Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of thermally insulating particles distributed within the polymeric network structure, wherein the thermally insulating particles are present in a range from 15 to 99 weight percent, based on the total weight of the thermally insulating particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density not greater than 3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, in electronic devices.

Abstract: A composite cooling film (100) comprises an antisoiling layer (160) secured to a first major surface of a reflective microporous layer (110). The reflective microporous layer (110) comprises a first fluoropolymer and is diffusely reflective of electromagnetic radiation over a majority of wavelengths in the range of 400 to 2500 nanometers. The antisoiling layer (160) has an outwardly facing antisoiling surface (162) opposite the micro-voided polymer film. An article (1100) comprising the composite cooling film (1112) secured to a substrate (1110) is also disclosed.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of intumescent particles distributed within the polymeric network structure; wherein the intumescent particles are present in a range from 15 to 99 weight percent, based on the total weight of the intumescent particles and the polymer (excluding the solvent); and wherein the polymer matrix composite volumetrically expands at least 2 times its initial volume when exposed to at least one temperature greater than 135° C.; and methods for making the same. The polymer matrix composites are useful, for example, as fillers, thermally initiated fuses, and fire stop devices.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of functional particles distributed within the polymeric network structure, and wherein the polymer matrix composite has an air flow resistance at 25° C., as measured by the “Air Flow Resistance Test,” of less than 300 seconds/50 cm3/500 micrometers; and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, as filters.

Abstract: Method of making a polymer matrix composite comprising a porous polymeric network structure; and a plurality of particles distributed within the polymeric network structure, the method comprising: combining a thermoplastic polymer, a solvent that the thermoplastic polymer is soluble in, and a plurality of particles to provide a slurry; forming the slurry in to an article; heating the article in an environment to retain at least 90 percent by weight of the solvent, based on the weight of the solvent in the slurry, and inducing phase separation of the thermoplastic polymer from the solvent to provide the polymer matrix composite.

Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of functional particles distributed within the polymeric network structure, and wherein the polymer matrix composite has an air flow resistance at 25° C., as measured by the “Air Flow Resistance Test,” of less than 300 seconds/50 cm3/500 micrometers; and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, as filters.

Abstract: A polymer matrix composite comprising a porous polymeric network; and a plurality of dielectric particles distributed within the polymeric network structure; wherein the dielectric particles are present in a range from 5 to 98 weight percent, based on the total weight of the dielectric particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a dielectric constant in a range from 1.05 to 80; and methods for making the same. Polymer matrix composites comprising dielectric particles are useful, for example, as electric field insulators.

Abstract: A polymer matrix composite includes a porous polymeric network structure; and a plurality of acoustically active particles distributed within the polymeric network structure. The weight fraction of acoustically active particles is between 0.80 and 0.99, based on the total weight of the polymer matrix composite. The polymer matrix composite has an air flow resistance of less than 100 seconds/50 mL/500 ?m.

Abstract: A magnetic shielding film includes opposing first and second major surfaces and a plurality of particles dispersed therebetween, each particle having a magnetic permeability, a thickness H along a thickness direction of the particle, and a longest dimension L along a length direction of the particle orthogonal to the thickness direction, L/H greater than or equal to 2, the particles defining a plurality of voids therebetween, the length directions of at least 60% of the particles oriented within 5.5 degrees of a same orientation direction.

Abstract: Polymer matrix composite comprising a porous polymeric network; and a plurality of thermally conductive particles distributed within the polymeric network structure; wherein the thermally conductive particles are present in a range from 15 to 99 weight percent, based on the total weight of the thermally conductive particles and the polymer (excluding the solvent); and wherein the polymer matrix composite has a density of at least 0.3 g/cm3; and methods for making the same. The polymer matrix composites are useful, for example, in electronic devices.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles and a multiplicity of magnetic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles, magnetic particles and optional magnetic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing thermal interface materials that also provide magnetic properties useful, for example, in flux field directional materials or shielding from electromagnetic interference.

Abstract: Foam compositions are provided including a polylactic acid polymer; second (e.g., polyvinyl acetate) polymer having a glass transition temperature (Tg) of at least 25° C.; and plasticizer. Also described are articles comprising the foam compositions, such as a sheet or hearing protection article. Methods of making and using the foam compositions are further described herein.

Abstract: A composite cooling film (100) comprises an ultraviolet-reflective multilayer optical film (120) and a reflective microporous layer (110) secured thereto. The ultraviolet-reflective multilayer optical film (120) hat is at least 50 percent reflective of ultraviolet radiation over a majority of the wavelength range of at least 340 but less than 400 nanometers. The reflective microporous layer (110) has a continuous phase comprising a nonfluorinated organic polymer and is diffusely reflective of solar radiation over a majority the wavelength range of 400 to 2500 nanometers, inclusive. The composite cooling film (100) has an average absorbance over the wavelength range 8-13 microns of at least 0.85. An article (1200) comprising the composite cooling film (100) adhered to a substrate (1210) is also disclosed.

Abstract: A composite cooling film (100) comprises an antisoiling layer (160) secured to a first major surface of a reflective microporous layer (110). The reflective microporous layer (110) comprises a first fluoropolymer and is diffusely reflective of electromagnetic radiation over a majority of wavelengths in the range of 400 to 2500 nanometers. The antisoiling layer (160) has an outwardly facing antisoiling surface (162) opposite the micro-voided polymer film. An article (1100) comprising the composite cooling film (1112) secured to a substrate (1110) is also disclosed.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles, a multiplicity of intumescent particles and optionally a multiplicity of endothermic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles, intumescent particles and optional endothermic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 50% over its initial volume when exposed to at least one temperature greater than 135° C. when exposed to at least one temperature greater than 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, thermally-initiated fuses, and fire-stop devices.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a multiplicity of thermally-conductive particles, and a multiplicity of endothermic particles distributed within the (co)polymeric network structure; wherein the thermally-conductive particles and endothermic particles are present in a range from 15 to 99 weight percent, based on the total weight of the particles and the (co)polymer (excluding the solvent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 10% of its initial volume when exposed to a temperature of at least 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, as fillers, thermal interface materials, and thermal management materials, for example, in electronic devices, more particularly mobile handheld electronic devices, power supplies, and batteries.

Abstract: A film includes a polymeric material and a plurality of particles dispersed therein. The polymeric material includes a plurality of elongate polymeric elements oriented along substantially a same first direction and interconnecting the particles. An elongate end portion of at least a first elongate polymeric element in the plurality of elongate polymeric elements conforms and is bonded to a first particle in the plurality of particles along an entire length of the elongate end portion. An elongate mid portion of at least a second elongate polymeric element in the plurality of elongate polymeric elements conforms and is bonded to a second particle in the plurality of particles along an entire length of the elongate mid portion with the second elongate polymeric element extending away from the second particle from opposite ends of the elongate mid portion. Multilayer films and processes are also described.

Abstract: (Co)polymer matrix composites including a porous (co)polymeric network; a nonvolatile diluent, and a multiplicity of thermally-conductive particles distributed within the (co)polymeric network; wherein the thermally-conductive particles are present in a range from 15 to 99 weight percent, based on the total weight of the (co)polymer matrix (including the thermally-conductive particles and the nonvolatile diluent). Optionally, the (co)polymer matrix composite volumetrically expands by at least 10% of its initial volume when exposed to a temperature of at least 135° C. Methods of making and using the (co)polymer matrix composites are also disclosed. The (co)polymer matrix composites are useful, for example, as heat dissipating or heat absorbing articles, as fillers, thermal interface materials, and thermal management materials, for example, in electronic devices, more particularly mobile handheld electronic devices, power supplies, and batteries.

Abstract: A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.