Residue (CCR), metal impurities, etc into lighter products by employing two riser reactors in which the feed impurities are removed using an adsorbent in a first riser reactor and cracking a portion of first riser reactor liquid product in a second riser reactor to lighter products using the active catalyst thus eliminating the catalyst deactivation due to metal, impurities and FCC catalyst activity dilution effect to achieve a better conversion and higher catalyst longevity.

Abstract: A two stage Fluid Catalytic Cracking process and an apparatus for simultaneous production of light olefins such as ethylene and propylene and middle distillate range hydrocarbons, wherein a first flow reactor, preferably a downer and a second flow reactor, preferably a riser are operating at varying reaction severities using different catalyst systems with the regenerated catalyst entering the reactors inlet through independent regenerators. Mild cracking of the fresh feedstock is carried out in the first flow reactor of short residence time and the effluent of first flow reactor is separated in an intermediate separator/fractionator followed by re-cracking of the C4 hydrocarbons and naphtha range hydrocarbons, preferably C5-150° C. from the second product separation section and unconverted hydrocarbons (370° C.+) of first flow reactor, in the second flow reactor at higher severity employing different catalyst system.

Abstract: This invention relates to a process and an apparatus for regeneration of spent FCC catalyst using multiple reactors operation resulting in wide variation of coke on spent catalyst are disclosed. This process uses an up flow regenerator with divided injection of spent catalyst based on their coke content to control the residence time for its efficient regeneration and reduced hydrothermal deactivation. This system has the advantage of minimizing the exposure to the high temperature of low coked catalyst to the minimum possible time and high coke contained catalyst to the required time for its complete regeneration.

Abstract: The invention provides for a process and apparatus for simultaneous conversion of lighter and heavier hydrocarbon feedstocks into improved yields of light olefins in the range of C2 to C4, liquid aromatics in the range C6 to C8 mainly benzene, toluene, xylene and ethyl benzene and other useful products employing at least two different reactors operated in series with respect to catalyst flow and parallel with respect to feed flow under different regimes and process conditions with same catalyst system.

Abstract: An apparatus for catalytic cracking of feedstock includes a first channel in which a feedstock is treated with an adsorbent to obtain a treated intermediate. The apparatus further comprises a separator-reactor vessel. The separator-reactor vessel includes an adsorbent separating region to remove the adsorbent from the treated intermediate. The separator-reactor vessel further includes a second channel connected to the adsorbent separating region. The treated intermediate is contacted with a catalyst in the second channel to produce a cracking yield. The second channel terminates in a catalyst separating region of the separator-reactor vessel. The catalyst is removed from the cracking yield in the catalyst separating region. The separator-reactor vessel further includes a physical partition disposed between the adsorbent separating region and the catalyst separating region to separate the two regions.

Abstract: The present invention relates to a fluidized catalytic cracking process for cracking hydrocarbon feed having organo-sulfur compound as an impurity, said process comprising: adding a heavy metal poisoned spent catalyst to an equilibrium catalyst to obtain a composite circulating catalyst, wherein the heavy metal poisoned spent catalyst is added in an amount to maintain the activity of the circulating catalyst; and obtaining a fluidized catalytic cracked product. The present invention further relates to fluidized catalytic cracked product obtained by the process of the present invention. The sulfur content of the fluidized catalytic cracked product mainly gasoline which is boiling in the range of C5-250° C. reduced by more than 20% (wt/wt). And Research Octane number of the fluidized catalytic cracked product is increased by more than 1 unit.

Abstract: A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 440 to 520° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm2 to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a hydrocarbon fraction having a boiling point in the range of 380 to 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 460 to 540° C.

Abstract: The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2 (g) and weight hourly space velocity in range of 0.1 to 20 hour?1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.

Abstract: A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 440 to 520° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm2 to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a hydrocarbon fraction having a boiling point in the range of 380 to 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 460 to 540° C.

Abstract: According to this invention, there is provided a process and apparatus for catalytic cracking of various petroleum based heavy feed stocks in the presence of solid zeolite catalyst and high pore size acidic components for selective bottom cracking and mixtures thereof, in multiple riser type continuously circulating fluidized bed reactors operated at different severities to produce high yield of middle distillates, in the range of 50–65 wt % of fresh feed.