Patents by Inventor Dennis J. Grebur

Dennis J. Grebur has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4794149
    Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: September 3, 1987
    Date of Patent: December 27, 1988
    Assignee: E. I. Du Pont De Nemours and Company
    Inventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
  • Patent number: 4778861
    Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: October 18, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
  • Patent number: 4769425
    Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy amine adduct precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with hydroxy functional secondary amine. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: September 6, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Andrew H. Dervan, Dennis J. Grebur, Panagiotis I. Kordomenos
  • Patent number: 4767829
    Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: June 11, 1987
    Date of Patent: August 30, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4754002
    Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: June 28, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4742129
    Abstract: An organic solvent based, thermosetting coating composition of a hydroxy functional epoxy-polyester graft copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: May 3, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4713425
    Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, and polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: December 15, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4708995
    Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone members in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide chain extended with diphenol and chain terminated with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: November 24, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4701502
    Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: October 20, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4701501
    Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide, previously chain extended with dicarboxylic acid, with hydroxy functional secondary amine in chain terminating reaction.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: October 20, 1987
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4699955
    Abstract: A solvent based thermosetting coating composition comprising hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide, chain extended with diphenol and dicarboxylic acid, with hydroxy functional secondary amine in chain terminating reaction.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: October 13, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4699958
    Abstract: A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: October 13, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4699959
    Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy amine adduct linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy amine adduct is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with hydroxy functional secondary amine.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: October 13, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4699957
    Abstract: Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is the reaction product of diepoxide chain extended with diphenol and either subsequently or simultaneously chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: October 13, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4698400
    Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: October 6, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4698402
    Abstract: An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy amine adduct precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with hydroxy functional secondary amine. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: October 6, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4698399
    Abstract: A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: October 6, 1987
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4698398
    Abstract: A hydroxy functional epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chippng by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: October 6, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4581424
    Abstract: Novel epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. Coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in presence of hydroxy functional epoxy resin precursor. Precursor resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.
    Type: Grant
    Filed: July 5, 1983
    Date of Patent: April 8, 1986
    Assignee: Ford Motor Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur
  • Patent number: 4579917
    Abstract: Novel epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. Coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in presence of hydroxy functional epoxy resin precursor. Precursor resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.
    Type: Grant
    Filed: August 8, 1984
    Date of Patent: April 1, 1986
    Assignee: Ford Motor Company
    Inventors: Panagiotis I. Kordomenos, Andrew H. Dervan, Dennis J. Grebur