Patents by Inventor Dennis J. Grebur
Dennis J. Grebur has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 4794149Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: September 3, 1987Date of Patent: December 27, 1988Assignee: E. I. Du Pont De Nemours and CompanyInventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
-
Patent number: 4778861Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.Type: GrantFiled: August 7, 1987Date of Patent: October 18, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
-
Patent number: 4769425Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy amine adduct precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with hydroxy functional secondary amine. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.Type: GrantFiled: August 7, 1987Date of Patent: September 6, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
-
Patent number: 4767829Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: June 11, 1987Date of Patent: August 30, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4754002Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: December 16, 1985Date of Patent: June 28, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4742129Abstract: An organic solvent based, thermosetting coating composition of a hydroxy functional epoxy-polyester graft copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: August 7, 1987Date of Patent: May 3, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4713425Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, and polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: November 22, 1985Date of Patent: December 15, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4708995Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone members in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide chain extended with diphenol and chain terminated with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree.Type: GrantFiled: November 14, 1985Date of Patent: November 24, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4701502Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: December 13, 1985Date of Patent: October 20, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4701501Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide, previously chain extended with dicarboxylic acid, with hydroxy functional secondary amine in chain terminating reaction.Type: GrantFiled: November 22, 1985Date of Patent: October 20, 1987Assignee: E. I. du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4699955Abstract: A solvent based thermosetting coating composition comprising hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide, chain extended with diphenol and dicarboxylic acid, with hydroxy functional secondary amine in chain terminating reaction.Type: GrantFiled: November 22, 1985Date of Patent: October 13, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4699958Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.Type: GrantFiled: November 22, 1985Date of Patent: October 13, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4699959Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy amine adduct linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy amine adduct is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with hydroxy functional secondary amine.Type: GrantFiled: December 16, 1985Date of Patent: October 13, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4699957Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with diphenol and either subsequently or simultaneously chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: November 22, 1985Date of Patent: October 13, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4698400Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree.Type: GrantFiled: December 16, 1985Date of Patent: October 6, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4698402Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy amine adduct precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with hydroxy functional secondary amine. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.Type: GrantFiled: December 16, 1985Date of Patent: October 6, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4698399Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: November 14, 1985Date of Patent: October 6, 1987Assignee: E. I. du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4698398Abstract: A hydroxy functional epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chippng by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.Type: GrantFiled: November 14, 1985Date of Patent: October 6, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4581424Abstract: Novel epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. Coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in presence of hydroxy functional epoxy resin precursor. Precursor resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.Type: GrantFiled: July 5, 1983Date of Patent: April 8, 1986Assignee: Ford Motor CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
-
Patent number: 4579917Abstract: Novel epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. Coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in presence of hydroxy functional epoxy resin precursor. Precursor resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.Type: GrantFiled: August 8, 1984Date of Patent: April 1, 1986Assignee: Ford Motor CompanyInventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur