Abstract: A spoolable pipe (100) comprising: a barrier layer (104) formed around a longitudinal axis of the pipe; a reinforcing layer (105) disposed around the barrier layer comprising a fiber material; and an outer layer (110), wherein at least one of the reinforcing layer (105) and the outer layer (110) comprises a thermoplastic elastomer (TPE) composition comprising a thermoplastic matrix and a rubber phase dispersed in the thermoplastic matrix and having a thermal conductivity of about 0.2 W/m-K or less.

Abstract: A method of conveying a production fluid from an offshore subsea well to an offshore vessel includes deploying an inflatable bladder from the offshore vessel, the inflatable bladder including a bladder valve, and fluidly connecting the inflatable bladder to an offloading port positioned at a seafloor, wherein the offloading port includes a port valve and is in fluid communication with one or more subterranean hydrocarbon-bearing formations. The method further includes opening the bladder and port valves to discharge the production fluid from the offloading port into the inflatable bladder, and thereby resulting in a substantially filled bladder, closing the bladder and port valves, and fluidly disconnecting the substantially filled bladder from the offloading port.

Abstract: In an embodiment is provided a composition having a thermal conductivity of less than 0.2 W/m-K, the composition including a rubber and a thermoplastic olefin. In another embodiment is provided an insulated high-temperature transport conduit that includes a continuous steel pipe comprising one or more pipe sections, wherein the steel pipe has an outer surface and an inner surface; and a first thermal insulation layer disposed over the outer surface of the steel pipe, wherein the first thermal insulation layer comprises a composition having a thermal conductivity of less than 0.2 W/m-K, the composition comprising a rubber and a thermoplastic olefin.

Abstract: A method of conveying a production fluid from an offshore subsea well to an offshore vessel includes deploying an inflatable bladder from the offshore vessel, the inflatable bladder including a bladder valve, and fluidly connecting the inflatable bladder to an offloading port positioned at a seafloor, wherein the offloading port includes a port valve and is in fluid communication with one or more subterranean hydrocarbon-bearing formations. The method further includes opening the bladder and port valves to discharge the production fluid from the offloading port into the inflatable bladder, and thereby resulting in a substantially filled bladder, closing the bladder and port valves, and fluidly disconnecting the substantially filled bladder from the offloading port.

Abstract: In an embodiment, a flexible pipe is provided. The flexible pipe includes a polymeric inner sheath that includes a thermoplastic vulcanizate (TPV) composition, the TPV composition comprising: a rubber and a thermoplastic olefin, wherein a concentration of the rubber is from 20 wt % to 90 wt % based on a combined weight of the rubber and the thermoplastic olefin, and a concentration of the thermoplastic olefin is from 10 wt % to 80 wt % based on the combined weight of the rubber and the thermoplastic olefin; and wherein the TPV composition has at least one of an air permeability of less than 30 barrers at 23° C. and a CO2 permeability of less than 40 barrers at 23° C. In another embodiment, a thermoplastic umbilical hose is provided. In another embodiment, a pipe structure is provided.

Abstract: Copolymer are formed by polymerizing C4 to C7 isoolefin monomers and alkyl-styrene monomers. The method comprises first providing feed streams into a reactor. The various feed streams provide monomers, a polar diluent or polar diluent mixture, and a catalyst system into the reactor. In the reactor, the feed streams contact one another so that the monomers form a polymer in a stable slurry, wherein the amount of polymer in the slurry yields a slurry concentration greater than 22 wt %. The ratio of moles of polymer formed per mole initiator is in the range of 0.25 to 4.0 moles polymer per mole of initiator.

Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.

Abstract: Copolymer are formed by polymerizing C4 to C7 isoolefin monomers and alkyl-styrene monomers. The method comprises first providing feed streams into a reactor. The various feed streams provide monomers, a polar diluent or polar diluent mixture, and a catalyst system into the reactor. In the reactor, the feed streams contact one another so that the monomers form a polymer in a stable slurry, wherein the amount of polymer in the slurry yields a slurry concentration greater than 22 wt %. The ratio of moles of polymer formed per mole initiator is in the range of 0.25 to 4.0 moles polymer per mole of initiator.

Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.

Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.

Abstract: The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.

Abstract: The disclosure provides a slurry polymerization system and method to decrease polymer deposition on reactor surfaces using an oxygenate such as alcohol (16) supplied to the polymerization medium (32) separate from the catalyst feed (34).