Patents by Inventor Demetrius Michos

Demetrius Michos has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20120288545
    Abstract: Compositions suitable for use as skin care products (e.g., skin cream) are disclosed. Methods of making and using compositions suitable for use as skin care products are also disclosed.
    Type: Application
    Filed: December 14, 2010
    Publication date: November 15, 2012
    Inventors: Demetrius Michos, James Neil Pryor
  • Publication number: 20120285349
    Abstract: Composite inorganic particles and compositions containing silica particles are disclosed. Methods of making silica particles and methods of using composite inorganic particles are also disclosed.
    Type: Application
    Filed: December 13, 2010
    Publication date: November 15, 2012
    Inventors: Demetrius Michos, Daniel Ray Fruge
  • Publication number: 20100294168
    Abstract: An inorganic oxide coating produced by preparing a coating composition comprising inorganic oxide particles and a polymer, applying the composition on a substrate to form a coating, and heating the substrate to remove the polymeric component, wherein the resulting coating is transparent.
    Type: Application
    Filed: March 22, 2007
    Publication date: November 25, 2010
    Applicant: W. R. GRACE & CO.-CONN.
    Inventors: Qi Sun, Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20100196300
    Abstract: A basic aluminum composition comprising an empirical formula: Al2(OH)6—aXa where 0.5?a?5.0, and X is an anion of nitrogen; and wherein the composition possesses an NMR spectrum in which a ?40 to +40 ppm resonance line comprises at least 60% of the total area of the NMR spectrum.
    Type: Application
    Filed: July 17, 2008
    Publication date: August 5, 2010
    Inventor: Demetrius Michos
  • Publication number: 20100183808
    Abstract: Alumina particles and compositions containing alumina particles are disclosed. Methods of making alumina particles and methods of using alumina particles are also disclosed.
    Type: Application
    Filed: May 22, 2008
    Publication date: July 22, 2010
    Inventor: Demetrius Michos
  • Patent number: 7622170
    Abstract: A coating composition comprising low sodium containing colloidal silicas and ink jet recording sheets prepared from such coatings are described. The coating comprises binder and colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: November 24, 2009
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20090148692
    Abstract: Alumina particles and compositions containing alumina particles are disclosed. Methods of making alumina particles and methods of using alumina particles are also disclosed.
    Type: Application
    Filed: December 12, 2006
    Publication date: June 11, 2009
    Applicant: W. R. GRACE & CO.-CONN.
    Inventor: Demetrius Michos
  • Patent number: 7393571
    Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 ? or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: July 1, 2008
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Monroe Chapman, Demetrius Michos
  • Patent number: 6902780
    Abstract: A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: June 7, 2005
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6896942
    Abstract: A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: May 24, 2005
    Assignee: W. R. Grace & Co. -Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6893691
    Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: May 17, 2005
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6841609
    Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 ? or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: January 11, 2005
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Monroe Chapman, Demetrius Michos
  • Publication number: 20040241425
    Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 Å or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g.
    Type: Application
    Filed: July 7, 2004
    Publication date: December 2, 2004
    Inventors: David Monroe Chapman, Demetrius Michos
  • Patent number: 6780920
    Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 Å or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g. Formulations comprising particles having a zeta potential of +20 mV are also disclosed.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: August 24, 2004
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Monroe Chapman, Demetrius Michos
  • Publication number: 20030198759
    Abstract: A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.
    Type: Application
    Filed: March 18, 2003
    Publication date: October 23, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030191226
    Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 Å or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g.
    Type: Application
    Filed: July 9, 1998
    Publication date: October 9, 2003
    Inventors: DAVID MONROE CHAPMAN, DEMETRIUS MICHOS
  • Publication number: 20030181566
    Abstract: Formulations comprising novel porous metal oxide particles and binder are particularly suitable for ink receptive coatings, e.g., for ink jet papers and films. The metal oxide particles used in this application have a porous structure that differs significantly from the nonporous silica colloids. The particles have a median particle size in the range of about 0.05 to about 3 microns and porosity such that when an aqueous dispersion of the particles is dried at least 0.5 cc/g of pore volume is from pores having a pore size of 600 Å or less. The particles also have a viscosity derived pore volume of at least 0.5 cc/g.
    Type: Application
    Filed: November 26, 2002
    Publication date: September 25, 2003
    Inventors: David Monroe Chapman, Demetrius Michos
  • Publication number: 20030180478
    Abstract: A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(−0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Application
    Filed: March 18, 2003
    Publication date: September 25, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030180480
    Abstract: A coating composition comprising low sodium containing colloidal silicas and ink jet recording sheets prepared from such coatings are described. The coating comprises binder and colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(−0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.
    Type: Application
    Filed: March 18, 2003
    Publication date: September 25, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Publication number: 20030180483
    Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.
    Type: Application
    Filed: March 18, 2003
    Publication date: September 25, 2003
    Inventors: Daniel Ray Fruge, Demetrius Michos