Abstract: An optical fiber comprising a core, a cladding disposed about the core, and a primary coating disposed about the cladding. The primary coating is cured during draw to at least eighty-five percent (85%) of the primary coating's fully cured primary-coating in situ modulus (P-ISM) value.

Abstract: Disclosed herein is a coating composition comprising a silsesquioxane component having one or more reactive functional groups that render it curable using ultraviolet radiation; where the one or more reactive functional groups are selected from the group consisting of an acrylate, a vinyl ether, or an epoxy; and optionally, a co-reactive non-silsesquioxane monomer and/or an oligomer having one or more reactive functional groups that are curable using ultraviolet radiation and are selected from the group consisting of free radically curable acrylates, cationically curable epoxies, and cationically curable vinyl ethers; where the coating composition is disposed and cured on an optical article; where the optical article is at least one of an optical fiber or an optical planar waveguide; and where the average functionality of the composition is greater than one.

Abstract: An optical fiber comprising a core, a cladding disposed about the core, and a primary coating disposed about the cladding. The primary coating is cured during draw to at least eighty-five percent (85%) of the primary coating's fully cured primary-coating in situ modulus (P-ISM) value.

Abstract: Disclosed herein is a coating composition comprising a silsesquioxane component having one or more reactive functional groups that render it curable using ultraviolet radiation; where the one or more reactive functional groups are selected from the group consisting of an acrylate, a vinyl ether, or an epoxy; and optionally, a co-reactive non-silsesquioxane monomer and/or an oligomer having one or more reactive functional groups that are curable using ultraviolet radiation and are selected from the group consisting of free radically curable acrylates, cationically curable epoxies, and cationically curable vinyl ethers; where the coating composition is disposed and cured on an optical article; where the optical article is at least one of an optical fiber or an optical planar waveguide; and where the average functionality of the composition is greater than one.

Abstract: Disclosed herein is a composition for coating an optical fiber comprising a free radically curable acrylate and/or a methacrylate functionalized oligomer having a density of less than 1.0 g/cm3; where the acrylate and/or the methacrylate functionalized oligomer has a functionality of 1 or more; a photoinitiator; and optionally a free radically curable acrylate and/or methacrylate diluent monomer that has a density of less than 1.0 g/cm3; where the coating composition is disposed and cured on an optical fiber; where the density of the cured coating is less than 1.0 g/cm3; and where the average functionality of the composition is greater than one.

Abstract: Disclosed herein is a coating composition comprising a silsesquioxane component having one or more reactive functional groups that render it curable using ultraviolet radiation; where the one or more reactive functional groups are selected from the group consisting of an acrylate, a vinyl ether, or an epoxy; and optionally, a co-reactive non-silsesquioxane monomer and/or an oligomer having one or more reactive functional groups that are curable using ultraviolet radiation and are selected from the group consisting of free radically curable acrylates, cationically curable epoxies, and cationically curable vinyl ethers; where the coating composition is disposed and cured on an optical article; where the optical article is at least one of an optical fiber or an optical planar waveguide; and where the average functionality of the composition is greater than one.

Abstract: A optical fiber having core and cladding regions, a primary coating, and a secondary coating may be defined in part by a curve relating the microbend sensitivity to a ratio of the elastic modulus of the secondary coating to the elastic modulus of the primary coating (as plotted on respective y and x axes). The curve has a substantially peaked shape defined by a positive-slope region and a negative-slope region. The ratio of the elastic modulus of the secondary coating to the elastic modulus of the primary coating is within the positive-slope region.

Abstract: A optical fiber having core and cladding regions, a primary coating, and a secondary coating may be defined in part by a curve relating the microbend sensitivity to a ratio of the elastic modulus of the secondary coating to the elastic modulus of the primary coating (as plotted on respective y and x axes). The curve has a substantially peaked shape defined by a positive-slope region and a negative-slope region. The ratio of the elastic modulus of the secondary coating to the elastic modulus of the primary coating is within the positive-slope region.

Abstract: Disclosed herein is a composition for coating an optical fiber comprising a free radically curable acrylate and/or a methacrylate functionalized oligomer having a density of less than 1.0 g/cm3; where the acrylate and/or the methacrylate functionalized oligomer has a functionality of 1 or more; a photoinitiator, and optionally a free radically curable acrylate and/or methacrylate diluent monomer that has a density of less than 1.0 g/cm3; where the coating composition is disposed and cured on an optical fiber, where the density of the cured coating is less than 1.0 g/cm3; and where the average functionality of the composition is greater than one.

Abstract: Disclosed herein is a composition comprising 65 to 95 weight percent of a fluorinated monofunctional monomer; 5 to 35 weight percent of a fluorinated multifunctional monomer; and 0.5 to 3 weight percent of a silane coupling agent; where all weight percents are based on the total weight of the composition; where the fluorinated monofunctional monomer and the fluorinated multifunctional monomer are devoid of any trifunctional fluorocarbon moieties when they have 6 or more fluorocarbon repeat units; where the fluorocarbon repeat units are CF2 or CF moieties; and where a crosslinked composition has a shore D hardness of 56 to 85 and has a refractive index (RI) that meets the limitation of the equation RI?1.368+10.8/X, where X denotes wavelength in nanometers.

Abstract: A technique is described for fabricating one or more optical devices in a carbon-coated optical fiber. A photosensitive optical fiber is provided having a hermetic carbon coating. Further provided is a laser having a beam output that is configured to inscribe one or more refractive index modulations into the optical fiber through the hermetic carbon layer while leaving the hermetic carbon layer intact. The laser is used to inscribe one or more optical devices into the optical fiber through the hermetic carbon layer.

Abstract: A technique is described for fabricating one or more optical devices in a carbon-coated optical fiber. A photosensitive optical fiber is provided having a hermetic carbon coating. Further provided is a laser having a beam output that is configured to inscribe one or more refractive index modulations into the optical fiber through the hermetic carbon layer while leaving the hermetic carbon layer intact. The laser is used to inscribe one or more optical devices into the optical fiber through the hermetic carbon layer.

Abstract: Disclosed herein is a coating composition comprising a silsesquioxane component having one or more reactive functional groups that render it curable using ultraviolet radiation; where the one or more reactive functional groups are selected from the group consisting of an acrylate, a vinyl ether, or an epoxy; and optionally, a co-reactive non-silsesquioxane monomer and/or an oligomer having one or more reactive functional groups that are curable using ultraviolet radiation and are selected from the group consisting of free radically curable acrylates, cationically curable epoxies, and cationically curable vinyl ethers; where the coating composition is disposed and cured on an optical article; where the optical article is at least one of an optical fiber or an optical planar waveguide; and where the average functionality of the composition is greater than one.

Abstract: Disclosed herein is a composition comprising 65 to 95 weight percent of a fluorinated monofunctional monomer; 5 to 35 weight percent of a fluorinated multifunctional monomer; and 0.5 to 3 weight percent of a silane coupling agent; where all weight percents are based on the total weight of the composition; where the fluorinated monofunctional monomer and the fluorinated multifunctional monomer are devoid of any trifunctional fluorocarbon moieties when they have 6 or more fluorocarbon repeat units; where the fluorocarbon repeat units are CF2 or CF moieties; and where a crosslinked composition has a shore D hardness of 56 to 85 and has a refractive index (RI) that meets the limitation of the equation RI?1.368+10.8/X, where X denotes wavelength in nanometers.

Abstract: A technique is described for fabricating one or more optical devices in a carbon-coated optical fiber. A photosensitive optical fiber is provided having a hermetic carbon coating. Further provided is a laser having a beam output that is configured to inscribe one or more refractive index modulations into the optical fiber through the hermetic carbon layer while leaving the hermetic carbon layer intact. The laser is used to inscribe one or more optical devices into the optical fiber through the hermetic carbon layer.

Abstract: A technique is described for fabricating one or more optical devices in a carbon-coated optical fiber. A photosensitive optical fiber is provided having a hermetic carbon coating. Further provided is a laser having a beam output that is configured to inscribe one or more refractive index modulations into the optical fiber through the hermetic carbon layer while leaving the hermetic carbon layer intact. The laser is used to inscribe one or more optical devices into the optical fiber through the hermetic carbon layer.

Abstract: A technique is described for fabricating one or more optical devices in a carbon-coated optical fiber. A photosensitive optical fiber is provided having a hermetic carbon coating. Further provided is a laser having a beam output that is configured to inscribe one or more refractive index modulations into the optical fiber through the hermetic carbon layer while leaving the hermetic carbon layer intact. The laser is used to inscribe one or more optical devices into the optical fiber through the hermetic carbon layer.

Abstract: Certain embodiments of the invention may include systems and methods for providing optical fiber coatings to reduce microbend losses. According to an example embodiment of the invention, a method is provided for coating an optical fiber to reduce microbend losses and polarization mode dispersion (PMD). The method includes applying a primary layer to the optical fiber, wherein the optical fiber comprises a core region surrounded by a cladding region. The method includes applying a secondary layer to the primary layer, and curing the primary and secondary layers, wherein the cured primary layer adheres to the cladding region with a minimum pullout adhesion of 6 N/cm, and the cured secondary layer has an in situ modulus of about 700 MPa to about 1200 MPa at room temperature.

Abstract: Recognizing the rate-determining nature of the coating removal and recoating steps, applicants have demonstrated that with proper combination of low absorbing polymer, glass and low intensity radiation, UV-induced gratings can be side-written into polymer coated fibers without removing the polymer, thus permitting up the possibility of high speed fabrication of fiber gratings.